Masahiro Murakami
-
Photo-Driven Dehydrogenative Homo-Coupling of Benzylic C–H Bonds Forming Strained C–C Bonds
-
Photoinduced Direct Addition of Alkylarenes to Imines
-
Photoinduced Reaction of Triarylphosphines with Alkenes Forming Fused Tricyclic Phosphonium Salts
-
Visible Light-Driven Dehydrogenative Coupling of Primary Alcohols with Phenols Forming Aryl Carboxylates
-
Photocatalytic Cycloaddition Reaction of Triarylphosphines with Alkynes Forming Cyclic Phosphonium Salts
-
Photoinduced Carbamoylation of C(sp3)–H Bonds with Isocyanates
-
Planar chiral 2-(trifluoromethyl)quinoline-fused ferrocenes via palladium(0)-catalysed C–H functionalization of trifluoroacetimidoyl chlorides
-
Pd-Catalyzed Ring-Closing/Ring-Opening Cross Coupling Reactions: Enantioselective Diarylation of Unactivated Olefins
-
Isomerization of Unprotected Aldoses to 2-Deoxyaldonic Acids Induced by Visible Light/Quinuclidine/Water-Soluble Iridium Complex in Water
-
Photo-Induced Dihydroxylation of Alkenes with Diacetyl, Oxygen, and Water
-
Dehydrative/Decarboxylative Coupling of Carboxylic Acids with Allylic Alcohols
-
Sustainable System for Hydrogenation Exploiting Energy Derived from Solar Light
-
Stereo- and Enantioselective Synthesis of Propionate-Derived Trisubstituted Alkene Motifs
-
Photoinduced Dearomatizing Three-component Coupling of Arylphosphines, Alkenes, and Water
-
Achievements of the Late Professor Teruaki Mukaiyama
-
Regioselective 1,3-Dipolar Cycloaddition of Nitriles with Nitrile Imines Generated from Tetrazoles
-
Cleavage of Carbon-Carbon σ-Bonds of Four-Membered Rings
-
Nickel-Catalyzed α-1,3-Dienylation of 1,3-Dicarbonyl Compounds with Propargylic Carbonates
-
Synthesis of Alkyl Sulfones from Alkenes and Tosylmethylphosphonium Iodide through Photo-Promoted C-C Bond Formation
-
Degradation of Unprotected Aldohexonic Acids to Aldopentoses Promoted by Light and Oxygen
-
Chiral Macrocycles Having C3 Symmetry Resulting from Orientation of Thiophene Rings
-
Photoinduced Specific Acylation of Phenolic Hydroxy Groups with Aldehydes
-
Dehydrative Allylation of α C(sp3)-H Bonds of Alkylamines with Allylic Alcohols
-
A One-Pot Reaction of α-Imino Rhodium Carbenoids and Halohydrins: Access to 2,6-Substituted Dihydro-2H-1,4-oxazines
-
Dehydrative Allylation of 2-Alkylbenzophenones with Allylic Alcohols
-
Dehydrogenative Coupling of Benzylic and Aldehydic C–H Bonds
-
C-1 Oxidation/C-2 Reduction Isomerization of Unprotected Aldoses Induced by Light/Ketone
-
Carboxylation of Benzylic and Aliphatic C-H Bonds with CO2 Induced by Light/Ketone/Nickel
-
Synthesis of Tofisopam by Way of Photoinduced CO2 Fixation
-
Asymmetric Synthesis and Stereochemical Assignment of 12C/13C Isotopomers
-
Photo-Assisted Fixation of CO2 onto Aryl Bromides Producing Aromatic Esters
-
Diastereo- and Enantioselective Synthesis of (E)-δ-Boryl-Substituted anti-Homoallylic Alcohols in Two Steps from Terminal Alkynes
-
A Strained Vicinal Diol as a Reductant for Coupling of Organyl Halides
-
Generation of Boron Aza-Enolates by a Nickel-Catalyzed Reaction of Triazoles with Pinacolborane and Their Addition to Aldehydes
-
Cyclization Reaction of 4-Acyl-1,2,3-triazoles Possessing Phenyl Rings through Generation of Electron-Deficient CarbenoidsPreparation of Ni(cod)2 Using Light as the Source of Energy
