発表論文 - The Suginome Research Group

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2024 †

In Situ Dehydrogenative Generation of Vinyl Groups Bound to Heteroatoms by the Use of Ethyl Groups as Surrogates in Iridium-Catalyzed Intramolecular C–H/C–H Coupling
- Kaito Yagi, Toshimichi Ohmura, Michinori Suginome
- ACS Catal., 2024, 14, 2014–2021, 10.1021/acscatal.3c05965

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2023 †

A Traceless Chiral Shift Reagent Based on Nonbonding Interaction with Single-Handed Helical Poly(quinoxaline-2,3-diyl)
- Takaya Fujie, Takeshi Yamamoto, Michinori Suginome
- Angew. Chem. Int. Ed., 2023, 10.1002/anie.202301347

ボロニル基での重合後修飾に基づいた動的キラル高分子触媒の創製
- 山本武司, 良永裕佳子, 杉野目道紀
- 有機合成化学協会誌, 2023, 81, 324-332, 10.5059/yukigoseikyokaishi.81.324

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2022 †

Iridium-Catalyzed Enantioselective Intramolecular Cross-Dehydrogenative Coupling of Alkyl Aryl Ethers Giving Enantioenriched 2,3-Dihydrobenzofurans
- Satoshi Kusaka, Toshimichi Ohmura, Michinori Suginome
- Chem. Lett., 2022, 51, 601–604, 10.1246/cl.220129 (Open Access)

Synthesis of Disilanes, Dihydrosiloles, and 1,4-Disilacyclohexa-2,5-dienes by Transition-Metal-Free Transfer of Diphenylsilylene and Dimethylsilylene from Silylboronic Esters
- Ikuo Sasaki, Asahi Maebashi, Jiaying Li, Toshimichi Ohmura, Michinori Suginome
- Eur. J. Org. Chem., 2022, e202101573, 10.1002/ejoc.202101573
- A Special Collection on “Silicon Chemistry in Organic Synthesis”

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2021 †

Iridium-Catalyzed Enantioselective Intramolecular Hydroarylation of Allylic Aryl Ethers Devoid of a Directing Group on the Aryl Group
- Toshimichi Ohmura, Satoshi Kusaka, Michinori Suginome
- Chem. Commun., 2021, 57, 13542–13545, 10.1039/D1CC05684K

PQXdpap: Helical Poly(quinoxaline-2,3-diyl)s Bearing 4-(Dipropylamino)pyridin-3-yl Pendants as Chirality-Switchable Nucleophilic Catalysts for the Kinetic Resolution of Secondary Alcohols
- Takeshi Yamamoto, Ryo Murakami, Michinori Suginome
- Org. Lett., 2021, 23, 8711-8716, 10.1021/acs.orglett.1c03134

Mechanism of 2,6-Dichloro-4,4’-bipyridine-Catalyzed Diboration of Pyrazines Involving a Bipyridine-Stabilized Boryl Radical
- Toshimichi Ohmura, Yohei Morimasa, Tomoya Ichino, Yusuke Miyake, Yasujiro Murata, Michinori Suginome, Kunihiko Tajima, Tetsuya Taketsugu, Satoshi Maeda
- Bull. Chem. Soc. Jpn., 2021, 94, 1894–1902, 10.1246/bcsj.20210145 (Open Access)
- Selected as "BCSJ Award Article" (Vol. 94, No. 7, 2021).

Intramolecular Addition of a Dimethylamino C(sp3)–H Bond across C–C Triple Bonds using IrCL(DTBM-SEGPHOS)(ethylene) Catalyst: Synthesis of Indoles from 2-Alkynyl-N-methylanilines
- Toshimichi Ohmura, Kaito Yagi, Takeru Torigoe, Michinori Suginome
- Synthesis, 2021, 53, 3057–3064, 10.1055/a-1511-1025
- A Special Issue on “Bond Activation - in Honor of Prof. Shinji Murai”

Protected Amino Acids as a Nonbonding Source of Chirality in Induction of Single-Handed Screw-Sense to Helical Macromolecular Catalysts
- Shoma Ikeda, Ryohei Takeda, Takaya Fujie, Naoto Ariki, Yuuya Nagata, Michinori Suginome
- Chem. Sci., 2021, 12, 8811–8816, 10.1039/D1SC01764K (Open Access)

Copper-Catalyzed Regioselective trans-Silaboration of Internal Arylalkynes with Stereochemical Switch to cis-Addition Mode
- Toshimichi Ohmura, Yuta Takaoka, Michinori Suginome
- Chem. Commun., 2021, 57, 4670–4673, 10.1039/D1CC01579F

Asymmetric O-to-C Aryloxycarbonyl Migration of Indolyl Carbonates Using Single-handed Dynamic Helical Polyquinoxalines Bearing 4-Aminopyridyl Groups as Chiral Nucleophilic Catalysts
- Takeshi Yamamoto, Takuya Takahashi, Ryo Murakami, Naoto Ariki, Michinori Suginome
- Bull. Chem. Soc. Jpn., 2021, 94, 943–949,10.1246/bcsj.20200369

Amphiphilic Immobilized Diphenylprolinol Alkyl Ether Catalyst on PS-PEG Resin
- Seitaro Koshino, Shusuke Hattori, Shota Hasegawa, Naoki Haraguchi, Takeshi Yamamoto, Michinori Suginome, Yasuhiro Uozumi, Yujiro Hayashi
- Bull. Chem. Soc. Jpn., 2021, 94, 790–797, 10.1246/bcsj.20200355

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2020 †

Enantioconvergent Cu-Catalyzed Intramolecular C–C Coupling at Boron-Bound C(sp3) Atoms of α-Aminoalkylboronates Using a C1-Symmetrical 2,2′-Bipyridyl Ligand Attached to a Helically Chiral Macromolecular Scaffold
- Yukako Yoshinaga, Takeshi Yamamoto, Michinori Suginome
- J. Am. Chem. Soc., 2020, 142, 18317–18323, 10.1021/jacs.0c09080

ボリルシランをシリレンおよびシレン合成等価体として利用する触媒的分子変換 (written in Japanese)
- 大村智通、杉野目道紀
- ケイ素化学協会誌 2020, 37, 40-49.

Holding of planar chirality of pillar[5]arene by kinetic trapping using host–guest interactions with achiral guest solvents
- Yuuya Nagata, Misaki Suzuki, Yasuo Shimada, Hiroki Sengoku, Shungo Nishida, Takahiro Kakuta, Tadaaki Yamagishi, Michinori Suginome, Tomoki Ogoshi
- Chem. Commun., 2020, 56, 8424-8427, 10.1039/d0cc03413d

Stereoinvertive C−C Bond Formation at the Boron‐Bound Stereogenic Centers via Copper–Bipyridine‐Catalyzed Intramolecular Coupling of α‐Aminobenzylboronic Esters
- Yukako Yoshinaga, Takeshi Yamamoto, Michinori Suginome
- Angew. Chem. Int. Ed., 2020, 59, 7251-7255, 10.1002/anie.201914864
Construction of Silicon-Containing Seven-Membered Rings by Catalytic [4+2+1] Cycloaddition through Rhodium Silylenoid
- Ikuo Sasaki, Toshimichi Ohmura, and Michinori Suginome
- Org. Lett., 2020, 22, 2961-2966, 10.1021/acs.orglett.0c00690

Tandem C–H Activation by a Single Iridium Catalyst: Direct Access to Indoles and Indolines from o-Alkyl-N-methylanilines
- Toshimichi Ohmura, Kaito Yagi, Satoshi Kusaka, and Michinori Suginome
- ACS Catal., 2020, 10, 3152-3157, 10.1021/acscatal.9b05579

