Publications

2024 †

• In Situ Dehydrogenative Generation of Vinyl Groups Bound to Heteroatoms by the Use of Ethyl Groups as Surrogates in Iridium-Catalyzed Intramolecular C–H/C–H Coupling
  • Kaito Yagi, Toshimichi Ohmura, Michinori Suginome
  • ACS Catal., 2024, 14, 2014–2021, 10.1021/acscatal.3c05965
    

2023 †

• A Traceless Chiral Shift Reagent Based on Nonbonding Interaction with Single-Handed Helical Poly(quinoxaline-2,3-diyl)
  • Takaya Fujie, Takeshi Yamamoto, Michinori Suginome
  • Angew. Chem. Int. Ed., 2023, 10.1002/anie.202301347
    

• Development of Dynamically Chiral Helical Polymer Catalysts Based on Post-Polymerization Modification of Boronyl Pendants
  • Takeshi Yamamoto, Yukako Yoshinaga, and Michinori Suginome
  • J. Synth. Org. Chem. Jpn., 2023, 81, 324-332, 10.5059/yukigoseikyokaishi.81.324 (Japanese)

2022 †

• Iridium-Catalyzed Enantioselective Intramolecular Cross-Dehydrogenative Coupling of Alkyl Aryl Ethers Giving Enantioenriched 2,3-Dihydrobenzofurans
  • Satoshi Kusaka, Toshimichi Ohmura, Michinori Suginome
  • Chem. Lett., 2022, 51, 601–604, 10.1246/cl.220129 (Open Access)
    

• Synthesis of Disilanes, Dihydrosiloles, and 1,4-Disilacyclohexa-2,5-dienes by Transition-Metal-Free Transfer of Diphenylsilylene and Dimethylsilylene from Silylboronic Esters
  • Ikuo Sasaki, Asahi Maebashi, Jiaying Li, Toshimichi Ohmura, Michinori Suginome
  • Eur. J. Org. Chem., 2022, e202101573, 10.1002/ejoc.202101573
    
  • A Special Collection on “Silicon Chemistry in Organic Synthesis”

2021 †

• Iridium-Catalyzed Enantioselective Intramolecular Hydroarylation of Allylic Aryl Ethers Devoid of a Directing Group on the Aryl Group
  • Toshimichi Ohmura, Satoshi Kusaka, Michinori Suginome
  • Chem. Commun., 2021, 57, 13542–13545, 10.1039/D1CC05684K
    

• PQXdpap: Helical Poly(quinoxaline-2,3-diyl)s Bearing 4-(Dipropylamino)pyridin-3-yl Pendants as Chirality-Switchable Nucleophilic Catalysts for the Kinetic Resolution of Secondary Alcohols
  • Takeshi Yamamoto, Ryo Murakami, Michinori Suginome
  • Org. Lett., 2021, 23, 8711-8716, 10.1021/acs.orglett.1c03134
    

• Mechanism of 2,6-Dichloro-4,4’-bipyridine-Catalyzed Diboration of Pyrazines Involving a Bipyridine-Stabilized Boryl Radical
  • Toshimichi Ohmura, Yohei Morimasa, Tomoya Ichino, Yusuke Miyake, Yasujiro Murata, Michinori Suginome, Kunihiko Tajima, Tetsuya Taketsugu, Satoshi Maeda
  • Bull. Chem. Soc. Jpn., 2021, 94, 1894–1902, 10.1246/bcsj.20210145 (Open Access)
    
  • Selected as "BCSJ Award Article" (Vol. 94, No. 7, 2021).

• Intramolecular Addition of a Dimethylamino C(sp3)–H Bond across C–C Triple Bonds using IrCL(DTBM-SEGPHOS)(ethylene) Catalyst: Synthesis of Indoles from 2-Alkynyl-N-methylanilines
  • Toshimichi Ohmura, Kaito Yagi, Takeru Torigoe, Michinori Suginome
  • Synthesis, 2021, 53, 3057–3064, 10.1055/a-1511-1025
    
  • A Special Issue on “Bond Activation - in Honor of Prof. Shinji Murai”

• Protected Amino Acids as a Nonbonding Source of Chirality in Induction of Single-Handed Screw-Sense to Helical Macromolecular Catalysts
  • Shoma Ikeda, Ryohei Takeda, Takaya Fujie, Naoto Ariki, Yuuya Nagata, Michinori Suginome
  • Chem. Sci., 2021, 12, 8811–8816, 10.1039/D1SC01764K (Open Access)
    

• Copper-Catalyzed Regioselective trans-Silaboration of Internal Arylalkynes with Stereochemical Switch to cis-Addition Mode
  • Toshimichi Ohmura, Yuta Takaoka, Michinori Suginome
  • Chem. Commun., 2021, 57, 4670–4673, 10.1039/D1CC01579F
    

• Asymmetric O-to-C Aryloxycarbonyl Migration of Indolyl Carbonates Using Single-handed Dynamic Helical Polyquinoxalines Bearing 4-Aminopyridyl Groups as Chiral Nucleophilic Catalysts
  • Takeshi Yamamoto, Takuya Takahashi, Ryo Murakami, Naoto Ariki, Michinori Suginome
  • Bull. Chem. Soc. Jpn., 2021, 94, 943–949, 10.1246/bcsj.20200369
    

• Amphiphilic Immobilized Diphenylprolinol Alkyl Ether Catalyst on PS-PEG Resin
  • Seitaro Koshino, Shusuke Hattori, Shota Hasegawa, Naoki Haraguchi, Takeshi Yamamoto, Michinori Suginome, Yasuhiro Uozumi, Yujiro Hayashi
  • Bull. Chem. Soc. Jpn., 2021, 94, 790–797, 10.1246/bcsj.20200355
    

2020 †

• Enantioconvergent Cu-Catalyzed Intramolecular C–C Coupling at Boron-Bound C(sp3) Atoms of α-Aminoalkylboronates Using a C1-Symmetrical 2,2′-Bipyridyl Ligand Attached to a Helically Chiral Macromolecular Scaffold
  • Yukako Yoshinaga, Takeshi Yamamoto, Michinori Suginome
  • J. Am. Chem. Soc., 2020, 142, 18317–18323, 10.1021/jacs.0c09080
    

• Holding of planar chirality of pillar[5]arene by kinetic trapping using host–guest interactions with achiral guest solvents
  • Yuuya Nagata, Misaki Suzuki, Yasuo Shimada, Hiroki Sengoku, Shungo Nishida, Takahiro Kakuta, Tadaaki Yamagishi, Michinori Suginome, Tomoki Ogoshi
  • Chem. Commun., 2020, 56, 8424-8427, 10.1039/d0cc03413d
    

• Stereoinvertive C−C Bond Formation at the Boron‐Bound Stereogenic Centers via Copper–Bipyridine‐Catalyzed Intramolecular Coupling of α‐Aminobenzylboronic Esters
  • Yukako Yoshinaga, Takeshi Yamamoto, Michinori Suginome
  • Angew. Chem. Int. Ed., 2020, 59, 7251-7255, 10.1002/anie.201914864
    

• Construction of Silicon-Containing Seven-Membered Rings by Catalytic [4+2+1] Cycloaddition through Rhodium Silylenoid
  • Ikuo Sasaki, Toshimichi Ohmura, and Michinori Suginome
  • Org. Lett., 2020, 22, 2961-2966, 10.1021/acs.orglett.0c00690
    

• Tandem C–H Activation by a Single Iridium Catalyst: Direct Access to Indoles and Indolines from o-Alkyl-N-methylanilines
  • Toshimichi Ohmura, Kaito Yagi, Satoshi Kusaka, and Michinori Suginome
  • ACS Catal., 2020, 10, 3152-3157, 10.1021/acscatal.9b05579
    