-
Photoinduced 1,2-Hydro(cyanomethylation) of Alkenes with a Cyanomethylphosphonium Ylide
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Light/Palladium-Promoted Benzylic C–H Acylation Using a Benzoyl Group as the Photo-Directing Group
-
Synthesis of γ-Boryl-Substituted Homoallylic Alcohols with Anti Stereochemistry Based on a Double-Bond Transposition Protocol
-
Synthesis of 2-Aryloxy-1,3-Dienes from Phenols and Propargyl Carbonates
-
Light/Copper Relay for Aerobic Fragmentation of Lignin Model Compounds
-
Synthesis of Fused and Linked Benzofurans from 2-Alkynylphenol Derivatives through Rhodium(I)-catalyzed Domino-type Addition Reactions
-
Synthesis of Elongated Esters from Alkenes
-
2-Arylsilacyclobutane as a Latent Carbanion Reacting with CO2
-
Enantioselective Denitrogenative Annulation of 1H-Tetrazoles with Styrenes Catalyzed by Rhodium
-
Photo-Catalyzed Ortho-Alkylation of Pyridine N-Oxides through Alkene Cleavage
-
Site- and Regio-Selective Incorporation of Carbon Dioxide into the C(sp2)–Si Bond of Benzosilacyclobutenes
-
Synthetic Approach to Benzocyclobutenones Using Visible Light and a Phosphonate Auxiliary
-
Palladium-Catalyzed Dehydrogenative Coupling Reaction of Terminal Alkynes with Unactivated Alkenes
-
Selective Functionalization of Aromatic C(sp2)–H Bonds in the Presence of Benzylic C(sp3)–H Bonds by Electron-Deficient Carbenoid Generated from 4-Acyl-1-sulfonyl-1,2,3-triazoles
-
β-Scission of Alkoxy Radicals in Synthetic Transformations
-
Palladium-Catalyzed Intermolecular Exchange between C–C and C–Si σ-Bonds
-
Enantioselective Synthesis of anti-1,2-Oxaborinan-3-enes from Aldehydes and 1,1-Di(boryl)alk-3-enes Using Ruthenium and Chiral Phosphoric Acid Catalysts
-
Photo-Induced Cyclization of (o-Alkylbenzoyl)phosphonates to Benzocyclobutenols
-
Enantioselective Synthesis of (E)-δ-Boryl-Substituted anti-Homoallylic Alcohols Using Palladium and a Chiral Phosphoric Acid
-
Cooperation of a Nickel-Bipyridine Complex with Light for Benzylic C–H Arylation of Toluene Derivatives
-
A shortcut to molecular complexity
-
Synthesis of Enantiopure C3-Symmetric Triangular Molecules
-
Acceleration of Inward Ring Opening of 3-Phosphorylcyclobutenes
-
Synthesis of 2-Substituted 2-Amino Ketones by Rhodium-Catalyzed Reaction of N-Sulfonyl-1,2,3-triazoles with 2-Alkenols
-
Buttressing Salicylaldehydes: Multipurpose Directing Group for C(sp3)–H Bond Activation
-
Synthesis of Penta-2,4-dien-1-imines and 1,2-Dihydropyridines by Rhodium-Catalyzed Reaction of N-Sulfonyl-1,2,3-triazoles with 2-(Siloxy)furans
-
Aryl Ketones as Single-Electron Transfer Photoredox Catalysts in Nickel-Catalyzed Homo-Coupling of Aryl Halides
-
Potential of Metal-Catalyzed C–C Single Bond Cleavage for Organic Synthesis
-
Asymmetric Synthesis of Cyclopropylmethanamines by Rhodium-Catalyzed Cyclopropanation of Pinacol Allylboronate with N-Sulfonyl-1,2,3-triazoles
-
A syn-Selective Aza-Aldol Reaction of Boron Aza-Enolates Generated from N-Sulfonyl-1,2,3-Triazoles and 9-BBN-H
-
A Light/Ketone/Copper System for Carboxylation of Allylic C–H Bonds of Alkenes with CO2
-
Ruthenium-Catalyzed Cycloisomerization of 2,2'-Diethynylbiphenyls Involving Cleavage of a Carbon-Carbon Triple Bond
-
Cleavage of Carbon–Carbon Single Bonds by Transition Metals
-