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2019 †

4,4’-Bipyridyl-catalyzed Reduction of Nitroarenes by Bis(neopentylglycolato)diboron
- Hiromu Hosoya, Luis C. Misal Castro, Ibrahim Sultan, Yumiko Nakajima, Toshimichi Ohmura, Kazuhiko Sato, Hayato Tsurugi, Michinori Suginome, and Kazushi Mashima
- Org. Lett., 2019, 21, 9812-9817, 10.1021/acs.orglett.9b03419

Iridium-Catalyzed C(sp3)–H Addition of Methyl Ethers across Intramolecular Carbon–Carbon Double Bonds Giving 2,3-Dihydrobenzofurans
- Toshimichi Ohmura, Satoshi Kusaka, Takeru Torigoe, and Michinori Suginome
- Adv. Synth. Catal., 2019, 361, 4448-4453, 10.1002/adsc.201900749
- Selected as Very Important Publication (VIP)
- One of the Fifteen Most Accessed Articles (ASC, Sep. 2019)

Boryl-Directed, Ir-Catalyzed C(sp3)–H Borylation of Alkylboronic Acids Leading to Site-Selective Synthesis of Polyborylalkanes
- Takeshi Yamamoto, Aoi Ishibashi, and Michinori Suginome
- Org. Lett., 2019, 21, 6235-6240, 10.1021/acs.orglett.9b02112

Asymmetric Catalysis in Chiral Solvents: Chirality Transfer with Amplification of Homochirality through a Helical Macromolecular Scaffold
- Yuuya Nagata, Ryohei Takeda, and Michinori Suginome
- ACS Cent. Sci., 2019, 5, 1235-1240, 10.1021/acscentsci.9b00330

Pyridine-Based Organocatalysts for Regioselective syn-1,2-Silaboration of Terminal Alkynes and Allenes
- Yohei Morimasa, Kosuke Kabasawa, Toshimichi Ohmura, and Michinori Suginome
- Asian J. Org. Chem., 2019, 8, 1092-1096, 10.1002/ajoc.201900176
- Special Issue: Heterocyclic Chemistry

Lyotropic Liquid Crystallinity of Linear and Star Poly(quinoxaline-2,3-diyl)s: Isotropic-Liquid Crystal Phase Equilibria in Tetrahydrofuran
- Hirokazu Hasegawa, Ken Terao, Takahiro Sato, Yuuya Nagata, and Michinori Suginome
- Macromolecules, 2019, 52, 3158-3164, 10.1021/acs.macromol.9b00460

Telechelic Helical Poly(quinoxaline-2,3-diyl)s Containing a Structurally Defined, Circularly Polarized Luminescent Terquinoxaline Core: Synthesis by Core-Initiated Bidirectional Living Polymerization
- Shogo Kuriyama, Yuuya Nagata, and Michinori Suginome
- ACS Macro Lett., 2019, 8, 479-485, 10.1021/acsmacrolett.9b00165

Catalytic Generation of Rhodium Silylenoid for Alkene-Alkyne-Silylene [2+2+1] Cycloaddition
- Toshimichi Ohmura, Ikuo Sasaki, and Michinori Suginome
- Org. Lett., 2019, 21, 1649-1653, 10.1021/acs.orglett.9b00326

Helical Poly(quinoxaline‐2,3‐diyl)s Bearing 1,2,3‐Triazole Pendants: Synthesis by CuAAC and Use as Reusable Abnormal NHC Ligands in Gold Catalysis
- Pinglu Zhang, Takeshi Yamamoto, and Michinori Suginome
- ChemCatChem, 2019, 11, 424-429, 10.1002/cctc.201801361

A bidirectional screw‐sense induction of poly(quinoxaline‐2,3‐diyl)s that depends on the degree of polymerization
- Yuuya Nagata, Tsuyoshi Nishikawa, Ken Terao, Hirokazu Hasegawa, and Michinori Suginome
- J. Polym. Sci. Part A: Polym. Chem., 2019, 57, 260-263, 10.1002/pola.29224
- This manuscript is dedicated to Professor Mitsuo Sawamoto's outstanding achievements in polymer chemistry and recognizes his recent retirement from 40 years of exceptional service to Kyoto University.
  - https://onlinelibrary.wiley.com/toc/10990518/2019/57/3

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2018 †

鈴木-宮浦カップリング　ノーベル賞後の新展開 (written in Japanese)
- 大村智通
- 化学 2018, 73 (8), 29-32.

A Planar-Chiral Pillar[5]arene-Based Monophosphine Ligand with Induced Chirality at the Biaryl Axis
- Yuuya Nagata, Yasuo Shimada, Tsuyoshi Nishikawa, Ryohei Takeda, Makoto Uno, Tomoki Ogoshi, and Michinori Suginome
- Synlett, 2018, 29, 2167-2170, 10.1055/s-0037-1610635
- This article has been published in SYNLETT issue 16/2018 in the cluster section, "Atropisomerism - in Memoriam Kurt Mislow".
- This article was selected for the cover of SYNLETT.

Enantiospecific Suzuki-Miyaura Coupling of Nonbenzylic α-(Acylamino)alkylboronic Acid Derivatives
- Toshimichi Ohmura, Kyoko Miwa, Tomotsugu Awano, and Michinori Suginome
- Chem. Asian J., 2018, 13, 2414–2417, 10.1002/asia.201800536
- Special Issue: Homogeneous Catalysis from Young Investigators in Asia
- Highlighted in Synfacts, 2018, 14, 1264, 10.1055/s-0037-16110113

Abnormal Sergeants-and-Soldiers Effect of Poly(quinoxaline-2,3-diyl)s Enabling Discrimination of One-Carbon Homologous n-Alkanes through a Highly Sensitive Solvent-dependent Helix Inversion
- Yuuya Nagata, Tsuyoshi Nishikawa, and Michinori Suginome
- Chem. Comm., 2018, 54, 6867-6870, 10.1039/C8CC02836B
- This article is part of the themed collection: 2018 Emerging Investigators

Chirality-Amplifying, Dynamic Induction of Single-Handed Helix by Chiral Guests to Macromolecular Chiral Catalysts Bearing Boronyl Pendants as Receptor Sites
- Takeshi Yamamoto, Ryo Murakami, Satoko Komatsu, and Michinori Suginome
- J. Am. Chem. Soc., 2018, 140, 3867-3870, 10.1021/jacs.8b00529

Elucidating the Solvent Effect on the Switch of the Helicity of Poly(quinoxaline-2,3-diyl)s: A Conformational Analysis by Small-Angle Neutron Scattering
- Yuuya Nagata, Tsuyoshi Nishikawa, Michinori Suginome, Sota Sato, Masaaki Sugiyama, Lionel Porcar, Anne Martel, Rintaro Inoue, and Nobuhiro Sato
- J. Am. Chem. Soc., 2018, 140, 2722-2726, 10.1021/jacs.7b11626
  - 京都大学からのプレスリリースはこちらです
  - 日経プレスリリースにて紹介されました
  - 日刊工業新聞（2018年2月16日, 27面）にて紹介されました
  - 京都新聞（2018年2月21日, 25面）にて紹介されました。

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2017 †

Palladium-Catalyzed β-Elimination of Aminoboranes from (Aminomethylsilyl)boranes Leading to the Formation of Silene Dimers
- Toshimichi Ohmura, Hiroki Nishiura, and Michinori Suginome
- Organometallics, 2017, 36, 4298–4304, 10.1021/acs.organomet.7b00695