2019 †

• 4,4’-Bipyridyl-catalyzed Reduction of Nitroarenes by Bis(neopentylglycolato)diboron
  • Hiromu Hosoya, Luis C. Misal Castro, Ibrahim Sultan, Yumiko Nakajima, Toshimichi Ohmura, Kazuhiko Sato, Hayato Tsurugi, Michinori Suginome, and Kazushi Mashima
  • Org. Lett., 2019, 21, 9812-9817, 10.1021/acs.orglett.9b03419
    

• Iridium-Catalyzed C(sp3)–H Addition of Methyl Ethers across Intramolecular Carbon–Carbon Double Bonds Giving 2,3-Dihydrobenzofurans
  • Toshimichi Ohmura, Satoshi Kusaka, Takeru Torigoe, Michinori Suginome
  • Adv. Synth. Catal., 2019, 361, 4448-4453, 10.1002/adsc.201900749
    
  • Selected as Very Important Publication (VIP)
  • One of the Fifteen Most Accessed Articles (ASC, Sep. 2019)

• Boryl-Directed, Ir-Catalyzed C(sp3)–H Borylation of Alkylboronic Acids Leading to Site-Selective Synthesis of Polyborylalkanes
  • Takeshi Yamamoto, Aoi Ishibashi, and Michinori Suginome
  • Org. Lett., 2019, 21, 6235-6240, 10.1021/acs.orglett.9b02112
    

• Asymmetric Catalysis in Chiral Solvents: Chirality Transfer with Amplification of Homochirality through a Helical Macromolecular Scaffold
  • Yuuya Nagata, Ryohei Takeda, and Michinori Suginome
  • ACS Cent. Sci., 2019, 5, 1235-1240, 10.1021/acscentsci.9b00330
    

• Pyridine-Based Organocatalysts for Regioselective syn-1,2-Silaboration of Terminal Alkynes and Allenes
  • Yohei Morimasa, Kosuke Kabasawa, Toshimichi Ohmura, and Michinori Suginome
  • Asian J. Org. Chem., 2019, 8, 1092-1096, 10.1002/ajoc.201900176
    
  • Special Issue: Heterocyclic Chemistry

• Lyotropic Liquid Crystallinity of Linear and Star Poly(quinoxaline-2,3-diyl)s: Isotropic-Liquid Crystal Phase Equilibria in Tetrahydrofuran
  • Hirokazu Hasegawa, Ken Terao, Takahiro Sato, Yuuya Nagata, and Michinori Suginome
  • Macromolecules, 2019, 52, 3158-3164, 10.1021/acs.macromol.9b00460
    

• Telechelic Helical Poly(quinoxaline-2,3-diyl)s Containing a Structurally Defined, Circularly Polarized Luminescent Terquinoxaline Core: Synthesis by Core-Initiated Bidirectional Living Polymerization
  • Shogo Kuriyama, Yuuya Nagata, and Michinori Suginome
  • ACS Macro Lett., 2019, 8, 479-485, 10.1021/acsmacrolett.9b00165
    

• Catalytic Generation of Rhodium Silylenoid for Alkene-Alkyne-Silylene [2+2+1] Cycloaddition
  • Toshimichi Ohmura, Ikuo Sasaki, and Michinori Suginome
  • Org. Lett., 2019, 21, 1649-1653, 10.1021/acs.orglett.9b00326
    

• Helical Poly(quinoxaline‐2,3‐diyl)s Bearing 1,2,3‐Triazole Pendants: Synthesis by CuAAC and Use as Reusable Abnormal NHC Ligands in Gold Catalysis
  • Pinglu Zhang, Takeshi Yamamoto, and Michinori Suginome
  • ChemCatChem, 2019, 11, 424-429, 10.1002/cctc.201801361
    

• A bidirectional screw‐sense induction of poly(quinoxaline‐2,3‐diyl)s that depends on the degree of polymerization
  • Yuuya Nagata, Tsuyoshi Nishikawa, Ken Terao, Hirokazu Hasegawa, and Michinori Suginome
  • J. Polym. Sci. Part A: Polym. Chem., 2019, 57, 260-263, 10.1002/pola.29224
    
  • This manuscript is dedicated to Professor Mitsuo Sawamoto's outstanding achievements in polymer chemistry and recognizes his recent retirement from 40 years of exceptional service to Kyoto University.
    • https://onlinelibrary.wiley.com/toc/10990518/2019/57/3

2018 †

• A Planar-Chiral Pillar[5]arene-Based Monophosphine Ligand with Induced Chirality at the Biaryl Axis
  • Yuuya Nagata, Yasuo Shimada, Tsuyoshi Nishikawa, Ryohei Takeda, Makoto Uno, Tomoki Ogoshi, and Michinori Suginome
  • Synlett, 2018, 29, 2167-2170, 10.1055/s-0037-1610635
    
  • This article has been published in SYNLETT issue 16/2018 in the cluster section, "Atropisomerism - in Memoriam Kurt Mislow".
  • This article was selected for the cover of SYNLETT.

• Enantiospecific Suzuki-Miyaura Coupling of Nonbenzylic α-(Acylamino)alkylboronic Acid Derivatives
  • Toshimichi Ohmura, Kyoko Miwa, Tomotsugu Awano, and Michinori Suginome
  • Chem. Asian J., 2018, 13, 2414–2417, 10.1002/asia.201800536
    
  • Special Issue: Homogeneous Catalysis from Young Investigators in Asia
  • Highlighted in Synfacts, 2018, 14, 1264, 10.1055/s-0037-16110113

• Abnormal Sergeants-and-Soldiers Effect of Poly(quinoxaline-2,3-diyl)s Enabling Discrimination of One-Carbon Homologous n-Alkanes through a Highly Sensitive Solvent-dependent Helix Inversion
  • Yuuya Nagata, Tsuyoshi Nishikawa, and Michinori Suginome
  • Chem. Comm., 2018, 54, 6867-6870, 10.1039/C8CC02836B
    
  • This article is part of the themed collection: 2018 Emerging Investigators

• Chirality-Amplifying, Dynamic Induction of Single-Handed Helix by Chiral Guests to Macromolecular Chiral Catalysts Bearing Boronyl Pendants as Receptor Sites
  • Takeshi Yamamoto, Ryo Murakami, Satoko Komatsu, and Michinori Suginome
  • J. Am. Chem. Soc., 2018, 140, 3867-3870, 10.1021/jacs.8b00529
    

• Elucidating the Solvent Effect on the Switch of the Helicity of Poly(quinoxaline-2,3-diyl)s: A Conformational Analysis by Small-Angle Neutron Scattering
  • Yuuya Nagata, Tsuyoshi Nishikawa, Michinori Suginome, Sota Sato, Masaaki Sugiyama, Lionel Porcar, Anne Martel, Rintaro Inoue, and Nobuhiro Sato
  • J. Am. Chem. Soc., 2018, 140, 2722-2726, 10.1021/jacs.7b11626
    

2017 †

• Palladium-Catalyzed β-Elimination of Aminoboranes from (Aminomethylsilyl)boranes Leading to the Formation of Silene Dimers
  • Toshimichi Ohmura, Hiroki Nishiura, and Michinori Suginome
  • Organometallics, 2017, 36, 4298–4304, 10.1021/acs.organomet.7b00695
    

• 4,4'-Bipyridine-Catalyzed Stereoselective trans-Diboration of Acetylenedicarboxylates to 2,3-Diborylfumarates
  • Toshimichi Ohmura, Yohei Morimasa, and Michinori Suginome
  • Chem. Lett., 2017, 46, 1793–1796, 10.1246/cl.170848 (Open Access)
    

• Asymmetric Cycloisomerization of o-Alkenyl-N-methylanilines to Indolines through Iridium-Catalyzed C(sp3)–H Addition to Carbon–Carbon Double Bonds
  • Takeru Torigoe, Toshimichi Ohmura, and Michinori Suginome
  • Angew. Chem. Int. Ed., 2017, 56, 14272–14276, 10.1002/anie.201708578
    