Light-Driven Carboxylation of o-Alkylphenyl Ketones with CO2
-
Hydrogenolysis of 1-Alkoxybenzocyclobutenes with Site-Selective Cleavage of the Sterically Hindered C(sp2)–C(sp3) Bond
-
Rhodium-Catalyzed Dehydrogenative Borylation of Aliphatic Terminal Alkenes with Pinacolborane
-
Site-Selective Introduction of an Enamido Group at the C(3)-Position of Indoles
-
A Reaction of Triazoles with Thioesters Producing β-Sulfanyl Enamides by Insertion of an Enamine Moiety into the Sulfur-Carbonyl Linkage
-
Palladium-Catalyzed Intramolecular Insertion of Alkenes into the Carbon–Nitrogen Bond of β-Lactams
-
Thermal Reaction of 4-(p-Aminophenyl)-1-sulfonyl-1,2,3-triazoles Furnishing Benzoyl Cyanides Through N-Sulfinyl Imine Intermediates
-
Enantioselective Construction of 3-Hydroxypiperidine Scaffolds by Sequential Action of Light and Rhodium upon N-Allylglyoxylamides
-
Ring-Opening Fluorination of Cyclobutanols and Cyclopropanols Catalyzed by Silver
-
Facile Synthesis of 2,5-Disubstituted Thiazoles from Terminal Alkynes, Sulfonyl Azides, and Thionoesters
-
Synthesis of α,β,γ,δ-Unsaturated Imines from N-Sulfonyl-1,2,3-triazoles and Allenes through Rhodium-Catalyzed Cyclopropanation and Thermal Rearrangement
-
Reactions of Alkynylboron Compounds
-
Development of New Synthetic Methods Based upon Carbon–Carbon Bond Activation
-
Construction of tetralin skeletons based on rhodium-catalysed site-selective ring opening of benzocyclobutenols
-
Synthesis of Acylphosphonates by a Palladium-Catalyzed Phosphonocarbonylation Reaction of Aryl Iodides with Phosphites
-
Synthesis of trans-Cycloalkenes via Enantioselective Cyclopropanation and Skeletal Rearrangement
-
Direct Synthesis of 2,5-Dihydropyrroles from Terminal Alkynes, Azides, and Propargylic Alcohols by Relay Actions of Copper, Rhodium, and Gold
-
Asymmetric Synthesis of Planar Chiral Ferrocenes by Enantioselective Intramolecular C−H Arylation of N-(2-Haloaryl)ferrocenecarboxamides
-
The stereoselective synthesis of α-amino aldols starting from terminal alkynes
-
Direct Production of Enaminones from Terminal Alkynes via Rhodium-Catalyzed Reaction of Formamides with N-Sulfonyl-1,2,3-triazoles
-
Enantioselective Insertion of a Carbenoid Carbon into a C–C Bond to Expand Cyclobutanols to Cyclopentanols
-
Construction of Homoallylic Alcohols from Terminal Alkynes and Aldehydes with Installation of syn-Stereochemistry
-
Cleavage of C-C and C-Si σ-Bonds and Their Intramolecular Exchange
-
Intramolecular Dearomatizing [3+2] Annulation of α-Imino Carbenoids with Aryl Rings Furnishing 3,4-Fused Indole Skeletons
-
Stereospecific ring expansion from orthocyclophanes with central chirality to metacyclophanes with planar chirality
-
sp3–sp2 vs sp3–sp3 C–C Site-Selectivity in Rh-Catalyzed Ring Opening of Benzocyclobutenol: A DFT Study
-
1,5-Rhodium Shift in Rearrangement of N-Arenesulfonylazetidin-3-ols into Benzosultams
-
Reactivity Change of Cyclobutanols towards Isocyanates: Rhodium Favors C-Carbamoylation over O-Carbamoylation
-
Doyle-Kirmse Reaction Using Triazoles Leading to One-pot Multi-functionalization of Terminal Alkynes
-
Stereoselective Synthesis of 2,3-Dihydropyrroles from Terminal Alkynes, Azides, and α,β-Unsaturated Aldehydes via N-Sulfonyl-1,2,3-triazoles
-
Pyridine-Directed Palladium-Catalyzed Phosphonation of C(sp2)-H Bonds
