In Press †
- Tandem C–H Activation by a Single Iridium Catalyst: Direct Access to Indoles and Indolines from o-Alkyl-N-methylanilines
- Stereoinvertive C−C Bond Formation at the Boron‐Bound Stereogenic Centers via Copper–Bipyridine‐Catalyzed Intramolecular Coupling of α‐Aminobenzylboronic Esters
- Yukako Yoshinaga, Takeshi Yamamoto, Michinori Suginome
- Angew. Chem. Int. Ed., 2020, accepted, 10.1002/anie.201914864
2020 †
2019 †
- 4,4’-Bipyridyl-catalyzed Reduction of Nitroarenes by Bis(neopentylglycolato)diboron
- Hiromu Hosoya, Luis C. Misal Castro, Ibrahim Sultan, Yumiko Nakajima, Toshimichi Ohmura, Kazuhiko Sato, Hayato Tsurugi, Michinori Suginome, and Kazushi Mashima
- Org. Lett., 2019, 21, 9812-9817, 10.1021/acs.orglett.9b03419
- Iridium-Catalyzed C(sp3)–H Addition of Methyl Ethers across Intramolecular Carbon–Carbon Double Bonds Giving 2,3-Dihydrobenzofurans
- Toshimichi Ohmura, Satoshi Kusaka, Takeru Torigoe, Michinori Suginome
- Adv. Synth. Catal., 2019, 361, 4448-4453, 10.1002/adsc.201900749
- Selected as Very Important Publication (VIP)
- One of the Fifteen Most Accessed Articles (ASC, Sep. 2019)
- Boryl-Directed, Ir-Catalyzed C(sp3)–H Borylation of Alkylboronic Acids Leading to Site-Selective Synthesis of Polyborylalkanes
- Asymmetric Catalysis in Chiral Solvents: Chirality Transfer with Amplification of Homochirality through a Helical Macromolecular Scaffold
- Pyridine-Based Organocatalysts for Regioselective syn-1,2-Silaboration of Terminal Alkynes and Allenes
- Yohei Morimasa, Kosuke Kabasawa, Toshimichi Ohmura, and Michinori Suginome
- Asian J. Org. Chem., 2019, 8, 1092-1096, 10.1002/ajoc.201900176
- Special Issue: Heterocyclic Chemistry
- Lyotropic Liquid Crystallinity of Linear and Star Poly(quinoxaline-2,3-diyl)s: Isotropic-Liquid Crystal Phase Equilibria in Tetrahydrofuran
- Hirokazu Hasegawa, Ken Terao, Takahiro Sato, Yuuya Nagata, and Michinori Suginome
- Macromolecules, 2019, 52, 3158-3164, 10.1021/acs.macromol.9b00460
- Telechelic Helical Poly(quinoxaline-2,3-diyl)s Containing a Structurally Defined, Circularly Polarized Luminescent Terquinoxaline Core: Synthesis by Core-Initiated Bidirectional Living Polymerization
- Catalytic Generation of Rhodium Silylenoid for Alkene-Alkyne-Silylene [2+2+1] Cycloaddition
- Helical Poly(quinoxaline‐2,3‐diyl)s Bearing 1,2,3‐Triazole Pendants: Synthesis by CuAAC and Use as Reusable Abnormal NHC Ligands in Gold Catalysis
- A bidirectional screw‐sense induction of poly(quinoxaline‐2,3‐diyl)s that depends on the degree of polymerization
- Yuuya Nagata, Tsuyoshi Nishikawa, Ken Terao, Hirokazu Hasegawa, and Michinori Suginome
- J. Polym. Sci. Part A: Polym. Chem., 2019, 57, 260-263, 10.1002/pola.29224
- This manuscript is dedicated to Professor Mitsuo Sawamoto's outstanding achievements in polymer chemistry and recognizes his recent retirement from 40 years of exceptional service to Kyoto University.
2018 †
- A Planar-Chiral Pillar[5]arene-Based Monophosphine Ligand with Induced Chirality at the Biaryl Axis
- Yuuya Nagata, Yasuo Shimada, Tsuyoshi Nishikawa, Ryohei Takeda, Makoto Uno, Tomoki Ogoshi, and Michinori Suginome
- Synlett, 2018, 29, 2167-2170, 10.1055/s-0037-1610635
- This article has been published in SYNLETT issue 16/2018 in the cluster section, "Atropisomerism - in Memoriam Kurt Mislow".
- This article was selected for the cover of SYNLETT.