4,4'-Bipyridine-Catalyzed Stereoselective trans-Diboration of Acetylenedicarboxylates to 2,3-Diborylfumarates
- Toshimichi Ohmura, Yohei Morimasa, and Michinori Suginome
- Chem. Lett., 2017, 46, 1793–1796, 10.1246/cl.170848 (Open Access)

Asymmetric Cycloisomerization of o-Alkenyl-N-methylanilines to Indolines through Iridium-Catalyzed C(sp3)–H Addition to Carbon–Carbon Double Bonds
- Takeru Torigoe, Toshimichi Ohmura, and Michinori Suginome
- Angew. Chem. Int. Ed., 2017, 56, 14272–14276, 10.1002/anie.201708578
- One of the Fifteen Most Accessed Articles (ACIE, Oct. 2017)
- Selected as Synfact of the month (Jan. 2018), Synfacts, 2018, 14, 0039, 10.1055/s-0036-1591055

Synthesis and Solution Properties of a Rigid Helical Star Polymer: Three-Arm Star Poly(quinoxaline-2,3-diyl)
- Hirokazu Hasegawa, Yuuya Nagata, Ken Terao, and Michinori Suginome
- Macromolecules, 2017, 50, 7491–7497, 10.1021/acs.macromol.7b01797

Chirality-Switchable 2,2'-Bipyridine Ligands Attached to Helical Poly(quinoxaline-2,3-diyl)s for Copper-Catalyzed Asymmetric Cyclopropanation of Alkenes
- Yukako Yoshinaga, Takeshi Yamamoto, and Michinori Suginome
- ACS Macro Lett., 2017, 6, 705–710, 10.1021/acsmacrolett.7b00352

Rhodium-Catalyzed C(sp2)–H Addition of Arylboronic Acids to Alkynes Using a Boron-Based, Convertible ortho-Directing Group
- Takeshi Yamamoto, Aoi Ishibashi, and Michinori Suginome
- Chem. Lett., 2017, 46, 1169-1172, 10.1246/cl.170404

キラル側鎖による高分子らせんキラリティーの動的誘起に基づいた新しいキラル機能開拓
- 杉野目道紀, 長田裕也, 山本武司
- 有機合成化学協会誌, 2017, 5, 476-490, 10.5059/yukigoseikyokaishi.75.476

Synthesis and Catalytic Applications of a Triptycene-Based Monophosphine Ligand for Palladium-Mediated Organic Transformations
- Franco King-Chi Leung, Fumitaka Ishiwari, Yoshiaki Shoji, Tsuyoshi Nishikawa, Ryohei Takeda, Yuuya Nagata, Michinori Suginome, Yasuhiro Uozumi, Yoichi M. A. Yamada, and Takanori Fukushima
- ACS Omega, 2017, 2, 1930-1937, 10.1021/acsomega.7b00200

Poly(quinoxaline-2,3-diyl) as a Multifunctional Chiral Scaffold for Circularly Polarized Luminescent Materials: Color Tuning, Energy Transfer, and Switching of the CPL Handedness
- Tsuyoshi Nishikawa, Yuuya Nagata, and Michinori Suginome
- ACS Macro Lett., 2017, 6, 431–435, 10.1021/acsmacrolett.7b00131

Utilization of a Trimethylsilyl Group as a Synthetic Equivalent of a Hydroxyl Group via Chemoselective C(sp3)–H Borylation at the Methyl Group on Silicon
- Takeru Torigoe, Toshimichi Ohmura, and Michinori Suginome
- J. Org. Chem., 2017, 82, 2943–2956, 10.1021/acs.joc.6b02917

C–H Activation-Based Transformation of Naphthalenes to 3-Iodo-2-naphthylboronic Acid Derivatives for Use in Iterative Coupling Synthesis of Helical Oligo(naphthalene-2,3-diyl)s
- Takeshi Yamamoto, Aoi Ishibashi, Masashi Koyanagi, Hideki Ihara, Nils Eichenauer, and Michinori Suginome
- Bull. Chem. Soc. Jpn., 2017, 90, 604-606, 10.1246/bcsj.20170026

Single-Handed Helical Poly(quinoxaline-2,3-diyl)s Bearing Achiral 4-Aminopyrid-3-yl Pendants as Highly Enantioselective, Reusable Chiral Nucleophilic Organocatalysts in the Steglich Reaction
- Takeshi Yamamoto, Ryo Murakami, and Michinori Suginome
- J. Am. Chem. Soc., 2017, 139, 2557–2560, 10.1021/jacs.6b12349

Regioselective Synthesis of o-Benzenediboronic Acids via Ir-Catalyzed o-C–H Borylation Directed by a Pyrazolylaniline-Modified Boronyl Group
- Takeshi Yamamoto, Aoi Ishibashi, and Michinori Suginome
- Org. Lett., 2017, 19, 886–889, 10.1021/acs.orglett.7b00041

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2016 †

High-Pressure Circular Dichroism Spectroscopy up to 400 MPa Using Polycrystalline Yttrium Aluminum Garnet (YAG) as Pressure-Resistant Optical Windows
- Yuuya Nagata, Ryohei Takeda, and Michinori Suginome
- RSC Adv., 2016, 6, 109726-109729, 10.1039/C6RA23736C

Iridium-Catalyzed Intramolecular Methoxy C–H Addition to Carbon–Carbon Triple Bonds: Direct Synthesis of 3-Substituted Benzofurans from o-Methoxyphenylalkynes
- Takeru Torigoe, Toshimichi Ohmura, and Michinori Suginome
- Chem. Eur. J., 2016, 22, 10415–10419, 10.1002/chem.201602152

Three-Way-Switchable (Right/Left/OFF) Selective Reflection of Circularly Polarized Light on Solid Thin Films of Helical Polymer Blends
- Yuuya Nagata, Makoto Uno, and Michinori Suginome
- Angew. Chem., Int. Ed, 2016, 55, 7126–7130, 10.1002/anie.201602035

A (Borylmethyl)silane Bearing Three Hydrolyzable Groups on Silicon: Synthesis via Iridium-Catalyzed C(sp3)–H Borylation and Conversion to Functionalized Siloxanes
- Toshimichi Ohmura, Ikuo Sasaki, Takeru Torigoe, and Michinori Suginome
- Organometallics, 2016, 35, 1601–1603, 10.1021/acs.organomet.6b00316

Solvent Effect on the Sergeants-and-Soldiers Effect Leading to Bidirectional Induction of Single-Handed Helical Sense of Poly(quinoxaline-2,3-diyl)s Copolymers in Aromatic Solvents
- Yuuya Nagata, Tsuyoshi Nishikawa, and Michinori Suginome
- ACS Macro Lett., 2016, 5, 519–522, 10.1021/acsmacrolett.6b00191

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2015 †

Poly(quinoxaline-2,3-diyl)s: A Fascinating Helical Macromolecular Scaffold for New Chiral Functions
- Michinori Suginome, Takeshi Yamamoto, and Yuuya Nagata
- J. Synth. Org. Chem. Jpn. 2015, 73, 1141-1155, 10.5059/yukigoseikyokaishi.73.1141

Main-Chain Stiffness and Helical Conformation of a Poly(quinoxaline-2,3-diyl) in Solution
- Yuuya Nagata, Hirokazu Hasegawa, Ken Terao, and Michinori Suginome
- Macromolecules, 2015, 48, 7983–7989. 10.1021/acs.macromol.5b01919

Majority-Rules-Type Helical Poly(quinoxaline-2,3-diyl)s as Highly Efficient Chirality-Amplification Systems for Asymmetric Catalysis
- Yuan-Zhen Ke, Yuuya Nagata, Tetsuya Yamada, and Michinori Suginome
- Angew. Chem., Int. Ed, 2015, 54, 9333–9337. 10.1002/anie.201502209

