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研究業績

個人のWebsiteを作成しましたので、2023年6月以降に更新された情報はそちらをご覧ください。(Publication List in Personal Website

生越研究室(2020-present)

Original Paper

  1. “Efficient synthesis and unit-selective π-extension of π-fused [4.3.3]propellane as a chiral building block”
    Kenichi Kato,* Seigo Tanaka, Nobuyoshi Seto, Keisuke Wada, Masayuki Gon, Shixin Fa, Shunsuke Ohtani, Kazuo Tanaka, Tomoki Ogoshi*
    Chem. Commun. 2023, XX, XX-XX. (DOI: 10.1039/d3cc01809a)
  2. “Adaptive Planar Chirality of Pillar[5]arenes Invertible by n-Alkane Lengths”
    Keisuke Adachi, Shixin Fa,* Keisuke Wada, Kenichi Kato, Shunsuke Ohtani, Yuuya Nagata, Shigehisa Akine, Tomoki Ogoshi*
    J. Am. Chem. Soc. 2023, 145, 8114-8121. (DOI: 10.1021/jacs.3c01019)
  3. “Per-Arylation of Pillar[n]arenes: An Effective Tool to Modify the Properties of Macrocycles”
    Kenichi Kato,* Tomoya Kaneda, Shunsuke Ohtani, Tomoki Ogoshi*
    J. Am. Chem. Soc. 2023, 145, 6905-6913. (DOI: 10.1021/jacs.3c00397)
  4. “Dynamic-to-Static Planar Chirality Conversion in Pillar[5]arenes Regulated by Guest Solvents or Amplified by Crystallization”
    Keisuke Wada, Misaki Suzuki, Takahiro Kakuta, Tada-aki Yamagishi, Shunsuke Ohtani, Shixin Fa, Kenichi Kato, Shigehisa Akine, Tomoki Ogoshi*
    Angew. Chem. Int. Ed. 2023, 62, e202217971. (DOI: 10.1002/anie.202217971)
  5. “Discrete chiral organic nanotubes by stacking pillar[5]arenes using covalent linkages”
    Tan-Hao Shi, Shixin Fa, Yuuya Nagata, Keisuke Wada, Shunsuke Ohtani, Kenichi Kato, Tomoki Ogoshi*
    Cell Rep. Phys. Sci. 2022, 3, 101173. (DOI: 10.1016/j.xcrp.2022.101173)
  6. “A Twisted Chiral Cavitand with 5-Fold Symmetry and Its Length-Selective Binding Properties”
    Tan-Hao Shi, Yuuya Nagata, Shigehisa Akine, Shunsuke Ohtani, Kenichi Kato, Tomoki Ogoshi*
    J. Am. Chem. Soc. 2022, 144, 23677-23684. (DOI: 10.1021/jacs.2c11225)
  7. “Real-time chirality transfer monitoring from statistically random to discrete homochiral nanotubes”
    Shixin Fa, Tan-hao Shi, Suzu Akama, Keisuke Adachi, Keisuke Wada, Seigo Tanaka, Naoki Oyama, Kenichi Kato, Shunsuke Ohtani, Yuuya Nagata, Shigehisa Akine, Tomoki Ogoshi*
    Nat. Commun. 2022, 13, 7378. (DOI: 10.1038/s41467-022-34827-z)
  8. “Cyclic arrays of five pyrenes on one rim of a planar chiral pillar[5]arene”
    Kenichi Kato,* Shunsuke Ohtani, Masayuki Gon, Kazuo Tanaka, Tomoki Ogoshi*
    Chem. Sci. 2022, 13, 13147-13152. (DOI: 10.1039/d2sc04168e)
  9. “Room-temperature Ring-opening Polymerization of δ-Valerolactone and ε-Caprolactone Caused by Uptake into Porous Pillar[5]arene Crystals”
    Kenichi Kato, Koki Maeda, Motohiro Mizuno, Yuta Nishina, Shixin Fa, Shunsuke Ohtani, Tomoki Ogoshi*
    Angew. Chem. Int. Ed. 2022, 61, e202212874. (DOI: 10.1002/anie.202212874)