- Enantiospecific Suzuki-Miyaura Coupling of Nonbenzylic α-(Acylamino)alkylboronic Acid Derivatives
- Toshimichi Ohmura, Kyoko Miwa, Tomotsugu Awano, and Michinori Suginome
- Chem. Asian J., 2018, 13, 2414–2417, 10.1002/asia.201800536
- Special Issue: Homogeneous Catalysis from Young Investigators in Asia
- Highlighted in Synfacts, 2018, 14, 1264, 10.1055/s-0037-16110113
- Abnormal Sergeants-and-Soldiers Effect of Poly(quinoxaline-2,3-diyl)s Enabling Discrimination of One-Carbon Homologous n-Alkanes through a Highly Sensitive Solvent-dependent Helix Inversion
- Chirality-Amplifying, Dynamic Induction of Single-Handed Helix by Chiral Guests to Macromolecular Chiral Catalysts Bearing Boronyl Pendants as Receptor Sites
- Takeshi Yamamoto, Ryo Murakami, Satoko Komatsu, and Michinori Suginome
- J. Am. Chem. Soc., 2018, 140, 3867-3870,
10.1021/jacs.8b00529
- Elucidating the Solvent Effect on the Switch of the Helicity of Poly(quinoxaline-2,3-diyl)s: A Conformational Analysis by Small-Angle Neutron Scattering
- Yuuya Nagata, Tsuyoshi Nishikawa, Michinori Suginome, Sota Sato, Masaaki Sugiyama, Lionel Porcar, Anne Martel, Rintaro Inoue, and Nobuhiro Sato
- J. Am. Chem. Soc., 2018, 140, 2722-2726, 10.1021/jacs.7b11626
2017 †
- Palladium-Catalyzed β-Elimination of Aminoboranes from (Aminomethylsilyl)boranes Leading to the Formation of Silene Dimers
- 4,4'-Bipyridine-Catalyzed Stereoselective trans-Diboration of Acetylenedicarboxylates to 2,3-Diborylfumarates
- Toshimichi Ohmura, Yohei Morimasa, and Michinori Suginome
- Chem. Lett., 2017, 46, 1793–1796, 10.1246/cl.170848 (Open Access)
- Asymmetric Cycloisomerization of o-Alkenyl-N-methylanilines to Indolines through Iridium-Catalyzed C(sp3)–H Addition to Carbon–Carbon Double Bonds
- Takeru Torigoe, Toshimichi Ohmura, and Michinori Suginome
- Angew. Chem. Int. Ed., 2017, 56, 14272–14276, 10.1002/anie.201708578
- One of the Fifteen Most Accessed Articles (ACIE, Oct. 2017)
- Selected as Synfact of the month (Jan. 2018), Synfacts, 2018, 14, 0039, 10.1055/s-0036-1591055
- Synthesis and Solution Properties of a Rigid Helical Star Polymer: Three-Arm Star Poly(quinoxaline-2,3-diyl)
- Chirality-Switchable 2,2'-Bipyridine Ligands Attached to Helical Poly(quinoxaline-2,3-diyl)s for Copper-Catalyzed Asymmetric Cyclopropanation of Alkenes
- Rhodium-Catalyzed C(sp2)–H Addition of Arylboronic Acids to Alkynes Using a Boron-Based, Convertible ortho-Directing Group
- Takeshi Yamamoto, Aoi Ishibashi, and Michinori Suginome
- Chem. Lett., 2017, 46, 1169-1172, 10.1246/cl.170404
- New Chiral Functions Based on the Dynamic Induction of Macromolecular Helical Chirality by Chiral Side Chains
- Synthesis and Catalytic Applications of a Triptycene-Based Monophosphine Ligand for Palladium-Mediated Organic Transformations
- Franco King-Chi Leung, Fumitaka Ishiwari, Yoshiaki Shoji, Tsuyoshi Nishikawa, Ryohei Takeda, Yuuya Nagata, Michinori Suginome, Yasuhiro Uozumi, Yoichi M. A. Yamada, and Takanori Fukushima
- ACS Omega, 2017, 2, 1930-1937,
10.1021/acsomega.7b00200
- Poly(quinoxaline-2,3-diyl) as a Multifunctional Chiral Scaffold for Circularly Polarized Luminescent Materials: Color Tuning, Energy Transfer, and Switching of the CPL Handedness
- Utilization of a Trimethylsilyl Group as a Synthetic Equivalent of a Hydroxyl Group via Chemoselective C(sp3)–H Borylation at the Methyl Group on Silicon
- Takeru Torigoe, Toshimichi Ohmura, and Michinori Suginome
- J. Org. Chem., 2017, 82, 2943–2956, 10.1021/acs.joc.6b02917
- C–H Activation-Based Transformation of Naphthalenes to 3-Iodo-2-naphthylboronic Acid Derivatives for Use in Iterative Coupling Synthesis of Helical Oligo(naphthalene-2,3-diyl)s
- Takeshi Yamamoto, Aoi Ishibashi, Masashi Koyanagi, Hideki Ihara, Nils Eichenauer, and Michinori Suginome
- Bull. Chem. Soc. Jpn., 2017, 90, 604-606, 10.1246/bcsj.20170026
- Single-Handed Helical Poly(quinoxaline-2,3-diyl)s Bearing Achiral 4-Aminopyrid-3-yl Pendants as Highly Enantioselective, Reusable Chiral Nucleophilic Organocatalysts in the Steglich Reaction
- Takeshi Yamamoto, Ryo Murakami, and Michinori Suginome
- J. Am. Chem. Soc., 2017, 139, 2557–2560, 10.1021/jacs.6b12349
- Regioselective Synthesis of o-Benzenediboronic Acids via Ir-Catalyzed o-C–H Borylation Directed by a Pyrazolylaniline-Modified Boronyl Group
2016 †
- High-Pressure Circular Dichroism Spectroscopy up to 400 MPa Using Polycrystalline Yttrium Aluminum Garnet (YAG) as Pressure-Resistant Optical Windows
- Yuuya Nagata, Ryohei Takeda, and Michinori Suginome
- RSC Adv., 2016, 6, 109726-109729, 10.1039/C6RA23736C
- Iridium-Catalyzed Intramolecular Methoxy C–H Addition to Carbon–Carbon Triple Bonds: Direct Synthesis of 3-Substituted Benzofurans from o-Methoxyphenylalkynes
- Takeru Torigoe, Toshimichi Ohmura, and Michinori Suginome
- Chem. Eur. J., 2016, 22, 10415–10419, 10.1002/chem.201602152
- Three-Way-Switchable (Right/Left/OFF) Selective Reflection of Circularly Polarized Light on Solid Thin Films of Helical Polymer Blends
