Publications のバックアップ(No.1)
2010
- Catalytic carboborations
- Michinori Suginome
- Chem. Rec. 2010, 10, 348–358, 10.1002/tcr.201000029
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- Stereospecific Suzuki-Miyaura Coupling of Chiral α-(Acylamino)benzylboronic Esters with Inversion of Configuration
- Toshimichi Ohmura, Tomotsugu Awano, and Michinori Suginome
- J. Am. Chem. Soc. 2010, 132, 13191-13193, 10.1021/ja106632j
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- Switch of Regioselectivity in Palladium-Catalyzed Silaboration of Terminal Alkynes by Ligand-Dependent Control of Reductive Elimination
- Toshimichi Ohmura, Kazuyuki Oshima, Hiroki Taniguchi, and Michinori Suginome
- J. Am. Chem. Soc. 2010, 132, 12194-12196, 10.1021/ja105096r
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- Non-hydrogen-bonding-based, solvent-dependent helix inversion between pure P-helix and pure M-helix in poly(quinoxaline-2,3-diyl)s bearing chiral side chains
- Tetsuya Yamada, Yuuya Nagata and Michinori Suginome
- Chem. Commun. 2010, 46, 4914-4916, 10.1039/c001564d
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- High-Molecular-Weight Polyquinoxaline-Based Helically Chiral Phosphine (PQXphos) as Chirality-Switchable, Reusable, and Highly Enantioselective Monodentate Ligand in Catalytic Asymmetric Hydrosilylation of Styrenes
- Takeshi Yamamoto, Tetsuya Yamada, Yuuya Nagata and Michinori Suginome
- J. Am. Chem. Soc. 2010, 132, 7899–7901, 10.1021/ja102428q
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- Rhodium-catalyzed Dehydroborylation of Styrenes with Naphthalene-1,8-diaminatoborane [(dan)BH]: New Synthesis of Masked β-Borylstyrenes as New Phenylene–Vinylene Cross-coupling Modules
- Noriyuki Iwadate and Michinori Suginome
- Chem. Lett. 2010, 39, 558-560, 10.1246/cl.2010.558
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- Nickel-Catalyzed Asymmetric Addition of Alkyne C-H Bonds across 1,3-Dienes Using Taddol-Based Chiral Phosphoramidite Ligands
- Masamichi Shirakura and Michinori Suginome
- Angew. Chem. Int. Ed. 2010, 49, 3827-3829, 10.1002/anie.201001188
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- Synthesis of Helical Rod−Coil Multiblock Copolymers by Living Block Copolymerization of Isocyanide and 1,2-Diisocyanobenzene Using Arylnickel Initiators
- Tetsuya Yamada and Michinori Suginome
- Macromolecules 2010, 43, 3999-4002, 10.1021/ma100500r
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- Langmuir–Blodgett films of helical rigid-rod poly(quinoxaline-2,3-diyl)s
- Yoshihiko Ito, Toshiyuki Miyake, Michinori Suginome, Rie Katakura, Masaya Mitsuishi, and Tokuji Miyashita
- Polym. J. 2010, 42, 406-410, 10.1038/pj.2010.14
- Recent Progress of Catalytic Hydroboration: Use of Copper and Iron Catalysts (written in Japanese)
- Toshimichi Ohmura
- Organometallic News 2010, 28, 28-28
- Differentially Protected Diboron for Regioselective Diboration of Alkynes: Internal-Selective Cross-Coupling of 1-Alkene-1,2-diboronic Acid Derivatives
- Noriyuki Iwadate and Michinori Suginome
- J. Am. Chem. Soc. 2010, 132, 2548-2549, 10.1021/ja1000642