-
Construction of Indole Skeletons by Sequential Actions of Sunlight and Rhodium on α-Amino Acetophenones
-
The Mukaiyama Aldol Reaction: 40 Years of Continuous Development
-
Enantioselective Synthesis of anti-Homoallylic Alcohols from Terminal Alkynes and Aldehydes Based on Concomitant Use of a Cationic Iridium Complex/a Chiral Phosphoric Acid
-
Regiocontrolled Synthesis of Polysubstituted Pyrroles Starting from Terminal Alkynes, Sulfonyl Azides, and Allenes
-
Azulenophenanthrenes from 2,2′-Di(arylethynyl)biphenyls through C-C Bond Cleavage of a Benzene Ring
-
Oxidative Addition of a Strained C−C Bond onto Electron-Rich Rhodium(I) at Room Temperature
-
Nickel-Catalyzed [2+2+2] Cycloaddition Reaction of Isocyanates with 1,3-Dienes
-
One-Pot Procedure for the Introduction of Three Different Bonds onto Terminal Alkynes through N-Sulfonyl-1,2,3-Triazole Intermediates
-
Regioselective Construction of Indene Skeletons by Palladium-Catalyzed Annulation of Alkynylborates with o-Iodophenyl Ketones
-
Synthesis of Azaaromatic-Borane Intramolecular Complexes by Palladium-Catalyzed Reaction of Azaaromatic Halides with Alkynyltriarylborates
-
Solar-Driven Incorporation of Carbon Dioxide into α-Amino Ketones
-
Rhodium-Catalyzed Ring Opening of Benzocyclobutenols with Site-Selectivity Complementary to Thermal Ring Opening
-
Synthesis of Enaminones by Rhodium-Catalyzed Denitrogenative Rearrangement of 1-(N-Sulfonyl-1,2,3-triazole-4-yl)alkanols
-
Copper-Catalyzed Amination of Silyl Ketene Acetals with N-Chloroamines
-
Synthesis of (1H)-Isochromen-1-imines by Nickel-catalyzed Reaction of 2-Iodobenzamides with Alkynes
-
Synthesis of Enantiopure Dehydropiperidinones from α-Amino Acids and Alkynes via Azetidin-3-ones
-
Intramolecular σ-Bond Metathesis Between Carbon–Carbon and Silicon-Silicon Bonds
-
Atom- and Step-Economical Pathway to Chiral Benzobicyclo[2.2.2]octenones through Carbon-Carbon Bond Cleavage
-
Synthesis of 3,3-disubstituted α-tetralones by rhodium-catalysed reaction of 1-(2-haloaryl)cyclobutanols
-
Synthesis of α-Amino Ketones from Terminal Alkynes via Rhodium-Catalyzed Denitrogenative Hydration of N-Sulfonyl-1,2,3-triazoles
-
Rhodium-Catalyzed Reaction of 1-Alkenylboronates with Aldehydes Leading to Allylation Products
-
Selective 1:2 Coupling of Aldehydes and Allenes with Control of Regiochemistry
-
Synthesis of Phenanthridinones and Phenanthridine Derivatives through Palladium-Catalyzed Oxidative C–H Coupling of Benzanilides
-
Gold-catalysed alkenyl- and arylsilylation reactions forming 1-silaindenes
-
Nickel-Catalyzed Synthesis of 1,3,5-Trisubstituted Hydantoins from Acrylates and Isocyanates
-
Synthesis of Pyridine-N-oxide–Borane Intramolecular Complexes by Palladium-Catalyzed Reaction of 2-Bromopyridine-N-oxides with Alkynyltriarylborates
-
Synthesis of Cross-Conjugated Trienes by Rhodium-Catalyzed Dimerization Reaction of Monosubstituted Allenes
-
Synthesis of Chiral N-Heterocyclic Carbene Ligands with Rigid Backbones and Application to the Palladium-Catalyzed Enantioselective Intramolecular α-Arylation of Amides
-
Palladium-Catalyzed Denitrogenation Reaction of 1,2,3-Benzotriazin-4(3H)-ones Incorporating Isocyanides
-
Metal-catalysed cleavage of carbon–carbon bonds
-
Synthesis of Pyrenes by Twofold Hydroarylation of 2,6-Dialkynylbiphenyls