- Yuuya Nagata, Makoto Uno, and Michinori Suginome
- Angew. Chem., Int. Ed, 2016, 55, 7126 –7130, 10.1002/anie.201602035
- A (Borylmethyl)silane Bearing Three Hydrolyzable Groups on Silicon: Synthesis via Iridium-Catalyzed C(sp3)–H Borylation and Conversion to Functionalized Siloxanes
- Solvent Effect on the Sergeants-and-Soldiers Effect Leading to Bidirectional Induction of Single-Handed Helical Sense of Poly(quinoxaline-2,3-diyl)s Copolymers in Aromatic Solvents
2015 †
- Poly(quinoxaline-2,3-diyl)s: A Fascinating Helical Macromolecular Scaffold for New Chiral Functions
- Main-Chain Stiffness and Helical Conformation of a Poly(quinoxaline-2,3-diyl) in Solution
- Majority-Rules-Type Helical Poly(quinoxaline-2,3-diyl)s as Highly Efficient Chirality-Amplification Systems for Asymmetric Catalysis
- Yuan-Zhen Ke, Yuuya Nagata, Tetsuya Yamada, and Michinori Suginome
- Angew. Chem., Int. Ed, 2015, 54, 9333–9337,
10.1002/anie.201502209
- Pressure-dependent Helix Inversion of Poly(quinoxaline-2,3-diyl)s Containing Chiral Side Chains in Non-aqueous Solvents
- Site- and Regioselective Silaborative C–C Cleavage of 1-Alkyl-2-Methylenecyclopropanes Using a Platinum Catalyst with a Sterically Demanding Silylboronic Ester
- Asymmetric Suzuki–Miyaura cross-coupling of 1-bromo-2-naphthoates using the helically chiral polymer ligand PQXphos
- Yuto Akai, Laure Konnert, Takeshi Yamamoto and Michinori Suginome
- Chem. Commun., 2015, 51, 7211–7214,
10.1039/C5CC01074H
- Exerting Control over the Helical Chirality in the Main-Chain of Sergeants-and-Soldiers-Type Poly(quinoxaline-2,3-diyl)s by Changing from Random to Block Copolymerization Protocols
- Yuuya Nagata, Tsuyoshi Nishikawa, and Michinori Suginome
- J. Am. Chem. Soc., 2015, 137, 4070–4073, 10.1021/jacs.5b01422
- Organocatalytic Diboration Involving “Reductive Addition” of a Boron–Boron σ-Bond to 4,4’-Bipyridine
- Facile Preparation of Poly(quinoxaline-2,3-diyl)s via Aromatizing Polymerization of 1,2-Diisocyanobenenes Using Phosphine Complexes of Nickel(II) Salts
- Yuuya Nagata, Yuan-Zhen Ke, and Michinori Suginome
- Chem. Lett, 2015, 44, 53–55, 10.1246/cl.140909
2014 †
- Poly(quinoxaline-2,3-diyl)s Bearing (S)-3-Octyloxymethyl Side Chains as an Efficient Amplifier of Alkane Solvent Effect Leading to Switch of Main Chain Helical Chirality
- Chiral Palladacycle Catalysts Generated on a Single-Handed Helical Polymer Skeleton for Asymmetric Arylative Ring Opening of 1,4-Epoxy-1,4-dihydronaphthalene
- Takeshi Yamamoto, Yuto Akai, and Michinori Suginome
- Angew. Chem., Int. Ed, 2014, 53, 12785–12788.
- Ether Solvent-induced Chirality Inversion of Helical Poly(quinoxaline-2,3-diyl)s Containing L-Lactic Acid Derived Side Chains
- Yuuya Nagata, Takuma Kuroda, Keisuke Takagi, and Michinori Suginome
- Chem. Sci., 2014, 5, 4953-4956, 10.1039/C4SC01920B
- Chirality-switchable Circularly Polarized Luminescence in Solution Based on the Solvent-dependent Helix Inversion of Poly(quinoxaline-2,3-diyl)s
- Yuuya Nagata, Tsuyoshi Nishikawa, and Michinori Suginome
- Chem. Commun., 2014, 50, 9951-9953, 10.1039/C4CC03944K
- Solid Polymer Films Exhibiting Handedness-switchable, Full-color-tunable Selective Reflection of Circularly Polarized Light
- Iridium-Catalysed Borylation of Sterically Hindered C(sp3)–H bonds: Remarkable Rate Acceleration by a Catalytic Amount of Potassium tert-Butoxide
- Toshimichi Ohmura, Takeru Torigoe, and Michinori Suginome
- Chem. Commun., 2014, 50, 6333-6336, 10.1039/C4CC01262C
2013 †
- Nickel-Catalyzed Cyclizative trans-Carboboration of Alkynes through Activation of Boron–Chlorine Bonds by Using Organometallic Reagents as Donors of Organic Groups
- Masaki Daini, Akihiko Yamamoto, and Michinori Suginome
- Asian J. Org. Chem., 2013, 2, 968-976, 10.1002/ajoc.201300164
- Functionalization of Tetraorganosilanes and Permethyloligosilanes at a Methyl Group on Silicon via Iridium Catalyzed C(sp3)–H Borylation
- Toshimichi Ohmura, Takeru Torigoe, and Michinori Suginome
- Organometallics 2013, 32, 6170-6173, 10.1021/om400900z
- Complementary Induction of Right- and Left-Handed Helical Structures by the Positioning of Chiral Groups on the Monomer Units: Introduction of (−)-Menthol as Side Chains of Poly(quinoxaline-2,3-diyl)s
- Takeshi Yamamoto, Takumi Adachi, and Michinori Suginome
- ACS Macro Lett., 2013, 2, 790-793, 10.1021/mz4003326
- Catalytic Borylation and Silylation of Unsaturated Organic Molecules: Reaction Control by Transition Metal Catalysts and Applications to Organic Synthesis (written in Japanese)
- Cycloaddition-based Formal C–H Alkynylation of Isoindoles Leading to the Synthesis of Air-stable Fluorescent 1,3-Dialkynylisoindoles
- Toshimichi Ohmura, Akihito Kijima, Yusuke Komori, and Michinori Suginome
- Org. Lett. 2013, 15, 3510–3513, 10.1021/ol401051d