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- Chiral Arylnickel Complexes as Highly Active Initiators for Screw-Sense Selective Living Polymerization of 1,2-Diisocyanobenzenes
- Tetsuya Yamada, Hiroyoshi Noguchi, Yuuya Nagata, and Michinori Suginome
- J. Polym. Sci. Part A: Polym. Chem. 2010, 48, 898-904, 10.1002/pola.23842
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2009
- Palladium-Catalyzed Silylene-1,3-Diene [4 + 1] Cycloaddition with Use of (Aminosilyl)boronic Esters as Synthetic Equivalents of Silylene
- Toshimichi Ohmura, Kohei Masuda, Ichiro Takase, and Michinori Suginome
- J. Am. Chem. Soc. 2009, 131, 16624-16625, 10.1021/ja907170p
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- Nickel-Catalyzed Ring-Opening Hydroacylation of Methylenecyclopropanes:
Synthesis of γ,δ-Unsaturated Ketones from Aldehydes
- Hiroki Taniguchi, Toshimichi Ohmura, and Michinori Suginome
- J. Am. Chem. Soc. 2009, 131, 11298-11299, 10.1021/ja9046894
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- Kinetic Resolution of Racemic 1-Alkyl-2-methylenecyclopropanes via Palladium-Catalyzed Silaborative C–C Cleavage
- Toshimichi Ohmura, Hiroki Taniguchi, and Michinori Suginome
- Org. Lett. 2009, 11, 2880-2883, 10.1021/ol900829c
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- Easily Attachable and Detachable ortho-Directing Agent for Arylboronic Acids in Ruthenium-Catalyzed Aromatic C−H Silylation
- Hideki Ihara and Michinori Suginome
- J. Am. Chem. Soc. 2009, 131, 7502-7503, 10.1021/ja902314v
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- α-Amidobenzylation of Aryl and Alkenyl Halides via Palladium-catalyzed Suzuki-Miyaura Coupling with α-(Acylamino)benzylboronic Esters
- Toshimichi Ohmura, Tomotsugu Awano, and Michinori Suginome
- Chem. Lett. 2009, 38, 664-665, 10.1246/cl.2009.664
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- Palladium-catalyzed intramolecular cyanoboration of allenes leading to the regioselective synthesis of β-cyanoallylboranes
- Akihiko Yamamoto, Yuto Ikeda, and Michinori Suginome
- Tetrahedron Lett. 2009, 50, 3168-3170, 10.1016/j.tetlet.2009.01.025
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- Synthesis of 1-Borylisoindoles via Palladium-Catalyzed Dehydrogenation/C−H Borylation of Isoindolines
- Toshimichi Ohmura, Akihito Kijima and Michinori Suginome
- J. Am. Chem. Soc. 2009, 131, 6070-6071, 10.1021/ja901095h
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- Synthesis of B-Protected β-Styrylboronic Acids via Iridium-Catalyzed Hydroboration of Alkynes with 1,8-Naphthalenediaminatoborane Leading to Iterative Synthesis of Oligo(phenylenevinylene)s
- Noriyuki Iwadate and Michinori Suginome
- Org. Lett. 2009, 11, 1899-1902, 10.1021/ol9003096
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- Nickel-Catalyzed, Regio- and Stereoselective Hydroalkynylation of Methylenecyclopropanes with Retention of the Cyclopropane Ring, Leading to the Synthesis of 1-Methyl-1-Alkynylcyclopropanes
- Masamichi Shirakura and Michinori Suginome
- J. Am. Chem. Soc. 2009, 131, 5060-5061, 10.1021/ja900876w