Pressure-dependent Helix Inversion of Poly(quinoxaline-2,3-diyl)s Containing Chiral Side Chains in Non-aqueous Solvents
- Yuuya Nagata, Ryohei Takeda, and Michinori Suginome
- Chem. Commun., 2015, 51, 11182-11185, 10.1039/C5CC04255K (Open Access)

Site- and Regioselective Silaborative C–C Cleavage of 1-Alkyl-2-Methylenecyclopropanes Using a Platinum Catalyst with a Sterically Demanding Silylboronic Ester
- Toshimichi Ohmura, Hiroki Taniguchi, and Michinori Suginome
- ACS Catal., 2015, 5, 3074–3077, 10.1021/acscatal.5b00513

Asymmetric Suzuki–Miyaura cross-coupling of 1-bromo-2-naphthoates using the helically chiral polymer ligand PQXphos
- Yuto Akai, Laure Konnert, Takeshi Yamamoto and Michinori Suginome
- Chem. Commun., 2015, 51, 7211–7214, 10.1039/C5CC01074H

Exerting Control over the Helical Chirality in the Main-Chain of Sergeants-and-Soldiers-Type Poly(quinoxaline-2,3-diyl)s by Changing from Random to Block Copolymerization Protocols
- Yuuya Nagata, Tsuyoshi Nishikawa, and Michinori Suginome
- J. Am. Chem. Soc., 2015, 137, 4070–4073, 10.1021/jacs.5b01422

Organocatalytic Diboration Involving “Reductive Addition” of a Boron–Boron σ-Bond to 4,4’-Bipyridine
- Toshimichi Ohmura, Yohei Morimasa, and Michinori Suginome
- J. Am. Chem. Soc., 2015, 137, 2852–2855, 10.1021/jacs.5b00546
- Highlighted in JACS Spotlights 10.1021/jacs.5b02133
- Highlighted in Virtual Issue Posts on Organocatalysis http://pubs.acs.org/page/vi/organocatalysis

Facile Preparation of Poly(quinoxaline-2,3-diyl)s via Aromatizing Polymerization of 1,2-Diisocyanobenenes Using Phosphine Complexes of Nickel(II) Salts
- Yuuya Nagata, Yuan-Zhen Ke, and Michinori Suginome
- Chem. Lett, 2015, 44, 53–55, 10.1246/cl.140909

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2014 †

Poly(quinoxaline-2,3-diyl)s Bearing (S)-3-Octyloxymethyl Side Chains as an Efficient Amplifier of Alkane Solvent Effect Leading to Switch of Main Chain Helical Chirality
- Yuuya Nagata, Tsuyoshi Nishikawa, and Michinori Suginome
- J. Am. Chem. Soc., 2014, 136, 15901–15904, 10.1021/ja509531t
- Highlighted in JACS Spotlights 10.1021/ja511738n

Chiral Palladacycle Catalysts Generated on a Single-Handed Helical Polymer Skeleton for Asymmetric Arylative Ring Opening of 1,4-Epoxy-1,4-dihydronaphthalene
- Takeshi Yamamoto, Yuto Akai, and Michinori Suginome
- Angew. Chem., Int. Ed, 2014, 53, 12785–12788.

Ether Solvent-induced Chirality Inversion of Helical Poly(quinoxaline-2,3-diyl)s Containing L-Lactic Acid Derived Side Chains
- Yuuya Nagata, Takuma Kuroda, Keisuke Takagi, and Michinori Suginome
- Chem. Sci., 2014, 5, 4953-4956, 10.1039/C4SC01920B

Chirality-switchable Circularly Polarized Luminescence in Solution Based on the Solvent-dependent Helix Inversion of Poly(quinoxaline-2,3-diyl)s
- Yuuya Nagata, Tsuyoshi Nishikawa, and Michinori Suginome
- Chem. Commun., 2014, 50, 9951-9953, 10.1039/C4CC03944K

Solid Polymer Films Exhibiting Handedness-switchable, Full-color-tunable Selective Reflection of Circularly Polarized Light
- Yuuya Nagata, Keisuke Takagi, and Michinori Suginome
- J. Am. Chem. Soc., 2014, 136, 9858–9861, 10.1021/ja504808r
- Highlighted in JACS Spotlights 10.1021/ja506476x

Iridium-Catalysed Borylation of Sterically Hindered C(sp3)–H bonds: Remarkable Rate Acceleration by a Catalytic Amount of Potassium tert-Butoxide
- Toshimichi Ohmura, Takeru Torigoe, and Michinori Suginome
- Chem. Commun., 2014, 50, 6333-6336, 10.1039/C4CC01262C

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2013 †

Nickel-Catalyzed Cyclizative trans-Carboboration of Alkynes through Activation of Boron–Chlorine Bonds by Using Organometallic Reagents as Donors of Organic Groups
- Masaki Daini, Akihiko Yamamoto, and Michinori Suginome
- Asian J. Org. Chem., 2013, 2, 968-976, 10.1002/ajoc.201300164

Functionalization of Tetraorganosilanes and Permethyloligosilanes at a Methyl Group on Silicon via Iridium Catalyzed C(sp3)–H Borylation
- Toshimichi Ohmura, Takeru Torigoe, and Michinori Suginome
- Organometallics 2013, 32, 6170-6173, 10.1021/om400900z

Complementary Induction of Right- and Left-Handed Helical Structures by the Positioning of Chiral Groups on the Monomer Units: Introduction of (−)-Menthol as Side Chains of Poly(quinoxaline-2,3-diyl)s
- Takeshi Yamamoto, Takumi Adachi, and Michinori Suginome
- ACS Macro Lett., 2013, 2, 790-793, 10.1021/mz4003326

Catalytic Borylation and Silylation of Unsaturated Organic Molecules: Reaction Control by Transition Metal Catalysts and Applications to Organic Synthesis (written in Japanese)
- Toshimichi Ohmura
- J. Synth. Org. Chem. Jpn. 2013, 71, 804-817, 10.5059/yukigoseikyokaishi.71.804

Cycloaddition-based Formal C–H Alkynylation of Isoindoles Leading to the Synthesis of Air-stable Fluorescent 1,3-Dialkynylisoindoles
- Toshimichi Ohmura, Akihito Kijima, Yusuke Komori, and Michinori Suginome
- Org. Lett. 2013, 15, 3510–3513, 10.1021/ol401051d

Solvent-Dependent Switch of Helical Main-Chain Chirality in Sergeants-and-Soldiers-Type Poly(quinoxaline-2,3-diyl)s: Effect of the Position and Structures of the “Sergeant” Chiral Units on the Screw-Sense Induction
- Yuuya Nagata, Tetsuya Yamada, Takumi Adachi, Yuto Akai, Takeshi Yamamoto, and Michinori Suginome
- J. Am. Chem. Soc., 2013, 135, 10104–10113, 10.1021/ja403391m

Catalytic Asymmetric Synthesis with Chirality-Switchable Helical Polymer Ligands
- Takeshi Yamamoto, Yuuya Nagata, and Michinori Suginome
- J. Synth. Org. Chem. Jpn., 2013, 71, 461-471, 10.5059/yukigoseikyokaishi.71.461 (Japanese)
- YamamotoSOCJ.png

Anthranilamide-masked o-Iodoarylboronic Acids as Coupling Modules for Iterative Synthesis of ortho-Linked Oligoarenes
- Masashi Koyanagi, Nils Eichenauer, Hideki Ihara, Takeshi Yamamoto, and Michinori Suginome
- Chem. Lett., 2013, 42, 541-543, 10.1246/cl.130136