- Solvent-Dependent Switch of Helical Main-Chain Chirality in Sergeants-and-Soldiers-Type Poly(quinoxaline-2,3-diyl)s: Effect of the Position and Structures of the “Sergeant” Chiral Units on the Screw-Sense Induction
- Yuuya Nagata, Tetsuya Yamada, Takumi Adachi, Yuto Akai, Takeshi Yamamoto, and Michinori Suginome
- J. Am. Chem. Soc., 2013, 135, 10104–10113, 10.1021/ja403391m
- Catalytic Asymmetric Synthesis with Chirality-Switchable Helical Polymer Ligands
- Anthranilamide-masked o-Iodoarylboronic Acids as Coupling Modules for Iterative Synthesis of ortho-Linked Oligoarenes
- Masashi Koyanagi, Nils Eichenauer, Hideki Ihara, Takeshi Yamamoto, and Michinori Suginome
- Chem. Lett., 2013, 42, 541-543, 10.1246/cl.130136
- Palladium-catalyzed Carboboration: Borylative Coupling of Alkynes with Alkenes through Activation of Boron Chlorine Bonds
- Kanayo Nakada, Masaki Daini, and Michinori Suginome
- Chem. Lett., 2013, 42, 538-540, 10.1246/cl.130131
- Synthesis of Cyclic Alkenylborates via Silaboration of Alkynes Followed by Hydrolysis for Utilization in External-Base-Free Cross Coupling
- Toshimichi Ohmura, Kazuyuki Oshima, and Michinori Suginome
- Organometallics 2013, 32, 2870-2873, 10.1021/om400138u
2012 †
- Arylboronic Acid Derivative Cross-Coupling Reactions
- Michinori Suginome and Toshimichi Ohmura
- Science of Synthesis Cross Coupling and Heck-Type Reactions 1, G. A. Molander Ed., Thieme, 2012, 147-201
- Catalytic Functionalization of Methyl Group on Silicon: Iridium-Catalyzed C(sp3)–H Borylation of Methylchlorosilanes
- Toshimichi Ohmura, Takeru Torigoe, and Michinori Suginome
- J. Am. Chem. Soc. 2012, 134, 17416-17419, 10.1021/ja307956w
- Solvent-dependent fluorescence and circular dichroism properties of poly(quinoxaline-2,3-diyl)s bearing pyrene pendants
- Yuuya Nagata, Tsuyoshi Nishikawa, and Michinori Suginome
- Chem. Commun., 2012, 48, 11193-11195, 10.1039/C2CC36275A
- Catalytic Asymmetric Synthesis Using Chirality-Switchable Helical Polymer as a Chiral Ligand
- Michinori Suginome,Takeshi Yamamoto, Yuuya Nagata, Tetsuya Yamada, and Yuto Akai
- Pure Appl. Chem., 2012, 84, 1759-1769, 10.1351/PAC-CON-11-08-23
- Dearomatizing conversion of pyrazines to 1,4-dihydropyrazine derivatives via transition-metal-free diboration, silaboration, and hydroboration
- Kazuyuki Oshima, Toshimichi Ohmura, and Michinori Suginome
- Chem. Commun. 2012, 48, 8571-8573, 10.1039/C2CC34086K
- Enhanced Catalyst Activity and Enantioselectivity with Chirality-Switchable Polymer Ligand PQXphos in Pd-Catalyzed Asymmetric Silaborative Cleavage of meso-Methylenecyclopropanes
- Yuto Akai, Takeshi Yamamoto, Yuuya Nagata, Toshimichi Ohmura, and Michinori Suginome
- J. Am. Chem. Soc., 2012, 134, 11092-11095, 10.1021/ja303506k
- Regioselective Synthesis of 1,2-Dihydropyridines by Rhodium-Catalyzed Hydroboration of Pyridines
- Kazuyuki Oshima, Toshimichi Ohmura, and Michinori Suginome
- J. Am. Chem. Soc. 2012, 134, 3699-3702, 10.1021/ja3002953
- Control of Helical Chirality of Poly(quinoxaline-2,3-diyl)s Based on Postpolymerization Modification of the Terminal Group by Small Chiral Molecules
2011 †
- 1,3,2-Dioxaborolane, 2-(dimethylphenylsilyl)-4,4,5,5-tetramethyl-
- Toshimichi Ohmura and Michinori Suginome
- Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, P. L. Fuchs Ed., Wiley, 2011, 270-276
- Transition Metal-Catalyzed Element-Boryl Additions to Unsaturated Organic Compounds
- Michinori Suginome and Toshimichi Ohmura
- Boronic Acids Second Edition, D. G. Hall Ed., Wiley, 2011, Vol 1, 171-212
- Inversion or Retention? Effects of Acidic Additives on the Stereochemical Course in Enantiospecific Suzuki–Miyaura Coupling of α-(Acetylamino)benzylboronic Esters
- Tomotsugu Awano, Toshimichi Ohmura, and Michinori Suginome
- J. Am. Chem. Soc. 2011, 133, 20738-20741, 10.1021/ja210025q
- (E)- and (Z)-β-Borylallylsilanes via Alkyne Silaboration Followed by Regio- and Stereoselective Double Bond Migration
- Toshimichi Ohmura, Kazuyuki Oshima, and Michinori Suginome
- Angew. Chem. Int. Ed. 2011, 50, 12501–12504, 10.1002/anie.201106077
- Highly Enantioselective Synthesis of Axially Chiral Biarylphosphonates: Asymmetric Suzuki–Miyaura Coupling Using High-Molecular-Weight, Helically Chiral Polyquinoxaline-Based Phosphines
- Takeshi Yamamoto, Yuto Akai, Yuuya Nagata, and Michinori Suginome
- Angew. Chem., Int. Ed, 2011, 50, 8844–8847, 10.1002/anie.201103792
- Synthesis of poly(quinoxaline-2,3-diyl)s with alkoxy side chains by aromatizing polymerization of 4,5-dialkoxy-substituted 1,2-diisocyanobenzenes
- Yuuya Nagata and Michinori Suginome
- J. Polym. Sci. Part A: Polym. Chem., 2011, 49, 4275–4282, 10.1002/pola.24871
- Ruthenium-Catalyzed C–H-Silylation of Methylboronic Acid Using a Removable α-Directing Modifier on the Boron Atom
- Hideki Ihara, Akinori Ueda, and Michinori Suginome
- Chem. Lett., 2011, 40, 916–918, 10.1246/cl.2011.916
- Dinuclear Palladium and Platinum Complexes with Bridging Silylene Ligands. Preparation Using (Aminosilyl)boronic Ester as the Ligand Precursor and Their Reactions with Alkynes