  • One of the Fifteen Most Accessed Articles (ACIE, Oct. 2017)
  • Selected as Synfact of the month (Jan. 2018), Synfacts, 2018, 14, 0039, 10.1055/s-0036-1591055

• Synthesis and Solution Properties of a Rigid Helical Star Polymer: Three-Arm Star Poly(quinoxaline-2,3-diyl)
  • Hirokazu Hasegawa, Yuuya Nagata, Ken Terao, and Michinori Suginome
  • Macromolecules, 2017, 50, 7491–7497, 10.1021/acs.macromol.7b01797
    

• Chirality-Switchable 2,2'-Bipyridine Ligands Attached to Helical Poly(quinoxaline-2,3-diyl)s for Copper-Catalyzed Asymmetric Cyclopropanation of Alkenes
  • Yukako Yoshinaga, Takeshi Yamamoto, and Michinori Suginome
  • ACS Macro Lett., 2017, 6, 705–710, 10.1021/acsmacrolett.7b00352
    

• Rhodium-Catalyzed C(sp2)–H Addition of Arylboronic Acids to Alkynes Using a Boron-Based, Convertible ortho-Directing Group
  • Takeshi Yamamoto, Aoi Ishibashi, and Michinori Suginome
  • Chem. Lett., 2017, 46, 1169-1172, 10.1246/cl.170404
    

• New Chiral Functions Based on the Dynamic Induction of Macromolecular Helical Chirality by Chiral Side Chains
  • Michinori Suginome, Yuuya Nagata, and Takeshi Yamamoto
  • J. Synth. Org. Chem. Jpn., 2017, 5, 476-490, 10.5059/yukigoseikyokaishi.75.476 (Japanese)

• Synthesis and Catalytic Applications of a Triptycene-Based Monophosphine Ligand for Palladium-Mediated Organic Transformations
  • Franco King-Chi Leung, Fumitaka Ishiwari, Yoshiaki Shoji, Tsuyoshi Nishikawa, Ryohei Takeda, Yuuya Nagata, Michinori Suginome, Yasuhiro Uozumi, Yoichi M. A. Yamada, and Takanori Fukushima
  • ACS Omega, 2017, 2, 1930-1937, 10.1021/acsomega.7b00200
    

• Poly(quinoxaline-2,3-diyl) as a Multifunctional Chiral Scaffold for Circularly Polarized Luminescent Materials: Color Tuning, Energy Transfer, and Switching of the CPL Handedness
  • Tsuyoshi Nishikawa, Yuuya Nagata, and Michinori Suginome
  • ACS Macro Lett., 2017, 6, 431–435, 10.1021/acsmacrolett.7b00131
    

• Utilization of a Trimethylsilyl Group as a Synthetic Equivalent of a Hydroxyl Group via Chemoselective C(sp3)–H Borylation at the Methyl Group on Silicon
  • Takeru Torigoe, Toshimichi Ohmura, and Michinori Suginome
  • J. Org. Chem., 2017, 82, 2943–2956, 10.1021/acs.joc.6b02917
    

• C–H Activation-Based Transformation of Naphthalenes to 3-Iodo-2-naphthylboronic Acid Derivatives for Use in Iterative Coupling Synthesis of Helical Oligo(naphthalene-2,3-diyl)s
  • Takeshi Yamamoto, Aoi Ishibashi, Masashi Koyanagi, Hideki Ihara, Nils Eichenauer, and Michinori Suginome
  • Bull. Chem. Soc. Jpn., 2017, 90, 604-606, 10.1246/bcsj.20170026
    

• Single-Handed Helical Poly(quinoxaline-2,3-diyl)s Bearing Achiral 4-Aminopyrid-3-yl Pendants as Highly Enantioselective, Reusable Chiral Nucleophilic Organocatalysts in the Steglich Reaction
  • Takeshi Yamamoto, Ryo Murakami, and Michinori Suginome
  • J. Am. Chem. Soc., 2017, 139, 2557–2560, 10.1021/jacs.6b12349
    

• Regioselective Synthesis of o-Benzenediboronic Acids via Ir-Catalyzed o-C–H Borylation Directed by a Pyrazolylaniline-Modified Boronyl Group
  • Takeshi Yamamoto, Aoi Ishibashi, and Michinori Suginome
  • Org. Lett., 2017, 19, 886–889, 10.1021/acs.orglett.7b00041
    

2016 †

• High-Pressure Circular Dichroism Spectroscopy up to 400 MPa Using Polycrystalline Yttrium Aluminum Garnet (YAG) as Pressure-Resistant Optical Windows
  • Yuuya Nagata, Ryohei Takeda, and Michinori Suginome
  • RSC Adv., 2016, 6, 109726-109729, 10.1039/C6RA23736C
    

• Iridium-Catalyzed Intramolecular Methoxy C–H Addition to Carbon–Carbon Triple Bonds: Direct Synthesis of 3-Substituted Benzofurans from o-Methoxyphenylalkynes
  • Takeru Torigoe, Toshimichi Ohmura, and Michinori Suginome
  • Chem. Eur. J., 2016, 22, 10415–10419, 10.1002/chem.201602152
    

• Three-Way-Switchable (Right/Left/OFF) Selective Reflection of Circularly Polarized Light on Solid Thin Films of Helical Polymer Blends
  • Yuuya Nagata, Makoto Uno, and Michinori Suginome
  • Angew. Chem., Int. Ed, 2016, 55, 7126 –7130, 10.1002/anie.201602035
    

• A (Borylmethyl)silane Bearing Three Hydrolyzable Groups on Silicon: Synthesis via Iridium-Catalyzed C(sp3)–H Borylation and Conversion to Functionalized Siloxanes
  • Toshimichi Ohmura, Ikuo Sasaki, Takeru Torigoe, and Michinori Suginome
  • Organometallics, 2016, 35, 1601–1603, 10.1021/acs.organomet.6b00316
    

• Solvent Effect on the Sergeants-and-Soldiers Effect Leading to Bidirectional Induction of Single-Handed Helical Sense of Poly(quinoxaline-2,3-diyl)s Copolymers in Aromatic Solvents
  • Yuuya Nagata, Tsuyoshi Nishikawa, and Michinori Suginome
  • ACS Macro Lett., 2016, 5, 519–522, 10.1021/acsmacrolett.6b00191
    

2015 †

• Poly(quinoxaline-2,3-diyl)s: A Fascinating Helical Macromolecular Scaffold for New Chiral Functions
  • Michinori Suginome, Takeshi Yamamoto, and Yuuya Nagata
  • J. Synth. Org. Chem. Jpn. 2015, 73, 1141-1155, 10.5059/yukigoseikyokaishi.73.1141
    

• Main-Chain Stiffness and Helical Conformation of a Poly(quinoxaline-2,3-diyl) in Solution
  • Yuuya Nagata, Hirokazu Hasegawa, Ken Terao, and Michinori Suginome
  • Macromolecules, 2015, 48, 7983–7989, 10.1021/acs.macromol.5b01919
    

• Majority-Rules-Type Helical Poly(quinoxaline-2,3-diyl)s as Highly Efficient Chirality-Amplification Systems for Asymmetric Catalysis
  • Yuan-Zhen Ke, Yuuya Nagata, Tetsuya Yamada, and Michinori Suginome
  • Angew. Chem., Int. Ed, 2015, 54, 9333–9337, 10.1002/anie.201502209
    

• Pressure-dependent Helix Inversion of Poly(quinoxaline-2,3-diyl)s Containing Chiral Side Chains in Non-aqueous Solvents
  • Yuuya Nagata, Ryohei Takeda, and Michinori Suginome
  • Chem. Commun., 2015, 51, 11182-11185, 10.1039/C5CC04255K (Open Access)
    