  10. “Selective Gas Adsorption on Molecular Solids of a Hydrogen-bonding [3.3.3]Propellane”
    Kenichi Kato,* Tatsuki Hiroi, Nobuyoshi Seto, Shunsuke Ohtani, Tomoki Ogoshi*
    Chem. Lett. 2022, 51, 975-977. (DOI: 10.1246/cl.220320)
  11. “Discrete Macrocycles with Fixed Chirality and Two Distinct Sides: Dipole-Dependent Chiroptical Response”
    Kenichi Kato,* Yuta Kurakake, Shunsuke Ohtani, Shixin Fa, Masayuki Gon, Kazuo Tanaka, Tomoki Ogoshi*
    Angew. Chem. Int. Ed. 2022, 61, e202209222. (DOI: 10.1002/anie.202209222)
  12. “Synthesis of hexa-aminated trinaphtho[3.3.3]propellane and its porous polymer solids with alkane adsorption properties”
    Kenichi Kato,* Nobuyoshi Seto, Koki Chida, Takeharu Yoshii, Motohiro Mizuno, Hirotomo Nishihara, Shunsuke Ohtani, Tomoki Ogoshi*
    Bull. Chem. Soc. Jpn. 2022, 95, 1296-1302. (DOI: 10.1246/bcsj.20220180, Selected Paper)
  13. "Hybrid Chiral MoS2 Layers for Spin-polarized Charge Transport and Spin-dependent Electrocatalytic Applications"
    Zhiyun Bian, Kenichi Kato, Tomoki Ogoshi, Zhou Cui, Baisheng Sa, Yusuke Tsutsui, Shu Seki, Masayuki Suda*
    Adv. Sci. 2022, 9, 2201063. (DOI: 10.1002/advs.202201063)
  14. “CPL on/off control of an assembled system by water soluble macrocyclic chiral sources with planar chirality”
    Shixin Fa, Takuya Tomita, Keisuke Wada, Kazuma Yasuhara, Shunsuke Ohtani, Kenichi Kato, Masayuki Gon, Kazuo Tanaka, Takahiro Kakuta, Tada-aki Yamagishi, Tomoki Ogoshi*
    Chem. Sci. 2022, 13, 5846-5853. (DOI: 10.1039/d2sc00952h)
  15. "State- and Water Repellency-Controllable Molecular Glass of Pillar[5]arene with Fluoroalkyl Groups by Guest Vapor"
    Katsuto Onishi, Shunsuke Ohtani, Kenichi Kato, Shixin Fa, Yoko Sakata, Shigehisa Akine, Moe Ogasawara, Hitoshi Asakawa, Shusaku Nagano, Yoshinori Takashima, Motohiro Mizuno, Tomoki Ogoshi*
    Chem. Sci. 2022, 13, 4082-4087. (DOI: 10.1039/d2sc00828a)
  16. "Pre-regulation of the Planar Chirality of Pillar[5]arenes for Preparing Discrete Chiral Nanotubes"
    Shixin Fa, Keisuke Adachi, Yuuya Nagata, Kouichi Egami, Kenichi Kato, Tomoki Ogoshi*
    Chem. Sci. 2021, 12, 3483-3488. (DOI: 10.1039/d1sc00074h, Back Cover)
  17. "Thermally Responsive Poly(ethylene oxide)-based Polyrotaxanes Bearing Hydrogen-bonding Pillar[5]arene Rings"
    Kenichi Kato, Katsuto Onishi, Koki Maeda, Masafumi Yagyu, Shixin Fa, Takahiro Ichikawa, Motohiro Mizuno, Takahiro Kakuta, Tada-aki Yamagishi, Tomoki Ogoshi*
    Chem. Eur. J. 2021, 27, 6435-6439. (DOI: 10.1002/chem.202005099, Front Cover)
  18. "Sequential Chiral Induction and Regulator-assisted Chiral Memory of Pillar[5]arenes"
    Shixin Fa, Koichi Egami, Keisuke Adachi, Kenichi Kato, Tomoki Ogoshi*
    Angew. Chem. Int. Ed. 2020, 59, 20353-20356. (DOI: 10.1002/anie.202010050, Inside Back Cover)