- Makoto Tanabe, Jian Jiang, Hideto Yamazawa, Kohtaro Osakada, Toshimichi Ohmura, and Michinori Suginome
- Organometallics 2011, 30, 3981-3991, 10.1021/om200156g
- Anthranilamide: A Simple, Removable Ortho-Directing Modifier for Arylboronic Acids Serving also as a Protective Group in Cross-Coupling Reactions
- Hideki Ihara, Masashi Koyanagi, and Michinori Suginome
- Org. Lett., 2011, 13, 2662-2665, 10.1021/ol200764g
- Palladium-Catalyzed Regioselective Silaboration of Pyridines Leading to the Synthesis of Silylated Dihydropyridines
- Kazuyuki Oshima, Toshimichi Ohmura, and Michinori Suginome
- J. Am. Chem. Soc. 2011, 133, 7324-7327, 10.1021/ja2020229
- Palladium-Catalyzed, Stereoselective, Cyclizative Alkenylboration of Carbon−Carbon Double Bonds through Activation of a Boron−Chlorine Bond
- Masaki Daini and Michinori Suginome
- J. Am. Chem. Soc., 2011, 133, 4758-4761, 10.1021/ja200856t
- 2-Vinylindoles As the Four-Atom Component in a Catalytic [4+1] Cycloaddition with a Silylene-Palladium Species Generated from (Aminosilyl)boronic Ester
- Kohei Masuda, Toshimichi Ohmura, and Michinori Suginome
- Organometallics 2011, 30, 1322-1325, 10.1021/om200135u
- Integrated Catalytic C−H Transformations for One-Pot Synthesis of 1-Arylisoindoles from Isoindolines via Palladium-Catalyzed Dehydrogenation Followed by C−H Arylation
- Toshimichi Ohmura, Akihito Kijima, and Michinori Suginome
- Org. Lett. 2011, 13, 1238-1241, 10.1021/ol2001232
2010 †
- Stereospecific Suzuki-Miyaura Coupling of Chiral α-(Acylamino)benzylboronic Esters with Inversion of Configuration
- Toshimichi Ohmura, Tomotsugu Awano, and Michinori Suginome
- J. Am. Chem. Soc. 2010, 132, 13191-13193, 10.1021/ja106632j
- Switch of Regioselectivity in Palladium-Catalyzed Silaboration of Terminal Alkynes by Ligand-Dependent Control of Reductive Elimination
- Toshimichi Ohmura, Kazuyuki Oshima, Hiroki Taniguchi, and Michinori Suginome
- J. Am. Chem. Soc. 2010, 132, 12194-12196, 10.1021/ja105096r
- Non-hydrogen-bonding-based, solvent-dependent helix inversion between pure P-helix and pure M-helix in poly(quinoxaline-2,3-diyl)s bearing chiral side chains
- Tetsuya Yamada, Yuuya Nagata and Michinori Suginome
- Chem. Commun. 2010, 46, 4914-4916, 10.1039/c001564d
- High-Molecular-Weight Polyquinoxaline-Based Helically Chiral Phosphine (PQXphos) as Chirality-Switchable, Reusable, and Highly Enantioselective Monodentate Ligand in Catalytic Asymmetric Hydrosilylation of Styrenes
- Takeshi Yamamoto, Tetsuya Yamada, Yuuya Nagata and Michinori Suginome
- J. Am. Chem. Soc. 2010, 132, 7899–7901, 10.1021/ja102428q
- Rhodium-catalyzed Dehydroborylation of Styrenes with Naphthalene-1,8-diaminatoborane [(dan)BH]: New Synthesis of Masked β-Borylstyrenes as New Phenylene–Vinylene Cross-coupling Modules
- Nickel-Catalyzed Asymmetric Addition of Alkyne C-H Bonds across 1,3-Dienes Using Taddol-Based Chiral Phosphoramidite Ligands
- Synthesis of Helical Rod−Coil Multiblock Copolymers by Living Block Copolymerization of Isocyanide and 1,2-Diisocyanobenzene Using Arylnickel Initiators
- Tetsuya Yamada and Michinori Suginome
- Macromolecules 2010, 43, 3999-4002, 10.1021/ma100500r
- Langmuir–Blodgett films of helical rigid-rod poly(quinoxaline-2,3-diyl)s
- Yoshihiko Ito, Toshiyuki Miyake, Michinori Suginome, Rie Katakura, Masaya Mitsuishi, and Tokuji Miyashita
- Polym. J. 2010, 42, 406-410, 10.1038/pj.2010.14
- Recent Progress of Catalytic Hydroboration: Use of Copper and Iron Catalysts (written in Japanese)
- Toshimichi Ohmura
- Organometallic News 2010, 28, 28-28
- Differentially Protected Diboron for Regioselective Diboration of Alkynes: Internal-Selective Cross-Coupling of 1-Alkene-1,2-diboronic Acid Derivatives
- Noriyuki Iwadate and Michinori Suginome
- J. Am. Chem. Soc. 2010, 132, 2548-2549, 10.1021/ja1000642
- Chiral Arylnickel Complexes as Highly Active Initiators for Screw-Sense Selective Living Polymerization of 1,2-Diisocyanobenzenes
- Tetsuya Yamada, Hiroyoshi Noguchi, Yuuya Nagata, and Michinori Suginome
- J. Polym. Sci. Part A: Polym. Chem. 2010, 48, 898-904, 10.1002/pola.23842
2009 †
- Palladium-Catalyzed Silylene-1,3-Diene [4 + 1] Cycloaddition with Use of (Aminosilyl)boronic Esters as Synthetic Equivalents of Silylene
- Toshimichi Ohmura, Kohei Masuda, Ichiro Takase, and Michinori Suginome
- J. Am. Chem. Soc. 2009, 131, 16624-16625, 10.1021/ja907170p
- Nickel-Catalyzed Ring-Opening Hydroacylation of Methylenecyclopropanes:
Synthesis of γ,δ-Unsaturated Ketones from Aldehydes
- Hiroki Taniguchi, Toshimichi Ohmura, and Michinori Suginome
- J. Am. Chem. Soc. 2009, 131, 11298-11299, 10.1021/ja9046894
- Kinetic Resolution of Racemic 1-Alkyl-2-methylenecyclopropanes via Palladium-Catalyzed Silaborative C–C Cleavage
- Toshimichi Ohmura, Hiroki Taniguchi, and Michinori Suginome
- Org. Lett. 2009, 11, 2880-2883, 10.1021/ol900829c