Palladium-catalyzed Carboboration: Borylative Coupling of Alkynes with Alkenes through Activation of Boron Chlorine Bonds
- Kanayo Nakada, Masaki Daini, and Michinori Suginome
- Chem. Lett., 2013, 42, 538-540, 10.1246/cl.130131

Synthesis of Cyclic Alkenylborates via Silaboration of Alkynes Followed by Hydrolysis for Utilization in External-Base-Free Cross Coupling
- Toshimichi Ohmura, Kazuyuki Oshima, and Michinori Suginome
- Organometallics 2013, 32, 2870-2873, 10.1021/om400138u

↑

2012 †

Arylboronic Acid Derivative Cross-Coupling Reactions
- Michinori Suginome and Toshimichi Ohmura
- Science of Synthesis Cross Coupling and Heck-Type Reactions 1, G. A. Molander Ed., Thieme, 2012, 147-201

Catalytic Functionalization of Methyl Group on Silicon: Iridium-Catalyzed C(sp3)–H Borylation of Methylchlorosilanes
- Toshimichi Ohmura, Takeru Torigoe, and Michinori Suginome
- J. Am. Chem. Soc. 2012, 134, 17416-17419, 10.1021/ja307956w

Solvent-dependent fluorescence and circular dichroism properties of poly(quinoxaline-2,3-diyl)s bearing pyrene pendants
- Yuuya Nagata, Tsuyoshi Nishikawa, and Michinori Suginome
- Chem. Commun., 2012, 48, 11193-11195, 10.1039/C2CC36275A

Catalytic Asymmetric Synthesis Using Chirality-Switchable Helical Polymer as a Chiral Ligand
- Michinori Suginome,Takeshi Yamamoto, Yuuya Nagata, Tetsuya Yamada, and Yuto Akai
- Pure Appl. Chem., 2012, 84, 1759-1769, 10.1351/PAC-CON-11-08-23

Dearomatizing conversion of pyrazines to 1,4-dihydropyrazine derivatives via transition-metal-free diboration, silaboration, and hydroboration
- Kazuyuki Oshima, Toshimichi Ohmura, and Michinori Suginome
- Chem. Commun. 2012, 48, 8571-8573, 10.1039/C2CC34086K

Enhanced Catalyst Activity and Enantioselectivity with Chirality-Switchable Polymer Ligand PQXphos in Pd-Catalyzed Asymmetric Silaborative Cleavage of meso-Methylenecyclopropanes
- Yuto Akai, Takeshi Yamamoto, Yuuya Nagata, Toshimichi Ohmura, and Michinori Suginome
- J. Am. Chem. Soc., 2012, 134, 11092-11095, 10.1021/ja303506k

Regioselective Synthesis of 1,2-Dihydropyridines by Rhodium-Catalyzed Hydroboration of Pyridines
- Kazuyuki Oshima, Toshimichi Ohmura, and Michinori Suginome
- J. Am. Chem. Soc. 2012, 134, 3699-3702, 10.1021/ja3002953

Control of Helical Chirality of Poly(quinoxaline-2,3-diyl)s Based on Postpolymerization Modification of the Terminal Group by Small Chiral Molecules
- Yuuya Nagata, Satoru Ohashi, and Michinori Suginome
- J. Polym. Sci. Part A: Polym. Chem., 2012, 50, 1564–1571, 10.1002/pola.25926
- Selected as Cover Image, 10.1002/pola.26030

↑

2011 †

1,3,2-Dioxaborolane, 2-(dimethylphenylsilyl)-4,4,5,5-tetramethyl-
- Toshimichi Ohmura and Michinori Suginome
- Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, P. L. Fuchs Ed., Wiley, 2011, 270-276

Transition Metal-Catalyzed Element-Boryl Additions to Unsaturated Organic Compounds
- Michinori Suginome and Toshimichi Ohmura
- Boronic Acids Second Edition, D. G. Hall Ed., Wiley, 2011, Vol 1, 171-212

Inversion or Retention? Effects of Acidic Additives on the Stereochemical Course in Enantiospecific Suzuki–Miyaura Coupling of α-(Acetylamino)benzylboronic Esters
- Tomotsugu Awano, Toshimichi Ohmura, and Michinori Suginome
- J. Am. Chem. Soc. 2011, 133, 20738-20741, 10.1021/ja210025q

(E)- and (Z)-β-Borylallylsilanes via Alkyne Silaboration Followed by Regio- and Stereoselective Double Bond Migration
- Toshimichi Ohmura, Kazuyuki Oshima, and Michinori Suginome
- Angew. Chem. Int. Ed. 2011, 50, 12501–12504, 10.1002/anie.201106077

Highly Enantioselective Synthesis of Axially Chiral Biarylphosphonates: Asymmetric Suzuki–Miyaura Coupling Using High-Molecular-Weight, Helically Chiral Polyquinoxaline-Based Phosphines
- Takeshi Yamamoto, Yuto Akai, Yuuya Nagata, and Michinori Suginome
- Angew. Chem., Int. Ed, 2011, 50, 8844–8847, 10.1002/anie.201103792

Synthesis of poly(quinoxaline-2,3-diyl)s with alkoxy side chains by aromatizing polymerization of 4,5-dialkoxy-substituted 1,2-diisocyanobenzenes
- Yuuya Nagata and Michinori Suginome
- J. Polym. Sci. Part A: Polym. Chem., 2011, 49, 4275–4282, 10.1002/pola.24871

Ruthenium-Catalyzed C–H-Silylation of Methylboronic Acid Using a Removable α-Directing Modifier on the Boron Atom
- Hideki Ihara, Akinori Ueda, and Michinori Suginome
- Chem. Lett., 2011, 40, 916–918, 10.1246/cl.2011.916

Dinuclear Palladium and Platinum Complexes with Bridging Silylene Ligands. Preparation Using (Aminosilyl)boronic Ester as the Ligand Precursor and Their Reactions with Alkynes
- Makoto Tanabe, Jian Jiang, Hideto Yamazawa, Kohtaro Osakada, Toshimichi Ohmura, and Michinori Suginome
- Organometallics 2011, 30, 3981-3991, 10.1021/om200156g

Anthranilamide: A Simple, Removable Ortho-Directing Modifier for Arylboronic Acids Serving also as a Protective Group in Cross-Coupling Reactions
- Hideki Ihara, Masashi Koyanagi, and Michinori Suginome
- Org. Lett., 2011, 13, 2662-2665, 10.1021/ol200764g

Palladium-Catalyzed Regioselective Silaboration of Pyridines Leading to the Synthesis of Silylated Dihydropyridines
- Kazuyuki Oshima, Toshimichi Ohmura, and Michinori Suginome
- J. Am. Chem. Soc. 2011, 133, 7324-7327, 10.1021/ja2020229

Palladium-Catalyzed, Stereoselective, Cyclizative Alkenylboration of Carbon−Carbon Double Bonds through Activation of a Boron−Chlorine Bond
- Masaki Daini and Michinori Suginome
- J. Am. Chem. Soc., 2011, 133, 4758-4761, 10.1021/ja200856t

2-Vinylindoles As the Four-Atom Component in a Catalytic [4+1] Cycloaddition with a Silylene-Palladium Species Generated from (Aminosilyl)boronic Ester
- Kohei Masuda, Toshimichi Ohmura, and Michinori Suginome
- Organometallics 2011, 30, 1322-1325, 10.1021/om200135u

Integrated Catalytic C−H Transformations for One-Pot Synthesis of 1-Arylisoindoles from Isoindolines via Palladium-Catalyzed Dehydrogenation Followed by C−H Arylation
- Toshimichi Ohmura, Akihito Kijima, and Michinori Suginome
- Org. Lett. 2011, 13, 1238-1241, 10.1021/ol2001232