Review & Book Chapter

  1. "Host-Guest Behavior of Pillar[n]arene-Based Supramolecular Assemblies"
    Tan-hao Shi, Shunsuke Ohtani, Kenichi Kato, Shixin Fa, Tomoki Ogoshi*
    Trends Chem. 2023, XX, XX-XX. (DOI: 10.1016/j.trechm.2023.04.004)
  2. "Noncovalently bound and mechanically interlocked systems using pillar[n]arenes"
    Kenichi Kato, Shixin Fa, Shunsuke Ohtani, Tan-hao Shi, Albert M. Brouwer,* Tomoki Ogoshi*
    Chem. Soc. Rev. 2022, 51, 3648-3687. (DOI: 10.1039/d2cs00169a)
  3. "Host-Guest Chemistry Based on Solid-State Pillar[n]arenes"
    Shunsuke Ohtani, Kenichi Kato, Shixin Fa, Tomoki Ogoshi*
    Coord. Chem. Rev. 2022, 462, 214503. (DOI: 10.1016/j.ccr.2022.214503)
  4. "Discrete and Continuous One-Dimensional Channels Based on Pillar[n]arenes"
    Kenichi Kato, Shunsuke Ohtani, Shixin Fa, Tomoki Ogoshi*
    Bull. Chem. Soc. Jpn. 2021, 94, 2319-2328. (DOI: 10.1246/bcsj.20210243)

Others

  1. 「柱状分子ピラーアレーンに基づくチューブ構造の創成」
    加藤 研一、FA Shixin、生越 友樹
    超分子研究会アニュアルレビュー、No. 41 (2020)、高分子学会、2021年、pp. 8-9(レビュー)
  2. 「ピラー[n]アレーンを基にしたソフトクリスタルの開発」
    和田 圭介、加藤 研一、生越 友樹
    日本結晶学会誌、第63巻 第1号、日本結晶学会、2021年、pp. 8-15(DOI: 10.5940/jcrsj.63.8、特集記事)
  3. 「環状分子を非対称化しよう — 二面性ピラー[5]アレーンの化学」
    加藤 研一、FA Shixin、生越 友樹
    化学、第75巻 第12号、化学同人、2020年、pp. 64-65(最新のトピックス)

大須賀研究室(2014-2020)