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- Synthesis of masked haloareneboronic acids via iridium-catalyzed aromatic C–H borylation with 1,8-naphthalenediaminatoborane (danBH)
- Noriyuki Iwadate and Michinori Suginome
- J. Organomet. Chem. 2009, 694, 1713-1717, 10.1016/j.jorganchem.2008.11.068
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- Stereoselective Synthesis of cis-β-Methyl- and Phenyl-Substituted Alkenylboronates by Platinum-Catalyzed Dehydrogenative Borylation
- Toshimichi Ohmura, Yuta Takasaki, Hideki Furukawa, and Michinori Suginome
- Angew. Chem. Int. Ed. 2009, 48, 2372-2375, 10.1002/anie.200805406
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- B(OMe)SUB{3}; as a Nonacidic Iminium Ion Generator in Mannich- and Ugi-Type Reactions
- Yusuke Tanaka, Kousuke Hidaka, Tomoaki Hasui, and Michinori Suginome
- Eur. J. Org. Chem. 2009, 8, 1148-1151, 10.1002/ejoc.200801190
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- Nickel-Catalyzed Regioselective Hydroalkynylation of Styrenes: Improved Catalyst System, Reaction Scope, and Mechanism
- Masamichi Shirakura and Michinori Suginome
- Org. Lett. 2009, 11, 523-526, 10.1021/ol802475h
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- Silylboranes as New Tools in Organic Synthesis
- Toshimichi Ohmura and Michinori Suginome
- Bull. Chem. Soc. Jpn. 2009, 82, 29-49, 10.1246/bcsj.82.29
- Helical Poly(quinoxaline-2,3-diyl)s Bearing Metal-Binding Sites as Polymer-Based Chiral Ligands for Asymmetric Catalysis
- Takeshi Yamamoto and Michinori Suginome
- Angew. Chem. Int. Ed. 2009, 48, 539-542, 10.1002/anie.200803719
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2008
- Carbon-Silicon Bond Formation via Transition Metal-Catalyzed Reaction of Silylene Equivalents (Japanese)
- Toshimichi Ohmura and Michinori Suginome
- Keiso Kagaku Kyokaishi, 2008, 25, 32-35
- Iterative Suzuki-Miyaura cross-coupling reaction for the selective synthesis of oligoarenes
- Michinori Suginome
- Ekisho, 2008, 12, 296-305
- Palladium-Catalyzed Carboboration of Alkynes Using Chloroborane and
Organozirconium Reagents
- Masaki Daini and Michinori Suginome
- Chem. Commun. 2008, 5224-5226, 10.1039/b809433k
- Diarylborinic Acid Derivatives as a Catalytic Iminium Ion Generator in the Mannich-Type Reaction Using Secondary Amines, Aldehydes, and Ketene Silyl Acetals
- Yusuke Tanaka, Tomoaki Hasui, Michinori Suginome
- Synlett 2008, 1239-1242, 10.1055/s-2008-1072724
- Nickel-Catalyzed Addition of C-H Bonds of Terminal Alkynes to 1,3-Dienes and Styrenes
- Masamichi Shirakura and Michinori Suginome
- J. Am. Chem. Soc. 2008 130, 5410-5411, 10.1021/ja800997j
- A Mechanism for the Palladium-Catalyzed Regioselective Silaboration of Allene: A Theoretical Study
- Yoko Abe, Kei Kuramoto, Masahiro Ehara, Hiroshi Nakatsuji, Michinori Suginome, Masahiro Murakami and Yoshihiko Ito
- Organometallics, 2008, 27, 1736-1742, 10.1021/om070110f
- "Synthetic organic chemistry" and "polymer science" of isocyanide
- Michinori Suginome
- Kobunshi, 2008, 57, 130-133
- Palladium-Catalysed cis- and trans-Silaboration of Terminal Alkynes: Complementary Access to Stereo-Defined Trisubstituted Alkenes