- Easily Attachable and Detachable ortho-Directing Agent for Arylboronic Acids in Ruthenium-Catalyzed Aromatic C−H Silylation
- Hideki Ihara and Michinori Suginome
- J. Am. Chem. Soc. 2009, 131, 7502-7503, 10.1021/ja902314v
- α-Amidobenzylation of Aryl and Alkenyl Halides via Palladium-catalyzed Suzuki-Miyaura Coupling with α-(Acylamino)benzylboronic Esters
- Toshimichi Ohmura, Tomotsugu Awano, and Michinori Suginome
- Chem. Lett. 2009, 38, 664-665, 10.1246/cl.2009.664
- Palladium-catalyzed intramolecular cyanoboration of allenes leading to the regioselective synthesis of β-cyanoallylboranes
- Synthesis of 1-Borylisoindoles via Palladium-Catalyzed Dehydrogenation/C−H Borylation of Isoindolines
- Toshimichi Ohmura, Akihito Kijima and Michinori Suginome
- J. Am. Chem. Soc. 2009, 131, 6070-6071, 10.1021/ja901095h
- Synthesis of B-Protected β-Styrylboronic Acids via Iridium-Catalyzed Hydroboration of Alkynes with 1,8-Naphthalenediaminatoborane Leading to Iterative Synthesis of Oligo(phenylenevinylene)s
- Noriyuki Iwadate and Michinori Suginome
- Org. Lett. 2009, 11, 1899-1902, 10.1021/ol9003096
- Nickel-Catalyzed, Regio- and Stereoselective Hydroalkynylation of Methylenecyclopropanes with Retention of the Cyclopropane Ring, Leading to the Synthesis of 1-Methyl-1-Alkynylcyclopropanes
- Masamichi Shirakura and Michinori Suginome
- J. Am. Chem. Soc. 2009, 131, 5060-5061, 10.1021/ja900876w
- Synthesis of masked haloareneboronic acids via iridium-catalyzed aromatic C–H borylation with 1,8-naphthalenediaminatoborane (danBH)
- Stereoselective Synthesis of cis-β-Methyl- and Phenyl-Substituted Alkenylboronates by Platinum-Catalyzed Dehydrogenative Borylation
- Toshimichi Ohmura, Yuta Takasaki, Hideki Furukawa, and Michinori Suginome
- Angew. Chem. Int. Ed. 2009, 48, 2372-2375, 10.1002/anie.200805406
- B(OMe)SUB{3}; as a Nonacidic Iminium Ion Generator in Mannich- and Ugi-Type Reactions
- Yusuke Tanaka, Kousuke Hidaka, Tomoaki Hasui, and Michinori Suginome
- Eur. J. Org. Chem. 2009, 8, 1148-1151, 10.1002/ejoc.200801190
- Nickel-Catalyzed Regioselective Hydroalkynylation of Styrenes: Improved Catalyst System, Reaction Scope, and Mechanism
- Masamichi Shirakura and Michinori Suginome
- Org. Lett. 2009, 11, 523-526, 10.1021/ol802475h
- Silylboranes as New Tools in Organic Synthesis
- Toshimichi Ohmura and Michinori Suginome
- Bull. Chem. Soc. Jpn. 2009, 82, 29-49, 10.1246/bcsj.82.29
- Helical Poly(quinoxaline-2,3-diyl)s Bearing Metal-Binding Sites as Polymer-Based Chiral Ligands for Asymmetric Catalysis
2008 †
- Carbon-Silicon Bond Formation via Transition Metal-Catalyzed Reaction of Silylene Equivalents (Japanese)
- Toshimichi Ohmura and Michinori Suginome
- Keiso Kagaku Kyokaishi, 2008, 25, 32-35
- Iterative Suzuki-Miyaura cross-coupling reaction for the selective synthesis of oligoarenes
- Michinori Suginome
- Ekisho, 2008, 12, 296-305
- Palladium-Catalyzed Carboboration of Alkynes Using Chloroborane and
Organozirconium Reagents
- Masaki Daini and Michinori Suginome
- Chem. Commun. 2008, 5224-5226, 10.1039/b809433k
- Diarylborinic Acid Derivatives as a Catalytic Iminium Ion Generator in the Mannich-Type Reaction Using Secondary Amines, Aldehydes, and Ketene Silyl Acetals
- Nickel-Catalyzed Addition of C-H Bonds of Terminal Alkynes to 1,3-Dienes and Styrenes
- Masamichi Shirakura and Michinori Suginome
- J. Am. Chem. Soc. 2008 130, 5410-5411, 10.1021/ja800997j
- A Mechanism for the Palladium-Catalyzed Regioselective Silaboration of Allene: A Theoretical Study
- Yoko Abe, Kei Kuramoto, Masahiro Ehara, Hiroshi Nakatsuji, Michinori Suginome, Masahiro Murakami and Yoshihiko Ito
- Organometallics, 2008, 27, 1736-1742, 10.1021/om070110f
- "Synthetic organic chemistry" and "polymer science" of isocyanide
- Michinori Suginome
- Kobunshi, 2008, 57, 130-133
- Palladium-Catalysed cis- and trans-Silaboration of Terminal Alkynes: Complementary Access to Stereo-Defined Trisubstituted Alkenes
- Toshimichi Ohmura, Kazuyuki Oshima and Michinori Suginome
- Chem. Comm. 2008, 1416-1418, 10.1039/b800181b
- Palladium-Catalyzed trans- and cis-Carboboration of Alkynes Tethered to Chloroborane with Organozirconium Reagents: Ligand-Dependent Complementary Stereoselectivity
- Masaki Daini, Akihiko Yamamoto, and Michinori Suginome
- J. Am. Chem. Soc. 2008, 130, 2918-2919, 10.1021/ja711160h
- Synthetic Application of Intramolecular Cyanoboration on the Basis of Removal and Conversion of a Tethering Group by Palladium-Catalyzed Retro-Allylation
- Toshimichi Ohmura, Tomotsugu Awano, Michinori Suginome, Hideki Yorimitsu, and Koichiro Oshima
- Synlett 2008, 423-427, 10.1055/s-2008-1032075
- Silylboranes Bearing Dialkylamino Groups on Silicon as Silylene Equivalents: Palladium-Catalyzed Regioselective Synthesis of 2,4-Disubstituted Siloles
- Toshimichi Ohmura, Kohei Masuda, and Michinori Suginome
- J. Am. Chem. Soc. 2008, 130, 1526-1527, 10.1021/ja073896h
- Differentially Protected Benzenediboronic Acids: Divalent Cross-Coupling Modules for the Efficient Synthesis of Boron-Substituted Oligoarenes