• Site- and Regioselective Silaborative C–C Cleavage of 1-Alkyl-2-Methylenecyclopropanes Using a Platinum Catalyst with a Sterically Demanding Silylboronic Ester
  • Toshimichi Ohmura, Hiroki Taniguchi, and Michinori Suginome
  • ACS Catal., 2015, 5, 3074–3077, 10.1021/acscatal.5b00513
    

• Asymmetric Suzuki–Miyaura cross-coupling of 1-bromo-2-naphthoates using the helically chiral polymer ligand PQXphos
  • Yuto Akai, Laure Konnert, Takeshi Yamamoto and Michinori Suginome
  • Chem. Commun., 2015, 51, 7211–7214, 10.1039/C5CC01074H
    

• Exerting Control over the Helical Chirality in the Main-Chain of Sergeants-and-Soldiers-Type Poly(quinoxaline-2,3-diyl)s by Changing from Random to Block Copolymerization Protocols
  • Yuuya Nagata, Tsuyoshi Nishikawa, and Michinori Suginome
  • J. Am. Chem. Soc., 2015, 137, 4070–4073, 10.1021/jacs.5b01422
    

• Organocatalytic Diboration Involving “Reductive Addition” of a Boron–Boron σ-Bond to 4,4’-Bipyridine
  • Toshimichi Ohmura, Yohei Morimasa, and Michinori Suginome
  • J. Am. Chem. Soc., 2015, 137, 2852–2855, 10.1021/jacs.5b00546
    
  • Highlighted in JACS Spotlights 10.1021/jacs.5b02133
  • Highlighted in Virtual Issue Posts on Organocatalysis http://pubs.acs.org/page/vi/organocatalysis

• Facile Preparation of Poly(quinoxaline-2,3-diyl)s via Aromatizing Polymerization of 1,2-Diisocyanobenenes Using Phosphine Complexes of Nickel(II) Salts
  • Yuuya Nagata, Yuan-Zhen Ke, and Michinori Suginome
  • Chem. Lett, 2015, 44, 53–55, 10.1246/cl.140909
    

2014 †

• Poly(quinoxaline-2,3-diyl)s Bearing (S)-3-Octyloxymethyl Side Chains as an Efficient Amplifier of Alkane Solvent Effect Leading to Switch of Main Chain Helical Chirality
  • Yuuya Nagata, Tsuyoshi Nishikawa, and Michinori Suginome
  • J. Am. Chem. Soc., 2014, 136, 15901–15904, 10.1021/ja509531t
  • Highlighted in JACS Spotlights 10.1021/ja511738n
    

• Chiral Palladacycle Catalysts Generated on a Single-Handed Helical Polymer Skeleton for Asymmetric Arylative Ring Opening of 1,4-Epoxy-1,4-dihydronaphthalene
  • Takeshi Yamamoto, Yuto Akai, and Michinori Suginome
  • Angew. Chem., Int. Ed, 2014, 53, 12785–12788.
    

• Ether Solvent-induced Chirality Inversion of Helical Poly(quinoxaline-2,3-diyl)s Containing L-Lactic Acid Derived Side Chains
  • Yuuya Nagata, Takuma Kuroda, Keisuke Takagi, and Michinori Suginome
  • Chem. Sci., 2014, 5, 4953-4956, 10.1039/C4SC01920B
    

• Chirality-switchable Circularly Polarized Luminescence in Solution Based on the Solvent-dependent Helix Inversion of Poly(quinoxaline-2,3-diyl)s
  • Yuuya Nagata, Tsuyoshi Nishikawa, and Michinori Suginome
  • Chem. Commun., 2014, 50, 9951-9953, 10.1039/C4CC03944K
    

• Solid Polymer Films Exhibiting Handedness-switchable, Full-color-tunable Selective Reflection of Circularly Polarized Light
  • Yuuya Nagata, Keisuke Takagi, and Michinori Suginome
  • J. Am. Chem. Soc., 2014, 136, 9858–9861, 10.1021/ja504808r
  • Highlighted in JACS Spotlights 10.1021/ja506476x
    

• Iridium-Catalysed Borylation of Sterically Hindered C(sp3)–H bonds: Remarkable Rate Acceleration by a Catalytic Amount of Potassium tert-Butoxide
  • Toshimichi Ohmura, Takeru Torigoe, and Michinori Suginome
  • Chem. Commun., 2014, 50, 6333-6336, 10.1039/C4CC01262C
    

2013 †

• Nickel-Catalyzed Cyclizative trans-Carboboration of Alkynes through Activation of Boron–Chlorine Bonds by Using Organometallic Reagents as Donors of Organic Groups
  • Masaki Daini, Akihiko Yamamoto, and Michinori Suginome
  • Asian J. Org. Chem., 2013, 2, 968-976, 10.1002/ajoc.201300164
    

• Functionalization of Tetraorganosilanes and Permethyloligosilanes at a Methyl Group on Silicon via Iridium Catalyzed C(sp3)–H Borylation
  • Toshimichi Ohmura, Takeru Torigoe, and Michinori Suginome
  • Organometallics 2013, 32, 6170-6173, 10.1021/om400900z
    

• Complementary Induction of Right- and Left-Handed Helical Structures by the Positioning of Chiral Groups on the Monomer Units: Introduction of (−)-Menthol as Side Chains of Poly(quinoxaline-2,3-diyl)s
  • Takeshi Yamamoto, Takumi Adachi, and Michinori Suginome
  • ACS Macro Lett., 2013, 2, 790-793, 10.1021/mz4003326
    

• Catalytic Borylation and Silylation of Unsaturated Organic Molecules: Reaction Control by Transition Metal Catalysts and Applications to Organic Synthesis (written in Japanese)
  • Toshimichi Ohmura
  • J. Synth. Org. Chem. Jpn. 2013, 71, 804-817, 10.5059/yukigoseikyokaishi.71.804
    

• Cycloaddition-based Formal C–H Alkynylation of Isoindoles Leading to the Synthesis of Air-stable Fluorescent 1,3-Dialkynylisoindoles
  • Toshimichi Ohmura, Akihito Kijima, Yusuke Komori, and Michinori Suginome
  • Org. Lett. 2013, 15, 3510–3513, 10.1021/ol401051d
    

• Solvent-Dependent Switch of Helical Main-Chain Chirality in Sergeants-and-Soldiers-Type Poly(quinoxaline-2,3-diyl)s: Effect of the Position and Structures of the “Sergeant” Chiral Units on the Screw-Sense Induction
  • Yuuya Nagata, Tetsuya Yamada, Takumi Adachi, Yuto Akai, Takeshi Yamamoto, and Michinori Suginome
  • J. Am. Chem. Soc., 2013, 135, 10104–10113, 10.1021/ja403391m
    

• Catalytic Asymmetric Synthesis with Chirality-Switchable Helical Polymer Ligands
  • Takeshi Yamamoto, Yuuya Nagata, and Michinori Suginome
  • J. Synth. Org. Chem. Jpn., 2013, 71, 461-471, 10.5059/yukigoseikyokaishi.71.461 (Japanese)
  • YamamotoSOCJ.png

• Anthranilamide-masked o-Iodoarylboronic Acids as Coupling Modules for Iterative Synthesis of ortho-Linked Oligoarenes
  • Masashi Koyanagi, Nils Eichenauer, Hideki Ihara, Takeshi Yamamoto, and Michinori Suginome
  • Chem. Lett., 2013, 42, 541-543, 10.1246/cl.130136
    

• Palladium-catalyzed Carboboration: Borylative Coupling of Alkynes with Alkenes through Activation of Boron Chlorine Bonds
  • Kanayo Nakada, Masaki Daini, and Michinori Suginome
  • Chem. Lett., 2013, 42, 538-540, 10.1246/cl.130131
    