Original Paper

  1. “Double helices of dissymmetrical α,α’-disubstituted tripyrrins”
    Y. Fukuda, Y. Akamatsu, M. Umetani, K. Kise, K. Kato, A. Osuka, T. Tanaka
    Org. Biomol. Chem. 2023, 21, 1158-1162. (DOI: 10.1039/d2ob02125k)
  2. “A Robust Triplet Porphyrin-Stabilized Carbon Diradical”
    K. Wang, L. Xu, M. Zhou, A. Nakai, K. Kato, K. Furukawa, T. Tanaka, A. Osuka, J. Song
    Angew. Chem. Int. Ed. 2021, 60, 7002-7006. (DOI: 10.1002/anie.202015356)
  3. "Propeller-shaped Semi-fused Porphyrin Trimers: Molecular-symmetry-dependent Chiroptical Response"
    K. Kato, A. Osuka
    Chem. Eur. J. 2020, 26, 10217-10221. (DOI: 10.1002/chem.202002157)
  4. "Helically Twisted Benzene-1,3,5-triamine-fused Porphyrin Dimers"
    K. Kato, A. Osuka
    Chem. Lett. 2020, 49, 517-520. (DOI: 10.1246/cl.200115, Editor's Choice)
  5. "Cyclophane-type Chlorin Dimers from Dynamic Covalent Chemistry of 2,18-Porphyrinyl Dicyanomethyl Diradicals"
    B. Adinarayana, K. Kato, D. Shimizu, T. Tanaka, K. Furukawa, A. Osuka
    Angew. Chem. Int. Ed. 2020, 59, 4320-4323. (DOI: 10.1002/anie.201914480)
  6. "Phenylene-bridged Porphyrin meso-Oxy Radical Dimers"
    T. Yamamoto, K. Kato, D. Shimizu, T. Tanaka, A. Osuka
    Chem. Asian J. 2019, 14, 4031-4034. (DOI: 10.1002/asia.201901033)
  7. "meta- and para-Phenylenediamine-fused Porphyrin Dimers: Synthesis and Magnetic Interactions in Their Dication Diradicals"
    K. Kato, A. Osuka
    Angew. Chem. Int. Ed. 2019, 58, 8546-8550. (DOI: 10.1002/anie.201901939)
  8. "Aromatic and Antiaromatic Cyclophane-type Hexaphyrin Dimers"
    A. Nakai, T. Yoneda, S.-i. Ishida, K. Kato, A. Osuka
    Chem. Asian J. 2019, 14, 256-260. (DOI: 10.1002/asia.201801751)
  9. "A Stable Trimethylenemethane Triplet Diradical Based on a Trimeric Porphyrin Fused π-System"
    K. Kato, K. Furukawa, A. Osuka
    Angew. Chem. Int. Ed. 2018, 57, 9491-9494. (DOI: 10.1002/anie.201804644)
  10. "Porphyrin-Based Air-Stable Helical Radicals"
    K. Kato, K. Furukawa, T. Mori, A. Osuka
    Chem. Eur. J. 2018, 24, 572-575. (DOI: 10.1002/chem.201705291, Very Important Paper, highlighted in Synfacts 2018, 14, 0143)
  11. "Cyclic Hybrids of Alternately Linked 2,5-Pyrrolylenes and 3,4-Thienylenes"
    K. Kise, F. Chen, K. Kato, T. Tanaka, A. Osuka
    Chem. Lett. 2017, 46, 1319-1322. (DOI: 10.1246/cl.170511)
  12. "Spontaneous Formation of an Air-Stable Radical upon the Direct Fusion of Diphenylmethane to a Triarylporphyrin"
    K. Kato, W. Cha, J. Oh, K. Furukawa, H. Yorimitsu, D. Kim, A. Osuka
    Angew. Chem. Int. Ed. 2016, 55, 8711-8714. (DOI: 10.1002/anie.201602683)
  13. "Triphenylsilane-fused Porphyrins"
    K. Kato, J. O. Kim, H. Yorimitsu, D. Kim, A. Osuka
    Chem. Asian J. 2016, 11, 1738-1746. (DOI: 10.1002/asia.201600424)
  14. "Porphyrin Analogues of a Trityl Cation and Anion"
    K. Kato, W. Kim, D. Kim, H. Yorimitsu, A. Osuka
    Chem. Eur. J. 2016, 22, 7041-7045. (DOI: 10.1002/chem.201600473, Hot Paper)
  15. "Regioselective phenylene-fusion reactions of Ni(II)-porphyrins controlled by an electron-withdrawing meso-substituent"
    N. Fukui, S.-K. Lee, K. Kato, D. Shimizu, T. Tanaka, S. Lee, H. Yorimitsu, D. Kim, A. Osuka
    Chem. Sci. 2016, 7, 4059-4066. (DOI: 10.1039/c5sc04748j)
  16. "Peripherally Silylated Porphyrins"
    K. Kato, K. Fujimoto, H. Yorimitsu, A. Osuka
    Chem. Eur. J. 2015, 21, 13522-13525. (DOI: 10.1002/chem.201502563, Hot Paper)

Review & Book Chapter

  1. "Porphyrinoid-Based Diradicaloids"
    K. Kato, A. Osuka
    in Diradicaloids (Ed.: J. Wu), Jenny Stanford Publishing, Singapore, 2022, pp. 453-503 (Chapter 11). (ISBN: 9789814968089)
  2. "Platforms for Stable Carbon-Centered Radicals"
    K. Kato, A. Osuka
    Angew. Chem. Int. Ed. 2019, 58, 8978-8986. (DOI: 10.1002/anie.201900307)