- Toshimichi Ohmura, Kazuyuki Oshima and Michinori Suginome
- Chem. Comm. 2008, 1416-1418, 10.1039/b800181b
- Palladium-Catalyzed trans- and cis-Carboboration of Alkynes Tethered to Chloroborane with Organozirconium Reagents: Ligand-Dependent Complementary Stereoselectivity
- Masaki Daini, Akihiko Yamamoto, and Michinori Suginome
- J. Am. Chem. Soc. 2008, 130, 2918-2919, 10.1021/ja711160h
- Synthetic Application of Intramolecular Cyanoboration on the Basis of Removal and Conversion of a Tethering Group by Palladium-Catalyzed Retro-Allylation
- Toshimichi Ohmura, Tomotsugu Awano, Michinori Suginome, Hideki Yorimitsu, and Koichiro Oshima
- Synlett 2008, 423-427, 10.1055/s-2008-1032075
- Silylboranes Bearing Dialkylamino Groups on Silicon as Silylene Equivalents: Palladium-Catalyzed Regioselective Synthesis of 2,4-Disubstituted Siloles
- Toshimichi Ohmura, Kohei Masuda, and Michinori Suginome
- J. Am. Chem. Soc. 2008, 130, 1526-1527, 10.1021/ja073896h
- Differentially Protected Benzenediboronic Acids: Divalent Cross-Coupling Modules for the Efficient Synthesis of Boron-Substituted Oligoarenes
- Hiroyoshi Noguchi, Takayuki Shioda, Chih-Ming Chou, and Michinori Suginome
- Org. Lett. 2008, 10, 377-380, 10.1021/ol702420x
2007
- Development of Boron-Based Reactions and Reagents for Organic Synthesis
- Michinori Suginome
- J. Synth. Org. Chem., Jpn. 2007, 65, 1048-1059
- Acid-Free, Aminoborane-Mediated Ugi-Type Reaction Leading to General Utilization of Secondary Amines
- Yusuke Tanaka, Tomoaki Hasui, and Michinori Suginome
- Org. Lett. 2007, 9, 4407-4410, 10.1021/ol701570c
- Synthesis and Helical Structure of Oligo(quinoline-2,3-diyl)s
- Michinori Suginome, Hiroyoshi Noguchi and Masahiro Murakami
- Chem. Lett. 2007, 36, 1036-1037, 10.1246/cl.2007.1036
- Palladium-Catalyzed Asymmetric Silaborative C-C Cleavage of meso-Methylenecyclopropanes
- Toshimichi Ohmura, Hiroki Taniguchi, Yoshiyuki Kondo, and Michinori Suginome
- J. Am. Chem. Soc. 2007, 129, 3518-3519, 10.1021/ja0703170
- Synthesis of Silylboronic Esters Functionalized on Silicon
- Toshimichi Ohmura, Kohei Masuda, Hideki Furukawa, Michinori Suginome
- Organometallics 2007, 26, 1291-1294, 10.1021/om0609867
- Boron-Masking Strategy for the Selective Synthesis of Oligoarenes via Iterative Suzuki-Miyaura Coupling
- Hiroyoshi Noguchi, Kosho Hojo, Michinori Suginome
- J. Am. Chem. Soc. 2007, 129, 758-759, 10.1021/ja067975p
- C-E Bond Formation through Element-Element Addition to Carbon-Carbon Multiple Bonds
- Michinori Suginome, Takanori Matsuda, Toshimichi Ohmura, Atsushi Seki, Masahiro Murakami
- In Comprehensive Organometallic Chemistry III; Crabtree, R. and Mingos, M. Eds.; Ojima, I. Vol. Ed.; Elsevier, 2007; Volume 10, pp 725-787
2006
- Nickel-Catalyzed Addition of Alkynylboranes to Alkynes
- Michinori Suginome, Masamichi Shirakura, Akihiko Yamamoto
- J. Am. Chem. Soc. 2006, 128, 14438-14439
- Palladium-Catalyzed Asymmetric Silaboration of Allenes
- Toshimichi Ohmura, Hiroki Taniguchi, Michinori Suginome
- J. Am. Chem. Soc. 2006, 128, 13682-13683
- Ligand-Controlled, Complementary Stereoselectivity in the Platinum-Catalyzed Intramolecular Silaboration of Alkenes