• Synthesis of Cyclic Alkenylborates via Silaboration of Alkynes Followed by Hydrolysis for Utilization in External-Base-Free Cross Coupling
  • Toshimichi Ohmura, Kazuyuki Oshima, and Michinori Suginome
  • Organometallics 2013, 32, 2870-2873, 10.1021/om400138u
    

2012 †

• Arylboronic Acid Derivative Cross-Coupling Reactions
  • Michinori Suginome and Toshimichi Ohmura
  • Science of Synthesis Cross Coupling and Heck-Type Reactions 1, G. A. Molander Ed., Thieme, 2012, 147-201

• Catalytic Functionalization of Methyl Group on Silicon: Iridium-Catalyzed C(sp3)–H Borylation of Methylchlorosilanes
  • Toshimichi Ohmura, Takeru Torigoe, and Michinori Suginome
  • J. Am. Chem. Soc. 2012, 134, 17416-17419, 10.1021/ja307956w
    

• Solvent-dependent fluorescence and circular dichroism properties of poly(quinoxaline-2,3-diyl)s bearing pyrene pendants
  • Yuuya Nagata, Tsuyoshi Nishikawa, and Michinori Suginome
  • Chem. Commun., 2012, 48, 11193-11195, 10.1039/C2CC36275A
    

• Catalytic Asymmetric Synthesis Using Chirality-Switchable Helical Polymer as a Chiral Ligand
  • Michinori Suginome,Takeshi Yamamoto, Yuuya Nagata, Tetsuya Yamada, and Yuto Akai
  • Pure Appl. Chem., 2012, 84, 1759-1769, 10.1351/PAC-CON-11-08-23

• Dearomatizing conversion of pyrazines to 1,4-dihydropyrazine derivatives via transition-metal-free diboration, silaboration, and hydroboration
  • Kazuyuki Oshima, Toshimichi Ohmura, and Michinori Suginome
  • Chem. Commun. 2012, 48, 8571-8573, 10.1039/C2CC34086K
    

• Enhanced Catalyst Activity and Enantioselectivity with Chirality-Switchable Polymer Ligand PQXphos in Pd-Catalyzed Asymmetric Silaborative Cleavage of meso-Methylenecyclopropanes
  • Yuto Akai, Takeshi Yamamoto, Yuuya Nagata, Toshimichi Ohmura, and Michinori Suginome
  • J. Am. Chem. Soc., 2012, 134, 11092-11095, 10.1021/ja303506k
    

• Regioselective Synthesis of 1,2-Dihydropyridines by Rhodium-Catalyzed Hydroboration of Pyridines
  • Kazuyuki Oshima, Toshimichi Ohmura, and Michinori Suginome
  • J. Am. Chem. Soc. 2012, 134, 3699-3702, 10.1021/ja3002953
    

• Control of Helical Chirality of Poly(quinoxaline-2,3-diyl)s Based on Postpolymerization Modification of the Terminal Group by Small Chiral Molecules
  • Yuuya Nagata, Satoru Ohashi, and Michinori Suginome
  • J. Polym. Sci. Part A: Polym. Chem., 2012, 50, 1564–1571, 10.1002/pola.25926
  • Selected as Cover Image, 10.1002/pola.26030
    

2011 †

• 1,3,2-Dioxaborolane, 2-(dimethylphenylsilyl)-4,4,5,5-tetramethyl-
  • Toshimichi Ohmura and Michinori Suginome
  • Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, P. L. Fuchs Ed., Wiley, 2011, 270-276

• Transition Metal-Catalyzed Element-Boryl Additions to Unsaturated Organic Compounds
  • Michinori Suginome and Toshimichi Ohmura
  • Boronic Acids Second Edition, D. G. Hall Ed., Wiley, 2011, Vol 1, 171-212

• Inversion or Retention? Effects of Acidic Additives on the Stereochemical Course in Enantiospecific Suzuki–Miyaura Coupling of α-(Acetylamino)benzylboronic Esters
  • Tomotsugu Awano, Toshimichi Ohmura, and Michinori Suginome
  • J. Am. Chem. Soc. 2011, 133, 20738-20741, 10.1021/ja210025q
    

• (E)- and (Z)-β-Borylallylsilanes via Alkyne Silaboration Followed by Regio- and Stereoselective Double Bond Migration
  • Toshimichi Ohmura, Kazuyuki Oshima, and Michinori Suginome
  • Angew. Chem. Int. Ed. 2011, 50, 12501–12504, 10.1002/anie.201106077
    

• Highly Enantioselective Synthesis of Axially Chiral Biarylphosphonates: Asymmetric Suzuki–Miyaura Coupling Using High-Molecular-Weight, Helically Chiral Polyquinoxaline-Based Phosphines
  • Takeshi Yamamoto, Yuto Akai, Yuuya Nagata, and Michinori Suginome
  • Angew. Chem., Int. Ed, 2011, 50, 8844–8847, 10.1002/anie.201103792
    

• Synthesis of poly(quinoxaline-2,3-diyl)s with alkoxy side chains by aromatizing polymerization of 4,5-dialkoxy-substituted 1,2-diisocyanobenzenes
  • Yuuya Nagata and Michinori Suginome
  • J. Polym. Sci. Part A: Polym. Chem., 2011, 49, 4275–4282, 10.1002/pola.24871
    

• Ruthenium-Catalyzed C–H-Silylation of Methylboronic Acid Using a Removable α-Directing Modifier on the Boron Atom
  • Hideki Ihara, Akinori Ueda, and Michinori Suginome
  • Chem. Lett., 2011, 40, 916–918, 10.1246/cl.2011.916
    

• Dinuclear Palladium and Platinum Complexes with Bridging Silylene Ligands. Preparation Using (Aminosilyl)boronic Ester as the Ligand Precursor and Their Reactions with Alkynes
  • Makoto Tanabe, Jian Jiang, Hideto Yamazawa, Kohtaro Osakada, Toshimichi Ohmura, and Michinori Suginome
  • Organometallics 2011, 30, 3981-3991, 10.1021/om200156g
    

• Anthranilamide: A Simple, Removable Ortho-Directing Modifier for Arylboronic Acids Serving also as a Protective Group in Cross-Coupling Reactions
  • Hideki Ihara, Masashi Koyanagi, and Michinori Suginome
  • Org. Lett., 2011, 13, 2662-2665, 10.1021/ol200764g
    

• Palladium-Catalyzed Regioselective Silaboration of Pyridines Leading to the Synthesis of Silylated Dihydropyridines
  • Kazuyuki Oshima, Toshimichi Ohmura, and Michinori Suginome
  • J. Am. Chem. Soc. 2011, 133, 7324-7327, 10.1021/ja2020229
    

• Palladium-Catalyzed, Stereoselective, Cyclizative Alkenylboration of Carbon−Carbon Double Bonds through Activation of a Boron−Chlorine Bond
  • Masaki Daini and Michinori Suginome
  • J. Am. Chem. Soc., 2011, 133, 4758-4761, 10.1021/ja200856t
    

• 2-Vinylindoles As the Four-Atom Component in a Catalytic [4+1] Cycloaddition with a Silylene-Palladium Species Generated from (Aminosilyl)boronic Ester
  • Kohei Masuda, Toshimichi Ohmura, and Michinori Suginome
  • Organometallics 2011, 30, 1322-1325, 10.1021/om200135u
    

• Integrated Catalytic C−H Transformations for One-Pot Synthesis of 1-Arylisoindoles from Isoindolines via Palladium-Catalyzed Dehydrogenation Followed by C−H Arylation
  • Toshimichi Ohmura, Akihito Kijima, and Michinori Suginome
  • Org. Lett. 2011, 13, 1238-1241, 10.1021/ol2001232
    

2010 †

• Catalytic carboborations
  • Michinori Suginome
  • Chem. Rec. 2010, 10, 348–358, 10.1002/tcr.201000029
    