-
Rhodium-catalyzed restructuring of carbon frameworks
-
Synthesis of Pyridine-Borane Complexes via Electrophilic Aromatic Borylation
-
Palladium-Catalyzed Allylation Reaction of Alkynylborates
-
Enantioselective [2+2+2] Cycloaddition Reaction of Isocyanates and Allenes Catalyzed by Nickel
-
Hydrosilylation-Metathesis Sequence Leading to 1-Silaindenes
-
Stereoselective Synthesis of 3-(1-Cyanoalkylidene)oxindoles by Palladium-Catalyzed Cyclization Reaction of 2-(Alkynyl)aryl Isocyanates with Copper(I) Cyanide
-
Synthesis of 3,3-Disubstituted Oxindoles by Palladium-Catalyzed Tandem Reaction of 2-(Alkynyl)aryl Isocyanates with Benzylic Alcohols
-
Substituent Effect of Group 14 Elements on the Ring-Opening Reaction of Cyclobutenes
-
Stereoselective Synthesis of Vinyl-Substituted (Z)-Stilbenes by Rhodium-Catalysed Addition of Arylboronic Acids to Allenic Alcohols
-
Nickel-Catalyzed Denitrogenative Annulation Reaction of 1,2,3,4-Benzotriazin-4(3H)-ones with 1,3-Dienes and Alkenes
-
Development of Catalytic Reactions Triggered by Addition of Arylrhodium(I) Species across Alkynes
-
Iterative Approach to Oligo(arylenevinylene)s Containing Tetrasubstituted Vinylene Units
-
Nickel-Catalyzed Regio- and Enantioselective Annulation Reaction of 1,2,3,4-Benzothiatriazine-1,1(2H)-diones with Allenes
-
Synthesis of Functionalized Isoindoles by the Rhodium-Catalyzed Reaction of Cyanoformates with ortho-Borylbenzalacetone Derivatives
-
Ruthenium-Catalyzed trans-Hydrogermylation of Alkynes: Formation of 2,5-Disubstituted Germoles through Double trans-Hydrogermylation of 1,3-Diynes
-
Enantioselective Synthesis of 3,4-Dihydroisoquinolin-1(2H)-ones by Nickel-Catalyzed Denitrogenative Annulation of 1,2,3-Benzotriazin-4(3H)-ones with Allenes
-
Preparation of 2-Sulfonyl-1,2,3-triazoles by Base-Promoted 1,2-Rearrangement of a Sulfonyl Group
-
Stereoselective Restrucuring of 3-Arylcyclobutanols into 1-Indanols by Sequential Breaking and Formation of Carbon-Carbon Bonds
-
Synthesis of Stereodifined 3-Alkylideneoxindoles by Palladium-catalyzed Reactions of 2-(Alkynyl)aryl Isocyanoates with Thiols and Alcohols
-
Stereoselective Synthesis of (E)-(Trisubstituted alkenyl)borinic Esters: Stereochemistry Reversed by Ligand in the Palladium-Catalyzed Reaction of Alkynylborates with Aryl Halides
-
Stereoselective Synthesis of syn-Configured α-Allenols by Rhodium-Catalyzed Reaction of Alkynyl Oxiranes with Arylboronic Acids
-
Stereoselective Oxindole Synthesis by Palladium-Catalyzed Cyclization Reaction of 2-(Alkynyl)aryl Isocyanates with Amides
-
Synthesis of Oxindoles by Palladium-Catalyzed C-H Bond Amidation
-
Nickel-Catalysed Denitrogenative Alkyne Insertion Reaction of N-Sulfonyl-1,2,3-triazoles
-
Palladium-Catalyzed Sequential Carbon–Carbon Bond Cleavage/Formation Producing Arylated Benzolactones
-
Stereoselective Synthesis of 3-Alkylideneoxindoles by Palladium-Catalyzed Cyclization Reaction of 2-(Alkynyl)aryl Isocyanates with Organoboron Reagents
-
Rhodium-Catalysed Cyclisation Reaction of Allenynes with Arylboronic Acids
-
Synthesis of gem-Difluoroalkenes via β-Fluoride Elimination of Organorhodium(I)
-
Reaction of 2-Alkynylbenzoyl Cyanides with Carboxylic Acids Producing Functionalized Indenones
-
Nickel-Catlyzed [4+2+2]-Type Annulation Reaction of Cyclobutanones with Diynes and Enynes