- Toshimichi Ohmura, Hideki Furukawa, Michinori Suginome
- J. Am. Chem. Soc. 2006, 128, 13366-13367
- Aminoboranes as New Iminium Ion Generators in Amination Reactions
- Michinori Suginome
- Pure Appl. Chem. 2006, 78, 1377-1387
- Reductive amination of aldehydes using aminoboranes as iminium ion generators
- Michinori Suginome, Yusuke Tanaka, Tomoaki Hasui
- Synlett 2006, 1047-1050
- Asymmetric Silaboration of Terminal Allenes Bearing α-Stereogenic Centers: Stereoselection Based on "Reagent Control"
- Toshimichi Ohmura and Michinori Suginome
- Org. Lett. 2006, 8, 2503-2506
- Reactions of Cyanoboranes with a Palladium-PMeSUB{3}; Complex: Mechanism for the Catalytic Cyanoboration of Alkynes
- Michinori Suginome, Akihiko Yamamoto, Taisuke Sasaki, Masahiro Murakami
- Organometallics 2006, 25, 2911-2913
2005
- Nickel-Catalyzed trans-Alkynylboration of Alkynes via Activation of a Boron-Chlorine Bond
- Akihiko Yamamoto, Michinori Suginome
- J. Am. Chem. Soc. 2005, 127, 15706-15707
- Intramolecular Cyanoboration of Alkynes via Activation of Boron-Cyanide Bonds by Transition Metal Catalysts
- Michinori Suginome, Akihiko Yamamoto, Masahiro Murakami
- J. Organomet. Chem. 2005, 690, 5300-5308
- Carbon-carbon bond formation using boron. Design, creation, and new reactions of functional boron reagents
- Michinori Suginome
- Kagaku to Kogyo, 2005, 58, 919-922
- New development of organosilicon compound synthesis
- Toshimichi Ohmura and Michinori Suginome
- Kagaku, 2005, 60, 68-69
- Stereoselective Synthesis of Highly Enantioenriched (E)-Allylsilanes by Palladium-Catalyzed Intramolecular Bis-Silylation: 1,3-Chirality Transfer and Enantioenrichment via Dimer Formation
- Michinori Suginome, Taisuke Iwanami, Yutaka Ohmori, Akira Matsumoto, Yoshihiko Ito
- Chem. Eur. J. 2005, 11, 2954-2965
- Palladium-Catalyzed Addition of Cyanoboranes to Alkynes Leading to Regio- and Stereoselective Synthesis of β-Boryl-α,β-Unsaturated Nitriles
- Michinori Suginome, Akihiko Yamamoto, Masahiro Murakami
- Angew. Chem. Int. Ed. 2005, 44, 2380-2382
- Synthesis and Reactions of Cyclic Silylboranes
- Michinori Suginome, Hiroyoshi Noguchi, Tomoaki Hasui, Masahiro Murakami
- Bull. Chem. Soc. Jpn. 2005, 78, 323-326
- Synthesis and Structural Analysis of Oligo(naphthalene-2,3-diyl)s
- Takahisa Motomura, Hideko Nakamura, Michinori Suginome, Masahiro Murakami, and Yoshihiko Ito
- Bull. Chem. Soc. Jpn. 2005, 78, 142-146
2004
- Aminoboranes as "Compatible" Iminium Ion Generators in Aminative C-C Bond Formations
- Michinori Suginome, Lars Uehlin, and Masahiro Murakami
- J. Am. Chem. Soc. 2004, 126, 13196-13197
- A New Look at Boron Enolate Chemistry: Aminative C-C Bond Formation Using Diaminoboron Enolate with Aldehyde
- Michinori Suginome, Lars Uehlin, Akihiko Yamamoto, and Masahiro Murakami
- Org. Lett. 2004, 6, 1167-1169.
2003
- Enantioface-Selective Palladium-Catalyzed Silaboration of Allenes via Double Asymmetric Induction
- Michinori Suginome, Toshimichi Ohmura, Yoshihiro Miyake, Shin’ichirou Mitani, Yoshihiko Ito, Masahiro Murakami
- J. Am. Chem. Soc. 2003, 125, 11174-11175.