• Stereospecific Suzuki-Miyaura Coupling of Chiral α-(Acylamino)benzylboronic Esters with Inversion of Configuration
  • Toshimichi Ohmura, Tomotsugu Awano, and Michinori Suginome
  • J. Am. Chem. Soc. 2010, 132, 13191-13193, 10.1021/ja106632j
    

• Switch of Regioselectivity in Palladium-Catalyzed Silaboration of Terminal Alkynes by Ligand-Dependent Control of Reductive Elimination
  • Toshimichi Ohmura, Kazuyuki Oshima, Hiroki Taniguchi, and Michinori Suginome
  • J. Am. Chem. Soc. 2010, 132, 12194-12196, 10.1021/ja105096r
    

• Non-hydrogen-bonding-based, solvent-dependent helix inversion between pure P-helix and pure M-helix in poly(quinoxaline-2,3-diyl)s bearing chiral side chains
  • Tetsuya Yamada, Yuuya Nagata and Michinori Suginome
  • Chem. Commun. 2010, 46, 4914-4916, 10.1039/c001564d
    

• High-Molecular-Weight Polyquinoxaline-Based Helically Chiral Phosphine (PQXphos) as Chirality-Switchable, Reusable, and Highly Enantioselective Monodentate Ligand in Catalytic Asymmetric Hydrosilylation of Styrenes
  • Takeshi Yamamoto, Tetsuya Yamada, Yuuya Nagata and Michinori Suginome
  • J. Am. Chem. Soc. 2010, 132, 7899–7901, 10.1021/ja102428q
    

• Rhodium-catalyzed Dehydroborylation of Styrenes with Naphthalene-1,8-diaminatoborane [(dan)BH]: New Synthesis of Masked β-Borylstyrenes as New Phenylene–Vinylene Cross-coupling Modules
  • Noriyuki Iwadate and Michinori Suginome
  • Chem. Lett. 2010, 39, 558-560, 10.1246/cl.2010.558
    

• Nickel-Catalyzed Asymmetric Addition of Alkyne C-H Bonds across 1,3-Dienes Using Taddol-Based Chiral Phosphoramidite Ligands
  • Masamichi Shirakura and Michinori Suginome
  • Angew. Chem. Int. Ed. 2010, 49, 3827-3829, 10.1002/anie.201001188
    

• Synthesis of Helical Rod−Coil Multiblock Copolymers by Living Block Copolymerization of Isocyanide and 1,2-Diisocyanobenzene Using Arylnickel Initiators
  • Tetsuya Yamada and Michinori Suginome
  • Macromolecules 2010, 43, 3999-4002, 10.1021/ma100500r
    

• Langmuir–Blodgett films of helical rigid-rod poly(quinoxaline-2,3-diyl)s
  • Yoshihiko Ito, Toshiyuki Miyake, Michinori Suginome, Rie Katakura, Masaya Mitsuishi, and Tokuji Miyashita
  • Polym. J. 2010, 42, 406-410, 10.1038/pj.2010.14

• Recent Progress of Catalytic Hydroboration: Use of Copper and Iron Catalysts (written in Japanese)
  • Toshimichi Ohmura
  • Organometallic News 2010, 28, 28-28

• Differentially Protected Diboron for Regioselective Diboration of Alkynes: Internal-Selective Cross-Coupling of 1-Alkene-1,2-diboronic Acid Derivatives
  • Noriyuki Iwadate and Michinori Suginome
  • J. Am. Chem. Soc. 2010, 132, 2548-2549, 10.1021/ja1000642
    

• Chiral Arylnickel Complexes as Highly Active Initiators for Screw-Sense Selective Living Polymerization of 1,2-Diisocyanobenzenes
  • Tetsuya Yamada, Hiroyoshi Noguchi, Yuuya Nagata, and Michinori Suginome
  • J. Polym. Sci. Part A: Polym. Chem. 2010, 48, 898-904, 10.1002/pola.23842
    

2009 †

• Palladium-Catalyzed Silylene-1,3-Diene [4 + 1] Cycloaddition with Use of (Aminosilyl)boronic Esters as Synthetic Equivalents of Silylene
  • Toshimichi Ohmura, Kohei Masuda, Ichiro Takase, and Michinori Suginome
  • J. Am. Chem. Soc. 2009, 131, 16624-16625, 10.1021/ja907170p
    

• Nickel-Catalyzed Ring-Opening Hydroacylation of Methylenecyclopropanes: Synthesis of γ,δ-Unsaturated Ketones from Aldehydes
  • Hiroki Taniguchi, Toshimichi Ohmura, and Michinori Suginome
  • J. Am. Chem. Soc. 2009, 131, 11298-11299, 10.1021/ja9046894
    

• Kinetic Resolution of Racemic 1-Alkyl-2-methylenecyclopropanes via Palladium-Catalyzed Silaborative C–C Cleavage
  • Toshimichi Ohmura, Hiroki Taniguchi, and Michinori Suginome
  • Org. Lett. 2009, 11, 2880-2883, 10.1021/ol900829c
    

• Easily Attachable and Detachable ortho-Directing Agent for Arylboronic Acids in Ruthenium-Catalyzed Aromatic C−H Silylation
  • Hideki Ihara and Michinori Suginome
  • J. Am. Chem. Soc. 2009, 131, 7502-7503, 10.1021/ja902314v
    

• α-Amidobenzylation of Aryl and Alkenyl Halides via Palladium-catalyzed Suzuki-Miyaura Coupling with α-(Acylamino)benzylboronic Esters
  • Toshimichi Ohmura, Tomotsugu Awano, and Michinori Suginome
  • Chem. Lett. 2009, 38, 664-665, 10.1246/cl.2009.664
    

• Palladium-catalyzed intramolecular cyanoboration of allenes leading to the regioselective synthesis of β-cyanoallylboranes
  • Akihiko Yamamoto, Yuto Ikeda, and Michinori Suginome
  • Tetrahedron Lett. 2009, 50, 3168-3170, 10.1016/j.tetlet.2009.01.025
    

• Synthesis of 1-Borylisoindoles via Palladium-Catalyzed Dehydrogenation/C−H Borylation of Isoindolines
  • Toshimichi Ohmura, Akihito Kijima and Michinori Suginome
  • J. Am. Chem. Soc. 2009, 131, 6070-6071, 10.1021/ja901095h
    

• Synthesis of B-Protected β-Styrylboronic Acids via Iridium-Catalyzed Hydroboration of Alkynes with 1,8-Naphthalenediaminatoborane Leading to Iterative Synthesis of Oligo(phenylenevinylene)s
  • Noriyuki Iwadate and Michinori Suginome
  • Org. Lett. 2009, 11, 1899-1902, 10.1021/ol9003096
    

• Nickel-Catalyzed, Regio- and Stereoselective Hydroalkynylation of Methylenecyclopropanes with Retention of the Cyclopropane Ring, Leading to the Synthesis of 1-Methyl-1-Alkynylcyclopropanes
  • Masamichi Shirakura and Michinori Suginome
  • J. Am. Chem. Soc. 2009, 131, 5060-5061, 10.1021/ja900876w
    

• Synthesis of masked haloareneboronic acids via iridium-catalyzed aromatic C–H borylation with 1,8-naphthalenediaminatoborane (danBH)
  • Noriyuki Iwadate and Michinori Suginome
  • J. Organomet. Chem. 2009, 694, 1713-1717, 10.1016/j.jorganchem.2008.11.068
    

• Stereoselective Synthesis of cis-β-Methyl- and Phenyl-Substituted Alkenylboronates by Platinum-Catalyzed Dehydrogenative Borylation
  • Toshimichi Ohmura, Yuta Takasaki, Hideki Furukawa, and Michinori Suginome
  • Angew. Chem. Int. Ed. 2009, 48, 2372-2375, 10.1002/anie.200805406
    