- Hiroyoshi Noguchi, Takayuki Shioda, Chih-Ming Chou, and Michinori Suginome
- Org. Lett. 2008, 10, 377-380, 10.1021/ol702420x
2007 †
- Development of Boron-Based Reactions and Reagents for Organic Synthesis
- Michinori Suginome
- J. Synth. Org. Chem., Jpn. 2007, 65, 1048-1059
- Acid-Free, Aminoborane-Mediated Ugi-Type Reaction Leading to General Utilization of Secondary Amines
- Yusuke Tanaka, Tomoaki Hasui, and Michinori Suginome
- Org. Lett. 2007, 9, 4407-4410, 10.1021/ol701570c
- Synthesis and Helical Structure of Oligo(quinoline-2,3-diyl)s
- Michinori Suginome, Hiroyoshi Noguchi and Masahiro Murakami
- Chem. Lett. 2007, 36, 1036-1037, 10.1246/cl.2007.1036
- Palladium-Catalyzed Asymmetric Silaborative C-C Cleavage of meso-Methylenecyclopropanes
- Toshimichi Ohmura, Hiroki Taniguchi, Yoshiyuki Kondo, and Michinori Suginome
- J. Am. Chem. Soc. 2007, 129, 3518-3519, 10.1021/ja0703170
- Synthesis of Silylboronic Esters Functionalized on Silicon
- Toshimichi Ohmura, Kohei Masuda, Hideki Furukawa, Michinori Suginome
- Organometallics 2007, 26, 1291-1294, 10.1021/om0609867
- Boron-Masking Strategy for the Selective Synthesis of Oligoarenes via Iterative Suzuki-Miyaura Coupling
- Hiroyoshi Noguchi, Kosho Hojo, Michinori Suginome
- J. Am. Chem. Soc. 2007, 129, 758-759, 10.1021/ja067975p
- C-E Bond Formation through Element-Element Addition to Carbon-Carbon Multiple Bonds
- Michinori Suginome, Takanori Matsuda, Toshimichi Ohmura, Atsushi Seki, Masahiro Murakami
- In Comprehensive Organometallic Chemistry III; Crabtree, R. and Mingos, M. Eds.; Ojima, I. Vol. Ed.; Elsevier, 2007; Volume 10, pp 725-787
2006 †
- Nickel-Catalyzed Addition of Alkynylboranes to Alkynes
- Michinori Suginome, Masamichi Shirakura, Akihiko Yamamoto
- J. Am. Chem. Soc. 2006, 128, 14438-14439
- Palladium-Catalyzed Asymmetric Silaboration of Allenes
- Toshimichi Ohmura, Hiroki Taniguchi, Michinori Suginome
- J. Am. Chem. Soc. 2006, 128, 13682-13683
- Ligand-Controlled, Complementary Stereoselectivity in the Platinum-Catalyzed Intramolecular Silaboration of Alkenes
- Toshimichi Ohmura, Hideki Furukawa, Michinori Suginome
- J. Am. Chem. Soc. 2006, 128, 13366-13367
- Aminoboranes as New Iminium Ion Generators in Amination Reactions
- Michinori Suginome
- Pure Appl. Chem. 2006, 78, 1377-1387
- Reductive amination of aldehydes using aminoboranes as iminium ion generators
- Michinori Suginome, Yusuke Tanaka, Tomoaki Hasui
- Synlett 2006, 1047-1050
- Asymmetric Silaboration of Terminal Allenes Bearing α-Stereogenic Centers: Stereoselection Based on "Reagent Control"
- Toshimichi Ohmura and Michinori Suginome
- Org. Lett. 2006, 8, 2503-2506
- Reactions of Cyanoboranes with a Palladium-PMeSUB{3}; Complex: Mechanism for the Catalytic Cyanoboration of Alkynes
- Michinori Suginome, Akihiko Yamamoto, Taisuke Sasaki, Masahiro Murakami
- Organometallics 2006, 25, 2911-2913
2005 †
- Nickel-Catalyzed trans-Alkynylboration of Alkynes via Activation of a Boron-Chlorine Bond
- Akihiko Yamamoto, Michinori Suginome
- J. Am. Chem. Soc. 2005, 127, 15706-15707
- Intramolecular Cyanoboration of Alkynes via Activation of Boron-Cyanide Bonds by Transition Metal Catalysts
- Michinori Suginome, Akihiko Yamamoto, Masahiro Murakami
- J. Organomet. Chem. 2005, 690, 5300-5308
- Carbon-carbon bond formation using boron. Design, creation, and new reactions of functional boron reagents
- Michinori Suginome
- Kagaku to Kogyo, 2005, 58, 919-922
- New development of organosilicon compound synthesis
- Toshimichi Ohmura and Michinori Suginome
- Kagaku, 2005, 60, 68-69
- Stereoselective Synthesis of Highly Enantioenriched (E)-Allylsilanes by Palladium-Catalyzed Intramolecular Bis-Silylation: 1,3-Chirality Transfer and Enantioenrichment via Dimer Formation
- Michinori Suginome, Taisuke Iwanami, Yutaka Ohmori, Akira Matsumoto, Yoshihiko Ito
- Chem. Eur. J. 2005, 11, 2954-2965
- Palladium-Catalyzed Addition of Cyanoboranes to Alkynes Leading to Regio- and Stereoselective Synthesis of β-Boryl-α,β-Unsaturated Nitriles
- Michinori Suginome, Akihiko Yamamoto, Masahiro Murakami
- Angew. Chem. Int. Ed. 2005, 44, 2380-2382
- Synthesis and Reactions of Cyclic Silylboranes
- Michinori Suginome, Hiroyoshi Noguchi, Tomoaki Hasui, Masahiro Murakami
- Bull. Chem. Soc. Jpn. 2005, 78, 323-326
- Synthesis and Structural Analysis of Oligo(naphthalene-2,3-diyl)s
- Takahisa Motomura, Hideko Nakamura, Michinori Suginome, Masahiro Murakami, and Yoshihiko Ito
- Bull. Chem. Soc. Jpn. 2005, 78, 142-146
2004 †
- Aminoboranes as "Compatible" Iminium Ion Generators in Aminative C-C Bond Formations
- Michinori Suginome, Lars Uehlin, and Masahiro Murakami
- J. Am. Chem. Soc. 2004, 126, 13196-13197
- A New Look at Boron Enolate Chemistry: Aminative C-C Bond Formation Using Diaminoboron Enolate with Aldehyde
- Michinori Suginome, Lars Uehlin, Akihiko Yamamoto, and Masahiro Murakami
- Org. Lett. 2004, 6, 1167-1169.
