- 追加された行はこの色です。
- 削除された行はこの色です。
In the Suginome group, a variety of research projects are pursued on the basis of synthetic organic chemistry, organometallic chemistry, main group metal chemistry, transition metal chemistry, polymer chemistry, asymmetric synthesis, etc. Our research projects always involve new design of synthetic strategy, reagents, reactions, and products for the discovery of innovative synthetic methods, new molecular functions, new concept, new phenomena, new principles, etc.
In the Suginome group, a variety of research projects are pursued on the basis of synthetic organic chemistry, organometallic chemistry, main group metal chemistry, transition metal chemistry, polymer chemistry, asymmetric synthesis, etc. We always try to pursue innovative molecular and reaction design for establishing new synthetic methods, new molecular functions, new concept, new phenomena, new principles, etc.
We are interested in utilizing "'''carbonoid'''" elements, which actually are metalloid elements that show high affinity to carbon. Boron and silicon are particularly interesting, serving as key elements in our chemistry.
We are interested in development of new catalytic reactions for molecular synthesis, utilizing transition metal catalysts and organosemimetallic reagents. Boron and silicon are particularly interesting, serving as key elements in our chemistry.
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We are also interested in developing new synthetic strategies for single-handed helical polymers and new applications of thus synthesized chiral helical macromolecules.
We are also interested in the synthesis and new molecular functions of single-handed helical polymers, particularly poly(quinoxaline-2,3-diyl)s.
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Main project areas are shown below. Links to each of these project areas will lead you to detailed information on the topic.
Main parts of our research projects are shown below. Links to each of these project areas will lead you to detailed information on the topic.
+[[Catalytic Borylations: Carboborations and Silaborations>Catalytic Borylations]]
+[[Catalytic Silylations: Bis-Silylations and Silaborations>Catalytic Silylations]]
+[[Boron- and Silicon-Tethered Cyclizations>B- and Si-Tethered Cyclizations]]
+[[Catalytic C-C Bond Forming Reactions]]
+[[Catalytic Asymmetric Synthesis]]
+[[Stereoselective Synthesis]]
+[[Boron-Masking Strategy for the Module-Based Iterative Cross-Coupling>Boron-Masking Strategy]]
+[[New Iminium Ion Generators for Amination Reactions>New Iminium Ion generators]]
+[[Synthesis and Applications of Single-Handed Helical Polymers>Single-Handed Helical Polymers]]
+[[Chirality-Switchable Materials for New Chiral Science and Technology>Synthesis and Functions of Helical Polymers]]
++ Helical-Polymer-Based Chiral Catalysts
++ Chirality-Switchable Chiroptical Materials
+[[Catalytic Element-Boryl Addition Reactions>Catalytic Element-Boryl Addition Reactions]]
++ Catalytic Carboborations
++ Catalytic Silaborations
++ Miscellaneous
+[[Cross-Coupling-Based Synthetic Strategy>Cross-Coupling-Based Synthetic Strategy]]
++"Boron-Masking Strategy" for Iterative Synthesis of Oligoarenes
++Complementary Stereospecificity in Cross-Coupling of Chiral α-Aminoalkylboronic Acid Derivatives
+[[C-H Functionalization>New catalytic C-H Functionalization Reactions]]
++Catalytic Addition of C-H Bond to C=C Bonds
++Removable o-Directing Group for Organoboronic Acids
++C-H Activation at the Methyl Groups on Silicon
+[[Miscellaneous>Miscellaneous]]
++Catalytic Bis-silylation
++New Iminium Ion generators for Amination Reactions