• B(OMe)SUB{3}; as a Nonacidic Iminium Ion Generator in Mannich- and Ugi-Type Reactions
  • Yusuke Tanaka, Kousuke Hidaka, Tomoaki Hasui, and Michinori Suginome
  • Eur. J. Org. Chem. 2009, 8, 1148-1151, 10.1002/ejoc.200801190
    

• Nickel-Catalyzed Regioselective Hydroalkynylation of Styrenes: Improved Catalyst System, Reaction Scope, and Mechanism
  • Masamichi Shirakura and Michinori Suginome
  • Org. Lett. 2009, 11, 523-526, 10.1021/ol802475h
    

• Silylboranes as New Tools in Organic Synthesis
  • Toshimichi Ohmura and Michinori Suginome
  • Bull. Chem. Soc. Jpn. 2009, 82, 29-49, 10.1246/bcsj.82.29
    

• Helical Poly(quinoxaline-2,3-diyl)s Bearing Metal-Binding Sites as Polymer-Based Chiral Ligands for Asymmetric Catalysis
  • Takeshi Yamamoto and Michinori Suginome
  • Angew. Chem. Int. Ed. 2009, 48, 539-542, 10.1002/anie.200803719
    

2008 †

• Carbon-Silicon Bond Formation via Transition Metal-Catalyzed Reaction of Silylene Equivalents (Japanese)
  • Toshimichi Ohmura and Michinori Suginome
  • Keiso Kagaku Kyokaishi, 2008, 25, 32-35

• Iterative Suzuki-Miyaura cross-coupling reaction for the selective synthesis of oligoarenes
  • Michinori Suginome
  • Ekisho, 2008, 12, 296-305

• Palladium-Catalyzed Carboboration of Alkynes Using Chloroborane and Organozirconium Reagents
  • Masaki Daini and Michinori Suginome
  • Chem. Commun. 2008, 5224-5226, 10.1039/b809433k

• Diarylborinic Acid Derivatives as a Catalytic Iminium Ion Generator in the Mannich-Type Reaction Using Secondary Amines, Aldehydes, and Ketene Silyl Acetals
  • Yusuke Tanaka, Tomoaki Hasui, Michinori Suginome
  • Synlett 2008, 1239-1242, 10.1055/s-2008-1072724
    

• Nickel-Catalyzed Addition of C-H Bonds of Terminal Alkynes to 1,3-Dienes and Styrenes
  • Masamichi Shirakura and Michinori Suginome
  • J. Am. Chem. Soc. 2008 130, 5410-5411, 10.1021/ja800997j
    

• A Mechanism for the Palladium-Catalyzed Regioselective Silaboration of Allene: A Theoretical Study
  • Yoko Abe, Kei Kuramoto, Masahiro Ehara, Hiroshi Nakatsuji, Michinori Suginome, Masahiro Murakami and Yoshihiko Ito
  • Organometallics, 2008, 27, 1736-1742, 10.1021/om070110f
    

• "Synthetic organic chemistry" and "polymer science" of isocyanide
  • Michinori Suginome
  • Kobunshi, 2008, 57, 130-133

• Palladium-Catalysed cis- and trans-Silaboration of Terminal Alkynes: Complementary Access to Stereo-Defined Trisubstituted Alkenes
  • Toshimichi Ohmura, Kazuyuki Oshima and Michinori Suginome
  • Chem. Comm. 2008, 1416-1418, 10.1039/b800181b
    

• Palladium-Catalyzed trans- and cis-Carboboration of Alkynes Tethered to Chloroborane with Organozirconium Reagents: Ligand-Dependent Complementary Stereoselectivity
  • Masaki Daini, Akihiko Yamamoto, and Michinori Suginome
  • J. Am. Chem. Soc. 2008, 130, 2918-2919, 10.1021/ja711160h
    

• Synthetic Application of Intramolecular Cyanoboration on the Basis of Removal and Conversion of a Tethering Group by Palladium-Catalyzed Retro-Allylation
  • Toshimichi Ohmura, Tomotsugu Awano, Michinori Suginome, Hideki Yorimitsu, and Koichiro Oshima
  • Synlett 2008, 423-427, 10.1055/s-2008-1032075
    

• Silylboranes Bearing Dialkylamino Groups on Silicon as Silylene Equivalents: Palladium-Catalyzed Regioselective Synthesis of 2,4-Disubstituted Siloles
  • Toshimichi Ohmura, Kohei Masuda, and Michinori Suginome
  • J. Am. Chem. Soc. 2008, 130, 1526-1527, 10.1021/ja073896h
    

• Differentially Protected Benzenediboronic Acids: Divalent Cross-Coupling Modules for the Efficient Synthesis of Boron-Substituted Oligoarenes
  • Hiroyoshi Noguchi, Takayuki Shioda, Chih-Ming Chou, and Michinori Suginome
  • Org. Lett. 2008, 10, 377-380, 10.1021/ol702420x
    

2007 †

• Development of Boron-Based Reactions and Reagents for Organic Synthesis
  • Michinori Suginome
  • J. Synth. Org. Chem., Jpn. 2007, 65, 1048-1059

• Acid-Free, Aminoborane-Mediated Ugi-Type Reaction Leading to General Utilization of Secondary Amines
  • Yusuke Tanaka, Tomoaki Hasui, and Michinori Suginome
  • Org. Lett. 2007, 9, 4407-4410, 10.1021/ol701570c
    
• Synthesis and Helical Structure of Oligo(quinoline-2,3-diyl)s
  • Michinori Suginome, Hiroyoshi Noguchi and Masahiro Murakami
  • Chem. Lett. 2007, 36, 1036-1037, 10.1246/cl.2007.1036
    
• Palladium-Catalyzed Asymmetric Silaborative C-C Cleavage of meso-Methylenecyclopropanes
  • Toshimichi Ohmura, Hiroki Taniguchi, Yoshiyuki Kondo, and Michinori Suginome
  • J. Am. Chem. Soc. 2007, 129, 3518-3519, 10.1021/ja0703170
    
• Synthesis of Silylboronic Esters Functionalized on Silicon
  • Toshimichi Ohmura, Kohei Masuda, Hideki Furukawa, Michinori Suginome
  • Organometallics 2007, 26, 1291-1294, 10.1021/om0609867
    
• Boron-Masking Strategy for the Selective Synthesis of Oligoarenes via Iterative Suzuki-Miyaura Coupling
  • Hiroyoshi Noguchi, Kosho Hojo, Michinori Suginome
  • J. Am. Chem. Soc. 2007, 129, 758-759, 10.1021/ja067975p
    
• C-E Bond Formation through Element-Element Addition to Carbon-Carbon Multiple Bonds
  • Michinori Suginome, Takanori Matsuda, Toshimichi Ohmura, Atsushi Seki, Masahiro Murakami
  • In Comprehensive Organometallic Chemistry III; Crabtree, R. and Mingos, M. Eds.; Ojima, I. Vol. Ed.; Elsevier, 2007; Volume 10, pp 725-787

2006 †

• Nickel-Catalyzed Addition of Alkynylboranes to Alkynes
  • Michinori Suginome, Masamichi Shirakura, Akihiko Yamamoto
  • J. Am. Chem. Soc. 2006, 128, 14438-14439
    
• Palladium-Catalyzed Asymmetric Silaboration of Allenes
  • Toshimichi Ohmura, Hiroki Taniguchi, Michinori Suginome
  • J. Am. Chem. Soc. 2006, 128, 13682-13683
    
• Ligand-Controlled, Complementary Stereoselectivity in the Platinum-Catalyzed Intramolecular Silaboration of Alkenes
  • Toshimichi Ohmura, Hideki Furukawa, Michinori Suginome
  • J. Am. Chem. Soc. 2006, 128, 13366-13367
    
• Aminoboranes as New Iminium Ion Generators in Amination Reactions
  • Michinori Suginome
  • Pure Appl. Chem. 2006, 78, 1377-1387
• Reductive amination of aldehydes using aminoboranes as iminium ion generators
  • Michinori Suginome, Yusuke Tanaka, Tomoaki Hasui
  • Synlett 2006, 1047-1050
    