↑

2010 †

Catalytic carboborations
- Michinori Suginome
- Chem. Rec. 2010, 10, 348–358, 10.1002/tcr.201000029

Stereospecific Suzuki-Miyaura Coupling of Chiral α-(Acylamino)benzylboronic Esters with Inversion of Configuration
- Toshimichi Ohmura, Tomotsugu Awano, and Michinori Suginome
- J. Am. Chem. Soc. 2010, 132, 13191-13193, 10.1021/ja106632j

Switch of Regioselectivity in Palladium-Catalyzed Silaboration of Terminal Alkynes by Ligand-Dependent Control of Reductive Elimination
- Toshimichi Ohmura, Kazuyuki Oshima, Hiroki Taniguchi, and Michinori Suginome
- J. Am. Chem. Soc. 2010, 132, 12194-12196, 10.1021/ja105096r

Non-hydrogen-bonding-based, solvent-dependent helix inversion between pure P-helix and pure M-helix in poly(quinoxaline-2,3-diyl)s bearing chiral side chains
- Tetsuya Yamada, Yuuya Nagata and Michinori Suginome
- Chem. Commun. 2010, 46, 4914-4916, 10.1039/c001564d

High-Molecular-Weight Polyquinoxaline-Based Helically Chiral Phosphine (PQXphos) as Chirality-Switchable, Reusable, and Highly Enantioselective Monodentate Ligand in Catalytic Asymmetric Hydrosilylation of Styrenes
- Takeshi Yamamoto, Tetsuya Yamada, Yuuya Nagata and Michinori Suginome
- J. Am. Chem. Soc. 2010, 132, 7899–7901, 10.1021/ja102428q

Rhodium-catalyzed Dehydroborylation of Styrenes with Naphthalene-1,8-diaminatoborane [(dan)BH]: New Synthesis of Masked β-Borylstyrenes as New Phenylene–Vinylene Cross-coupling Modules
- Noriyuki Iwadate and Michinori Suginome
- Chem. Lett. 2010, 39, 558-560, 10.1246/cl.2010.558

Nickel-Catalyzed Asymmetric Addition of Alkyne C-H Bonds across 1,3-Dienes Using Taddol-Based Chiral Phosphoramidite Ligands
- Masamichi Shirakura and Michinori Suginome
- Angew. Chem. Int. Ed. 2010, 49, 3827-3829, 10.1002/anie.201001188

Synthesis of Helical Rod−Coil Multiblock Copolymers by Living Block Copolymerization of Isocyanide and 1,2-Diisocyanobenzene Using Arylnickel Initiators
- Tetsuya Yamada and Michinori Suginome
- Macromolecules 2010, 43, 3999-4002, 10.1021/ma100500r

Langmuir–Blodgett films of helical rigid-rod poly(quinoxaline-2,3-diyl)s
- Yoshihiko Ito, Toshiyuki Miyake, Michinori Suginome, Rie Katakura, Masaya Mitsuishi, and Tokuji Miyashita
- Polym. J. 2010, 42, 406-410, 10.1038/pj.2010.14

触媒的ヒドロホウ素化の新展開：銅および鉄触媒の利用
- 大村智通
- Organometallic News 2010, 28, 28-28

Differentially Protected Diboron for Regioselective Diboration of Alkynes: Internal-Selective Cross-Coupling of 1-Alkene-1,2-diboronic Acid Derivatives
- Noriyuki Iwadate and Michinori Suginome
- J. Am. Chem. Soc. 2010, 132, 2548-2549, 10.1021/ja1000642

Chiral Arylnickel Complexes as Highly Active Initiators for Screw-Sense Selective Living Polymerization of 1,2-Diisocyanobenzenes
- Tetsuya Yamada, Hiroyoshi Noguchi, Yuuya Nagata, and Michinori Suginome
- J. Polym. Sci. Part A: Polym. Chem. 2010, 48, 898-904, 10.1002/pola.23842

↑

2009 †

Palladium-Catalyzed Silylene-1,3-Diene [4 + 1] Cycloaddition with Use of (Aminosilyl)boronic Esters as Synthetic Equivalents of Silylene
- Toshimichi Ohmura, Kohei Masuda, Ichiro Takase, and Michinori Suginome
- J. Am. Chem. Soc. 2009, 131, 16624-16625, 10.1021/ja907170p

Nickel-Catalyzed Ring-Opening Hydroacylation of Methylenecyclopropanes: Synthesis of γ,δ-Unsaturated Ketones from Aldehydes
- Hiroki Taniguchi, Toshimichi Ohmura, and Michinori Suginome
- J. Am. Chem. Soc. 2009, 131, 11298-11299, 10.1021/ja9046894

Kinetic Resolution of Racemic 1-Alkyl-2-methylenecyclopropanes via Palladium-Catalyzed Silaborative C–C Cleavage
- Toshimichi Ohmura, Hiroki Taniguchi, and Michinori Suginome
- Org. Lett. 2009, 11, 2880-2883, 10.1021/ol900829c

Easily Attachable and Detachable ortho-Directing Agent for Arylboronic Acids in Ruthenium-Catalyzed Aromatic C−H Silylation
- Hideki Ihara and Michinori Suginome
- J. Am. Chem. Soc. 2009, 131, 7502-7503, 10.1021/ja902314v

α-Amidobenzylation of Aryl and Alkenyl Halides via Palladium-catalyzed Suzuki-Miyaura Coupling with α-(Acylamino)benzylboronic Esters
- Toshimichi Ohmura, Tomotsugu Awano, and Michinori Suginome
- Chem. Lett. 2009, 38, 664-665, 10.1246/cl.2009.664

Palladium-catalyzed intramolecular cyanoboration of allenes leading to the regioselective synthesis of β-cyanoallylboranes
- Akihiko Yamamoto, Yuto Ikeda, and Michinori Suginome
- Tetrahedron Lett. 2009, 50, 3168-3170, 10.1016/j.tetlet.2009.01.025

Synthesis of 1-Borylisoindoles via Palladium-Catalyzed Dehydrogenation/C−H Borylation of Isoindolines
- Toshimichi Ohmura, Akihito Kijima and Michinori Suginome
- J. Am. Chem. Soc. 2009, 131, 6070-6071, 10.1021/ja901095h

Synthesis of B-Protected β-Styrylboronic Acids via Iridium-Catalyzed Hydroboration of Alkynes with 1,8-Naphthalenediaminatoborane Leading to Iterative Synthesis of Oligo(phenylenevinylene)s
- Noriyuki Iwadate and Michinori Suginome
- Org. Lett. 2009, 11, 1899-1902, 10.1021/ol9003096

Nickel-Catalyzed, Regio- and Stereoselective Hydroalkynylation of Methylenecyclopropanes with Retention of the Cyclopropane Ring, Leading to the Synthesis of 1-Methyl-1-Alkynylcyclopropanes
- Masamichi Shirakura and Michinori Suginome
- J. Am. Chem. Soc. 2009, 131, 5060-5061, 10.1021/ja900876w

Synthesis of masked haloareneboronic acids via iridium-catalyzed aromatic C–H borylation with 1,8-naphthalenediaminatoborane (danBH)
- Noriyuki Iwadate and Michinori Suginome
- J. Organomet. Chem. 2009, 694, 1713-1717, 10.1016/j.jorganchem.2008.11.068

Stereoselective Synthesis of cis-β-Methyl- and Phenyl-Substituted Alkenylboronates by Platinum-Catalyzed Dehydrogenative Borylation
- Toshimichi Ohmura, Yuta Takasaki, Hideki Furukawa, and Michinori Suginome
- Angew. Chem. Int. Ed. 2009, 48, 2372-2375, 10.1002/anie.200805406