2003 †
- Enantioface-Selective Palladium-Catalyzed Silaboration of Allenes via Double Asymmetric Induction
- Michinori Suginome, Toshimichi Ohmura, Yoshihiro Miyake, Shin’ichirou Mitani, Yoshihiko Ito, Masahiro Murakami
- J. Am. Chem. Soc. 2003, 125, 11174-11175.
- Palladium- and Nickel-Catalyzed Intramolecular Cyanoboration of Alkynes
- Michinori Suginome, Akihiko Yamamoto, Masahiro Murakami
- J. Am. Chem. Soc. 2003, 125, 6358-6359.
2002 †
- Bis(dialkylamino)cyanoboranes: highly efficient reagents for the Strecker-type aminative cyanation of aldehydes and ketones.
- M. Suginome, A. Yamamoto, Y. Ito
- Chem. Comm. 2002, 1392-1393.
- Nickel-Catalyzed Silaboration of Small-Ring Vinylcycloalkanes: Regio- and Stereoselective(E)-Allylsilane Formation via C-C Bond Cleavage.
- M. Suginome, T. Matsuda, T. Yoshimoto, Y. Ito
- Organometallics 2002, 21, 1537-1539.
- 1,2-Azaboretidine Formation in the Reactions of (Boryl)(silyl)iminomethanes via Possible Generation of (Amino)(boryl)carbene Species
- M. Suginome, T. Fukuda, Y. Ito
- J. Organomet. Chem. 2002, 643-644, 508-511. (Special issue dedicated to Prof. F. Mathey)
- Highly Effective, Easily Accessible Screw-Sense-Determining End Group in theAsymmetric Polymerization of 1,2-Diisocyanobenzenes.
- M. Suginome, S. Collet, Y. Ito
- Org. Lett. 2002, 4, 351-354.
2001 †
- Stereoselective construction of trans-1,2-benzooxadecaline frameworks by three-component cascade reactions of an a-phenethyl-b-borylallylsilane with aldehydes
- M. Suginome, Y. Ohmori, Y. Ito
- Chem. Commun. 2001, 1090-1091.
- Solid-Phase Synthesis and Asymmetric Reactions of Polymer-Supported Highly Enantioenriched Allylsilanes
- M. Suginome, T. Iwanami, and Y. Ito
- J. Am. Chem. Soc. 2001, 123, 4356-4357.
- Asymmetric Synthesis of Cyclic Alkenes via Cyclization of Enantioenriched Allylsilanes
- M. Suginome, T. Iwanami, A. Yamamoto, and Y. Ito
- Synlett 2001, 1042-1045.
- β-Borylallylsilanes as a New Tool for Convenient Synthesis of Alkenylboranes
- M. Suginome, Y. Ohmori, and Y. Ito
- J. Am. Chem. Soc. 2001, 123, 4601-4602.
2000 †
- Palladium- and Platinum-Catalyzed Silaboration of Methylenecyclopropanes through Selective Proximal or Distal C-C Bond Cleavage
- M. Suginome, T. Matsuda, and Y. Ito
- J. Am. Chem. Soc. 2000, 122, 11015-11016.
- Convenient Preparation of Silylboranes
- M. Suginome, T. Matsuda, and Y. Ito
- Organometallics 2000, 19, 4647-4649.
- First Synthesis and Resolution of a Planar-chiral Tetrahydroindolyl Complex of Iron: Electronic Tuning of Reactivity and Enantioselective Nucleophilic Catalysis
- M. Suginome and G. C. Fu
- Chirality 2000, 12, 318-324.
- Palladium-Catalyzed Regioselective Silaboration of 1,2-Dienes
- M. Suginome, Y. Ohmori, Y. Ito
- J. Organomet. Chem. 2000, 611, 403-413. (Special issue: The Chemistry of Interelement Linkage)
- Structural Modification of Living Polymers: Synthesis of Helical Block Copolymers from a Single Monomer via Palladium-Mediated Aromatizing Polymerization of 1,2-Diisocyanobenzenes
- Y, Ito, T. Miyake, M. Suginome
- Macromolecules 2000, 33, 4034-4038.
- Synthesis of (Boryl)(silyl)iminomethanes by Insertion of Isonitriles into Silicon-Boron Bonds
- M. Suginome, T. Fukuda, H. Nakamura, Y. Ito
- Organometallics 2000, 19, 719-721.