-
Synthesis of 1(2H)-Isoquinolones by the Nickel-Catalyzed Denitrogenative Alkyne Insertion of 1,2,3-Benzotriazin-4(3H)-ones
-
Gold-Catalysed Intramolecular trans-Allylsilylation of Alkynes Forming 3-Allyl-1-silaindenes
-
Rhodium-Catalyzed Cyclization Reaction of 1,6-Enynes with Arylboronic Acids through ofβ-Hydride Elimination/Hydrorhodation Sequence
-
Rhodium-Catalyzed Borylative Cyclization of 2-Alkynylaryl Isocyanates with Bis(pinacolato)diboron
-
Synthesis of Silole Skeletons via Metathesis Reactions
-
Synthesis of Amine-Borane Intramolecular Complexes through Palladium-Catalyzed Rearrangement of Ammonioalkynyltriarylborates
-
A Direct Synthesis of Alkenyl Alkylidene Bicyclo[3.1.0]hexane Derivatives via Ruthenium(II)-Catalysed Bicyclisation of Allenynes
-
Stereoselective Synthesis of 3-Alkylideneoxindoles by Rhodium-Catalyzed Cyclization Reaction of 2-Alkynylaryl Isocyanates with Aryl- and Alkenylboronic Acids
-
Rhodium-Catalyzed Carbonylation of Spiropentanes
-
Asymmetric Synthesis of 3,4-Dihydrocoumarins by Rhodium-Catalyzed Reaction of 3-(2-Hydroxyphenyl)cyclobutanones
-
Stereoselective synthesis of trisubstituted alkenylboranes by palladium-catalysed reaction of alkynyltriarylborates with aryl halides
-
Rhodium-Catalysed Addition Reaction of Aryl- and Alkenylboronic Acids to Isocyanates
-
Rhodium-Catalyzed Arylative Cyclization Reaction of Diynes with Arylboronic Acids
-
Stereoselective Synthesis of α-Allenols by Rhodium-Catalyzed Reaction of Alkynyl Oxiranes with Arylboronic Acids
-
Synthesis and Helical Structure of Oligo(quinoline-2,3-diyl)s
-
Synthesis of α-Keto Esters by the Rhodium-Catalysed Reaction of Cyanoformate with Arylboronic Acids
-
Rhodium-Catalyzed Arylative Cyclization of Alkynones Induced by Addition of Arylboronic Acids
-
Ruthenium-Catalysed Double trans-Hydrosilylation of 1,4-Diarylbuta-1,3-diynes Leading to 2,5-Diarylsiloles
-
Rhodium-Catalyzed Reactions of Cyclobutanones with Alcohols and Amines Forming Esters and Amides
-
Studies on the Thermal Ring-Opening Reactions of cis-3,4-Bis(organosilyl)cyclobutenes<</li>
-
Cyclization Reaction of Cyano-Substituted Unsaturated Esters Prompted by Conjugate Addition of Organoborons
-
Synthesis of β-Amino Acid Derivatives by Nickel(0)-mediated Sequential Addition of Carbon Dioxide and Dibenzoyldiazene onto Unsaturated Hydrocarbons
-
Synthesis of Silafluorenes by Iridium-Catalyzed [2 + 2 + 2] Cycloaddition of Silicon-Bridged Diynes with Alkynes
-
Rhodium-Catalysed Substitutive Arylation of cis-Allylic Diols with Arylboroxines
-
Formation of Carbocycles through Sequential Carborhodation Triggered by Addition of Organoborons
-
C–E Bond Formation (E = Si, Sn, B, Te, S, P): Double Addition of Elements M–X to C=C and C≡C (X = Si, Sn, B, Te, S, P)
-
Rhodium-Catalyzed Cascade Reaction of 1,6-Enynes Involving Addition, Cyclization, and β-Oxygen Elimination
-
Nickel-Catalysed Intramolecular Alkene Insertion into Cyclobutanones
-
Construction of Carbon Frameworks through β-Carbon Elimination Mediated by Transition Metals
-
Synthesis of 3-Acyl-4-alkenylpyrrolidines by Platinum-Catalyzed Hydrative Cyclization of Allenynes
-
Two-Carbon Ring Expansion of Cyclobutanone Skeletons by Nickel-Catalyzed Intermolecular Alkyne Insertion
-