B(OMe)SUB{3}; as a Nonacidic Iminium Ion Generator in Mannich- and Ugi-Type Reactions
- Yusuke Tanaka, Kousuke Hidaka, Tomoaki Hasui, and Michinori Suginome
- Eur. J. Org. Chem. 2009, 8, 1148-1151, 10.1002/ejoc.200801190

Nickel-Catalyzed Regioselective Hydroalkynylation of Styrenes: Improved Catalyst System, Reaction Scope, and Mechanism
- Masamichi Shirakura and Michinori Suginome
- Org. Lett. 2009, 11, 523-526, 10.1021/ol802475h

Silylboranes as New Tools in Organic Synthesis
- Toshimichi Ohmura and Michinori Suginome
- Bull. Chem. Soc. Jpn. 2009, 82, 29-49, 10.1246/bcsj.82.29

Helical Poly(quinoxaline-2,3-diyl)s Bearing Metal-Binding Sites as Polymer-Based Chiral Ligands for Asymmetric Catalysis
- Takeshi Yamamoto and Michinori Suginome
- Angew. Chem. Int. Ed. 2009, 48, 539-542, 10.1002/anie.200803719

↑

2008 †

遷移金属触媒とシリレン等価体による炭素―ケイ素結合形成
- 大村智通、杉野目道紀
- ケイ素化学協会誌, 2008, 25, 32-35

芳香族オリゴマーの自在精密合成に向けた反復鈴木―宮浦カップリング反応
- 杉野目道紀
- 液晶, 2008, 12, 296-305

Palladium-Catalyzed Carboboration of Alkynes Using Chloroborane and Organozirconium Reagents
- Masaki Daini and Michinori Suginome
- Chem. Commun. 2008, 5224-5226, 10.1039/b809433k

Diarylborinic Acid Derivatives as a Catalytic Iminium Ion Generator in the Mannich-Type Reaction Using Secondary Amines, Aldehydes, and Ketene Silyl Acetals
- Yusuke Tanaka, Tomoaki Hasui, Michinori Suginome
- Synlett 2008, 1239-1242, 10.1055/s-2008-1072724

Nickel-Catalyzed Addition of C-H Bonds of Terminal Alkynes to 1,3-Dienes and Styrenes
- Masamichi Shirakura and Michinori Suginome
- J. Am. Chem. Soc. 2008 130, 5410-5411, 10.1021/ja800997j

A Mechanism for the Palladium-Catalyzed Regioselective Silaboration of Allene: A Theoretical Study
- Yoko Abe, Kei Kuramoto, Masahiro Ehara, Hiroshi Nakatsuji, Michinori Suginome, Masahiro Murakami and Yoshihiko Ito
- Organometallics, 2008, 27, 1736-1742, 10.1021/om070110f

イソシアニドの「有機合成化学」と「高分子科学」
- 杉野目道紀
- 高分子, 2008, 57, 130-133

Palladium-Catalysed cis- and trans-Silaboration of Terminal Alkynes: Complementary Access to Stereo-Defined Trisubstituted Alkenes
- Toshimichi Ohmura, Kazuyuki Oshima and Michinori Suginome
- Chem. Comm. 2008, 1416-1418, 10.1039/b800181b

Palladium-Catalyzed trans- and cis-Carboboration of Alkynes Tethered to Chloroborane with Organozirconium Reagents: Ligand-Dependent Complementary Stereoselectivity
- Masaki Daini, Akihiko Yamamoto, and Michinori Suginome
- J. Am. Chem. Soc. 2008, 130, 2918-2919, 10.1021/ja711160h

Synthetic Application of Intramolecular Cyanoboration on the Basis of Removal and Conversion of a Tethering Group by Palladium-Catalyzed Retro-Allylation
- Toshimichi Ohmura, Tomotsugu Awano, Michinori Suginome, Hideki Yorimitsu, and Koichiro Oshima
- Synlett 2008, 423-427, 10.1055/s-2008-1032075

Silylboranes Bearing Dialkylamino Groups on Silicon as Silylene Equivalents: Palladium-Catalyzed Regioselective Synthesis of 2,4-Disubstituted Siloles
- Toshimichi Ohmura, Kohei Masuda, and Michinori Suginome
- J. Am. Chem. Soc. 2008, 130, 1526-1527, 10.1021/ja073896h

Differentially Protected Benzenediboronic Acids: Divalent Cross-Coupling Modules for the Efficient Synthesis of Boron-Substituted Oligoarenes
- Hiroyoshi Noguchi, Takayuki Shioda, Chih-Ming Chou, and Michinori Suginome
- Org. Lett. 2008, 10, 377-380, 10.1021/ol702420x

↑

2007 †

Development of Boron-Based Reactions and Reagents for Organic Synthesis
- Michinori Suginome
- J. Synth. Org. Chem., Jpn. 2007, 65, 1048-1059

Acid-Free, Aminoborane-Mediated Ugi-Type Reaction Leading to General Utilization of Secondary Amines
- Yusuke Tanaka, Tomoaki Hasui, and Michinori Suginome
- Org. Lett. 2007, 9, 4407-4410, 10.1021/ol701570c
Synthesis and Helical Structure of Oligo(quinoline-2,3-diyl)s
- Michinori Suginome, Hiroyoshi Noguchi and Masahiro Murakami
- Chem. Lett. 2007, 36, 1036-1037, 10.1246/cl.2007.1036
Palladium-Catalyzed Asymmetric Silaborative C-C Cleavage of meso-Methylenecyclopropanes
- Toshimichi Ohmura, Hiroki Taniguchi, Yoshiyuki Kondo, and Michinori Suginome
- J. Am. Chem. Soc. 2007, 129, 3518-3519, 10.1021/ja0703170
Synthesis of Silylboronic Esters Functionalized on Silicon
- Toshimichi Ohmura, Kohei Masuda, Hideki Furukawa, Michinori Suginome
- Organometallics 2007, 26, 1291-1294, 10.1021/om0609867
Boron-Masking Strategy for the Selective Synthesis of Oligoarenes via Iterative Suzuki-Miyaura Coupling
- Hiroyoshi Noguchi, Kosho Hojo, Michinori Suginome
- J. Am. Chem. Soc. 2007, 129, 758-759, 10.1021/ja067975p
C-E Bond Formation through Element-Element Addition to Carbon-Carbon Multiple Bonds
- Michinori Suginome, Takanori Matsuda, Toshimichi Ohmura, Atsushi Seki, Masahiro Murakami
- In Comprehensive Organometallic Chemistry III; Crabtree, R. and Mingos, M. Eds.; Ojima, I. Vol. Ed.; Elsevier, 2007; Volume 10, pp 725-787

↑

2006 †

Nickel-Catalyzed Addition of Alkynylboranes to Alkynes
- Michinori Suginome, Masamichi Shirakura, Akihiko Yamamoto
- J. Am. Chem. Soc. 2006, 128, 14438-14439
Palladium-Catalyzed Asymmetric Silaboration of Allenes
- Toshimichi Ohmura, Hiroki Taniguchi, Michinori Suginome
- J. Am. Chem. Soc. 2006, 128, 13682-13683
Ligand-Controlled, Complementary Stereoselectivity in the Platinum-Catalyzed Intramolecular Silaboration of Alkenes
- Toshimichi Ohmura, Hideki Furukawa, Michinori Suginome
- J. Am. Chem. Soc. 2006, 128, 13366-13367
Aminoboranes as New Iminium Ion Generators in Amination Reactions
- Michinori Suginome
- Pure Appl. Chem. 2006, 78, 1377-1387
Reductive amination of aldehydes using aminoboranes as iminium ion generators
- Michinori Suginome, Yusuke Tanaka, Tomoaki Hasui
- Synlett 2006, 1047-1050
Asymmetric Silaboration of Terminal Allenes Bearing α-Stereogenic Centers: Stereoselection Based on "Reagent Control"
- Toshimichi Ohmura, Michinori Suginome
- Org. Lett. 2006, 8, 2503-2506
Reactions of Cyanoboranes with a Palladium-PMeSUB{3}; Complex: Mechanism for the Catalytic Cyanoboration of Alkynes
- Michinori Suginome, Akihiko Yamamoto, Taisuke Sasaki, Masahiro Murakami
- Organometallics 2006, 25, 2911-2913