• Asymmetric Silaboration of Terminal Allenes Bearing α-Stereogenic Centers: Stereoselection Based on "Reagent Control"
  • Toshimichi Ohmura and Michinori Suginome
  • Org. Lett. 2006, 8, 2503-2506
    
• Reactions of Cyanoboranes with a Palladium-PMeSUB{3}; Complex: Mechanism for the Catalytic Cyanoboration of Alkynes
  • Michinori Suginome, Akihiko Yamamoto, Taisuke Sasaki, Masahiro Murakami
  • Organometallics 2006, 25, 2911-2913
    

2005 †

• Nickel-Catalyzed trans-Alkynylboration of Alkynes via Activation of a Boron-Chlorine Bond
  • Akihiko Yamamoto, Michinori Suginome
  • J. Am. Chem. Soc. 2005, 127, 15706-15707

• Intramolecular Cyanoboration of Alkynes via Activation of Boron-Cyanide Bonds by Transition Metal Catalysts
  • Michinori Suginome, Akihiko Yamamoto, Masahiro Murakami
  • J. Organomet. Chem. 2005, 690, 5300-5308

• Carbon-carbon bond formation using boron. Design, creation, and new reactions of functional boron reagents
  • Michinori Suginome
  • Kagaku to Kogyo, 2005, 58, 919-922

• New development of organosilicon compound synthesis
  • Toshimichi Ohmura and Michinori Suginome
  • Kagaku, 2005, 60, 68-69

• Stereoselective Synthesis of Highly Enantioenriched (E)-Allylsilanes by Palladium-Catalyzed Intramolecular Bis-Silylation: 1,3-Chirality Transfer and Enantioenrichment via Dimer Formation
  • Michinori Suginome, Taisuke Iwanami, Yutaka Ohmori, Akira Matsumoto, Yoshihiko Ito
  • Chem. Eur. J. 2005, 11, 2954-2965

• Palladium-Catalyzed Addition of Cyanoboranes to Alkynes Leading to Regio- and Stereoselective Synthesis of β-Boryl-α,β-Unsaturated Nitriles
  • Michinori Suginome, Akihiko Yamamoto, Masahiro Murakami
  • Angew. Chem. Int. Ed. 2005, 44, 2380-2382

• Synthesis and Reactions of Cyclic Silylboranes
  • Michinori Suginome, Hiroyoshi Noguchi, Tomoaki Hasui, Masahiro Murakami
  • Bull. Chem. Soc. Jpn. 2005, 78, 323-326

• Synthesis and Structural Analysis of Oligo(naphthalene-2,3-diyl)s
  • Takahisa Motomura, Hideko Nakamura, Michinori Suginome, Masahiro Murakami, and Yoshihiko Ito
  • Bull. Chem. Soc. Jpn. 2005, 78, 142-146

2004 †

• Aminoboranes as "Compatible" Iminium Ion Generators in Aminative C-C Bond Formations
  • Michinori Suginome, Lars Uehlin, and Masahiro Murakami
  • J. Am. Chem. Soc. 2004, 126, 13196-13197

• A New Look at Boron Enolate Chemistry: Aminative C-C Bond Formation Using Diaminoboron Enolate with Aldehyde
  • Michinori Suginome, Lars Uehlin, Akihiko Yamamoto, and Masahiro Murakami
  • Org. Lett. 2004, 6, 1167-1169.

2003 †

• Enantioface-Selective Palladium-Catalyzed Silaboration of Allenes via Double Asymmetric Induction
  • Michinori Suginome, Toshimichi Ohmura, Yoshihiro Miyake, Shin’ichirou Mitani, Yoshihiko Ito, Masahiro Murakami
  • J. Am. Chem. Soc. 2003, 125, 11174-11175.

• Palladium- and Nickel-Catalyzed Intramolecular Cyanoboration of Alkynes
  • Michinori Suginome, Akihiko Yamamoto, Masahiro Murakami
  • J. Am. Chem. Soc. 2003, 125, 6358-6359.

2002 †

• Bis(dialkylamino)cyanoboranes: highly efficient reagents for the Strecker-type aminative cyanation of aldehydes and ketones.
  • M. Suginome, A. Yamamoto, Y. Ito
  • Chem. Comm. 2002, 1392-1393.

• Nickel-Catalyzed Silaboration of Small-Ring Vinylcycloalkanes: Regio- and Stereoselective(E)-Allylsilane Formation via C-C Bond Cleavage.
  • M. Suginome, T. Matsuda, T. Yoshimoto, Y. Ito
  • Organometallics 2002, 21, 1537-1539.

• 1,2-Azaboretidine Formation in the Reactions of (Boryl)(silyl)iminomethanes via Possible Generation of (Amino)(boryl)carbene Species
  • M. Suginome, T. Fukuda, Y. Ito
  • J. Organomet. Chem. 2002, 643-644, 508-511. (Special issue dedicated to Prof. F. Mathey)

• Highly Effective, Easily Accessible Screw-Sense-Determining End Group in theAsymmetric Polymerization of 1,2-Diisocyanobenzenes.
  • M. Suginome, S. Collet, Y. Ito
  • Org. Lett. 2002, 4, 351-354.

2001 †

• Stereoselective construction of trans-1,2-benzooxadecaline frameworks by three-component cascade reactions of an a-phenethyl-b-borylallylsilane with aldehydes
  • M. Suginome, Y. Ohmori, Y. Ito
  • Chem. Commun. 2001, 1090-1091.

• Solid-Phase Synthesis and Asymmetric Reactions of Polymer-Supported Highly Enantioenriched Allylsilanes
  • M. Suginome, T. Iwanami, and Y. Ito
  • J. Am. Chem. Soc. 2001, 123, 4356-4357.

• Asymmetric Synthesis of Cyclic Alkenes via Cyclization of Enantioenriched Allylsilanes
  • M. Suginome, T. Iwanami, A. Yamamoto, and Y. Ito
  • Synlett 2001, 1042-1045.

• β-Borylallylsilanes as a New Tool for Convenient Synthesis of Alkenylboranes
  • M. Suginome, Y. Ohmori, and Y. Ito
  • J. Am. Chem. Soc. 2001, 123, 4601-4602.

2000 †

• Palladium- and Platinum-Catalyzed Silaboration of Methylenecyclopropanes through Selective Proximal or Distal C-C Bond Cleavage
  • M. Suginome, T. Matsuda, and Y. Ito
  • J. Am. Chem. Soc. 2000, 122, 11015-11016.

• Convenient Preparation of Silylboranes
  • M. Suginome, T. Matsuda, and Y. Ito
  • Organometallics 2000, 19, 4647-4649.

• First Synthesis and Resolution of a Planar-chiral Tetrahydroindolyl Complex of Iron: Electronic Tuning of Reactivity and Enantioselective Nucleophilic Catalysis
  • M. Suginome and G. C. Fu
  • Chirality 2000, 12, 318-324.

• Palladium-Catalyzed Regioselective Silaboration of 1,2-Dienes
  • M. Suginome, Y. Ohmori, Y. Ito
  • J. Organomet. Chem. 2000, 611, 403-413. (Special issue: The Chemistry of Interelement Linkage)

• Structural Modification of Living Polymers: Synthesis of Helical Block Copolymers from a Single Monomer via Palladium-Mediated Aromatizing Polymerization of 1,2-Diisocyanobenzenes
  • Y, Ito, T. Miyake, M. Suginome
  • Macromolecules 2000, 33, 4034-4038.

• Synthesis of (Boryl)(silyl)iminomethanes by Insertion of Isonitriles into Silicon-Boron Bonds
  • M. Suginome, T. Fukuda, H. Nakamura, Y. Ito
  • Organometallics 2000, 19, 719-721.

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