- Palladium- and Nickel-Catalyzed Intramolecular Cyanoboration of Alkynes
- Michinori Suginome, Akihiko Yamamoto, Masahiro Murakami
- J. Am. Chem. Soc. 2003, 125, 6358-6359.
2002
- Bis(dialkylamino)cyanoboranes: highly efficient reagents for the Strecker-type aminative cyanation of aldehydes and ketones.
- M. Suginome, A. Yamamoto, Y. Ito
- Chem. Comm. 2002, 1392-1393.
- Nickel-Catalyzed Silaboration of Small-Ring Vinylcycloalkanes: Regio- and Stereoselective(E)-Allylsilane Formation via C-C Bond Cleavage.
- M. Suginome, T. Matsuda, T. Yoshimoto, Y. Ito
- Organometallics 2002, 21, 1537-1539.
- 1,2-Azaboretidine Formation in the Reactions of (Boryl)(silyl)iminomethanes via Possible Generation of (Amino)(boryl)carbene Species
- M. Suginome, T. Fukuda, Y. Ito
- J. Organomet. Chem. 2002, 643-644, 508-511. (Special issue dedicated to Prof. F. Mathey)
- Highly Effective, Easily Accessible Screw-Sense-Determining End Group in theAsymmetric Polymerization of 1,2-Diisocyanobenzenes.
- M. Suginome, S. Collet, Y. Ito
- Org. Lett. 2002, 4, 351-354.
2001
- Stereoselective construction of trans-1,2-benzooxadecaline frameworks by three-component cascade reactions of an a-phenethyl-b-borylallylsilane with aldehydes
- M. Suginome, Y. Ohmori, Y. Ito
- Chem. Commun. 2001, 1090-1091.
- Solid-Phase Synthesis and Asymmetric Reactions of Polymer-Supported Highly Enantioenriched Allylsilanes
- M. Suginome, T. Iwanami, and Y. Ito
- J. Am. Chem. Soc. 2001, 123, 4356-4357.
- Asymmetric Synthesis of Cyclic Alkenes via Cyclization of Enantioenriched Allylsilanes
- M. Suginome, T. Iwanami, A. Yamamoto, and Y. Ito
- Synlett 2001, 1042-1045.
- β-Borylallylsilanes as a New Tool for Convenient Synthesis of Alkenylboranes
- M. Suginome, Y. Ohmori, and Y. Ito
- J. Am. Chem. Soc. 2001, 123, 4601-4602.
2000
- Palladium- and Platinum-Catalyzed Silaboration of Methylenecyclopropanes through Selective Proximal or Distal C-C Bond Cleavage
- M. Suginome, T. Matsuda, and Y. Ito
- J. Am. Chem. Soc. 2000, 122, 11015-11016.
- Convenient Preparation of Silylboranes
- M. Suginome, T. Matsuda, and Y. Ito
- Organometallics 2000, 19, 4647-4649.
- First Synthesis and Resolution of a Planar-chiral Tetrahydroindolyl Complex of Iron: Electronic Tuning of Reactivity and Enantioselective Nucleophilic Catalysis
- M. Suginome and G. C. Fu
- Chirality 2000, 12, 318-324.
- Palladium-Catalyzed Regioselective Silaboration of 1,2-Dienes
- M. Suginome, Y. Ohmori, Y. Ito
- J. Organomet. Chem. 2000, 611, 403-413. (Special issue: The Chemistry of Interelement Linkage)
- Structural Modification of Living Polymers: Synthesis of Helical Block Copolymers from a Single Monomer via Palladium-Mediated Aromatizing Polymerization of 1,2-Diisocyanobenzenes
- Y, Ito, T. Miyake, M. Suginome
- Macromolecules 2000, 33, 4034-4038.
- Synthesis of (Boryl)(silyl)iminomethanes by Insertion of Isonitriles into Silicon-Boron Bonds
- M. Suginome, T. Fukuda, H. Nakamura, Y. Ito
- Organometallics 2000, 19, 719-721.