↑

2005 †

Nickel-Catalyzed trans-Alkynylboration of Alkynes via Activation of a Boron-Chlorine Bond
- Akihiko Yamamoto, Michinori Suginome
- J. Am. Chem. Soc. 2005, 127, 15706-15707

Intramolecular Cyanoboration of Alkynes via Activation of Boron-Cyanide Bonds by Transition Metal Catalysts
- Michinori Suginome, Akihiko Yamamoto, Masahiro Murakami
- J. Organomet. Chem. 2005, 690, 5300-5308

ホウ素で炭素を組み立てる―機能性ホウ素反応剤のデザイン・創製・新反応
- 杉野目道紀
- 化学と工業, 2005, 58, 919-922

有機ケイ素化合物合成の新展開ーC-H結合活性化を利用したC-Si結合形成
- 大村智通、杉野目道紀
- 化学, 2005, 60, 68-69

Stereoselective Synthesis of Highly Enantioenriched (E)-Allylsilanes by Palladium-Catalyzed Intramolecular Bis-Silylation: 1,3-Chirality Transfer and Enantioenrichment via Dimer Formation
- Michinori Suginome, Taisuke Iwanami, Yutaka Ohmori, Akira Matsumoto, Yoshihiko Ito
- Chem. Eur. J. 2005, 11, 2954-2965

Palladium-Catalyzed Addition of Cyanoboranes to Alkynes Leading to Regio- and Stereoselective Synthesis of β-Boryl-α,β-Unsaturated Nitriles
- Michinori Suginome, Akihiko Yamamoto, Masahiro Murakami
- Angew. Chem. Int. Ed. 2005, 44, 2380-2382

Synthesis and Reactions of Cyclic Silylboranes
- Michinori Suginome, Hiroyoshi Noguchi, Tomoaki Hasui, Masahiro Murakami
- Bull. Chem. Soc. Jpn. 2005, 78, 323-326

Synthesis and Structural Analysis of Oligo(naphthalene-2,3-diyl)s
- Takahisa Motomura, Hideko Nakamura, Michinori Suginome, Masahiro Murakami, and Yoshihiko Ito
- Bull. Chem. Soc. Jpn. 2005, 78, 142-146

↑

2004 †

Aminoboranes as "Compatible" Iminium Ion Generators in Aminative C-C Bond Formations
- Michinori Suginome, Lars Uehlin, and Masahiro Murakami
- J. Am. Chem. Soc. 2004, 126, 13196-13197

A New Look at Boron Enolate Chemistry: Aminative C-C Bond Formation Using Diaminoboron Enolate with Aldehyde
- Michinori Suginome, Lars Uehlin, Akihiko Yamamoto, and Masahiro Murakami
- Org. Lett. 2004, 6, 1167-1169.

↑

2003 †

Enantioface-Selective Palladium-Catalyzed Silaboration of Allenes via Double Asymmetric Induction
- Michinori Suginome, Toshimichi Ohmura, Yoshihiro Miyake, Shin’ichirou Mitani, Yoshihiko Ito, Masahiro Murakami
- J. Am. Chem. Soc. 2003, 125, 11174-11175.

Palladium- and Nickel-Catalyzed Intramolecular Cyanoboration of Alkynes
- Michinori Suginome, Akihiko Yamamoto, Masahiro Murakami
- J. Am. Chem. Soc. 2003, 125, 6358-6359.

↑

2002 †

Bis(dialkylamino)cyanoboranes: highly efficient reagents for the Strecker-type aminative cyanation of aldehydes and ketones.
- M. Suginome, A. Yamamoto, Y. Ito
- Chem. Comm. 2002, 1392-1393.

Nickel-Catalyzed Silaboration of Small-Ring Vinylcycloalkanes: Regio- and Stereoselective(E)-Allylsilane Formation via C-C Bond Cleavage.
- M. Suginome, T. Matsuda, T. Yoshimoto, Y. Ito
- Organometallics 2002, 21, 1537-1539.

1,2-Azaboretidine Formation in the Reactions of (Boryl)(silyl)iminomethanes via Possible Generation of (Amino)(boryl)carbene Species
- M. Suginome, T. Fukuda, Y. Ito
- J. Organomet. Chem. 2002, 643-644, 508-511. (Special issue dedicated to Prof. F. Mathey)

Highly Effective, Easily Accessible Screw-Sense-Determining End Group in theAsymmetric Polymerization of 1,2-Diisocyanobenzenes.
- M. Suginome, S. Collet, Y. Ito
- Org. Lett. 2002, 4, 351-354.

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2001 †

Stereoselective construction of trans-1,2-benzooxadecaline frameworks by three-component cascade reactions of an a-phenethyl-b-borylallylsilane with aldehydes
- M. Suginome, Y. Ohmori, Y. Ito
- Chem. Commun. 2001, 1090-1091.

Solid-Phase Synthesis and Asymmetric Reactions of Polymer-Supported Highly Enantioenriched Allylsilanes
- M. Suginome, T. Iwanami, and Y. Ito
- J. Am. Chem. Soc. 2001, 123, 4356-4357.

Asymmetric Synthesis of Cyclic Alkenes via Cyclization of Enantioenriched Allylsilanes
- M. Suginome, T. Iwanami, A. Yamamoto, and Y. Ito
- Synlett 2001, 1042-1045.

β-Borylallylsilanes as a New Tool for Convenient Synthesis of Alkenylboranes
- M. Suginome, Y. Ohmori, and Y. Ito
- J. Am. Chem. Soc. 2001, 123, 4601-4602.

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2000 †

Palladium- and Platinum-Catalyzed Silaboration of Methylenecyclopropanes through Selective Proximal or Distal C-C Bond Cleavage
- M. Suginome, T. Matsuda, and Y. Ito
- J. Am. Chem. Soc. 2000, 122, 11015-11016.

Convenient Preparation of Silylboranes
- M. Suginome, T. Matsuda, and Y. Ito
- Organometallics 2000, 19, 4647-4649.

First Synthesis and Resolution of a Planar-chiral Tetrahydroindolyl Complex of Iron: Electronic Tuning of Reactivity and Enantioselective Nucleophilic Catalysis
- M. Suginome and G. C. Fu
- Chirality 2000, 12, 318-324.

Palladium-Catalyzed Regioselective Silaboration of 1,2-Dienes
- M. Suginome, Y. Ohmori, Y. Ito
- J. Organomet. Chem. 2000, 611, 403-413. (Special issue: The Chemistry of Interelement Linkage)

Structural Modification of Living Polymers: Synthesis of Helical Block Copolymers from a Single Monomer via Palladium-Mediated Aromatizing Polymerization of 1,2-Diisocyanobenzenes
- Y, Ito, T. Miyake, M. Suginome
- Macromolecules 2000, 33, 4034-4038.

Synthesis of (Boryl)(silyl)iminomethanes by Insertion of Isonitriles into Silicon-Boron Bonds
- M. Suginome, T. Fukuda, H. Nakamura, Y. Ito
- Organometallics 2000, 19, 719-721.

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