Enantioselective C–C Bond Cleavage Creating Chiral Quaternary Carbon Centers
-
Reactions of Cyanoboranes with a Palladium–PMe3 Complex: Mechanism for the Catalytic Cyanoboration of Alkynes
-
Torque Control by Metal-Orbital Interactions
-
Vinylcyclopropanation of Olefins via 3-Methoxy-1-propenylrhodium(I)
-
Eight-Membered Ring Construction by [4+2+2] Annulation Involving β-Carbon Elimination
-
A Direct Entry to Bicyclic Cyclobutenes via Platinum-Catalyzed Cycloisomerization of Allenynes
-
Activation of a Cyclobutanone Carbon–Carbon Bond over an Aldehyde Carbon–Hydrogen Bond in the Rhodium-Catalyzed Decarbonylation
-
Solvent and Ligand Partition Reaction Pathways in Nickel-Mediated Carboxylation of Methylenecyclopropanes
-
Rhodium-Catalysed 1,4-Addition of Diarylindium Hydroxides to α,β-Unsaturated Carbonyl Compounds
-
Rhodium-Catalyzed 1,3-Acyl Migration Reaction of Acetylenic β-Keto Esters with Arylboronic Acids and Application to Two-Carbon Ring Expansion
-
Intramolecular Cyanoboration of Alkynes via Activation of Boron-Cyanide Bonds by Transition Metal Catalysts
-
Synthesis of 1H-Inden-1-ol Derivatives via Rhodium-Catalyzed Annulation of o-Acylphenylboronic Acids with Alkynes
-
Molybdenum-Catalyzed Ring-Closing Metathesis of Allenynes
-
Addition/Ring-Opening Reaction of Organoboronic Acids to Cyclobutanones Catalyzed by Rhodium(I)/P(t-Bu)3 Complex
-
Asymmetric Carroll Rearrangement of Allyl α-Acetamido-β-ketocarboxylates Catalysed by a Chiral Palladium Complex
-
Rhodium-Catalyzed Annulation Reactions of 2-Cyanophenylboronic Acid with Alkynes and Strained Alkenes
-
Synthesis of Seven-Membered Ring Ketones by Arylative Ring-Expansion of Alkyne-Substituted Cyclobutanones
-
Intramolecular Nucleophilic Addition of an Organorhodium(I) to a Nitrile
-
Nickel-Catalyzed Intermolecular Alkyne Insertion into Cyclobutanones
-
Acids Direct 2-Styrylcyclobutanone into Two Distinctly Different Reaction Pathways
-
Rhodium-Catalyzed Addition-Cyclization Reactions of 5-Yn-1-ones with Arylboronic Acids
-
Ketone Synthesis by Intramolecular Acylation of Organorhodium(I) with Ester
-
Contrasteric Stereochemical Dictation of the Cyclobutene Ring-Opening Reaction by a Vacant Boron p Orbital
-
Rhodium-Catalyzed Cyclization of 1,6-Enynes Triggered by Addition of Arylboronic Acids
-
Synthesis and Reactions of Cyclic Silylboranes
-
Synthesis and Structural Analysis of Oligo(naphthalene-2,3-diyl)s
-
Aminoboranes as "Compatible" Iminium Ion Generators in Aminative C-C Bond Formations
-
Dramatic Effects of Boryl Substituents on Thermal Ring-Closing Reaction of Vinylallenes
-
Cycloadditions of Allenes
-
Synthesis and Thermal Ring-Opening of trans-3,4-Disilylcyclobutene
-
Eight-Membered Ring Formation via Olefin Insertion into a Carbon-Carbon Single Bond
-
Stereoselective Synthesis of (Z)-1-Silyl-2-stannylethene by Palladium-Catalyzed Silastannation of Ethyne and Its Synthetic Transformations
-
Synthesis of Tertiary Propargylamines by Sequential Reactions of in Situ Generated Thioiminium Salts with Organolithium and -magnesium Reagents
-
Rhodium-Catalyzed Addition/Ring-Opening Reaction of Arylboronic Acids with Cyclobutanones
-
A New Look at Boron Enolate Chemistry: Aminative C-C Bond Formation Using Diaminoboron Enolate with Aldehyde
-
Theoretical and Experimental Studies on the Thermal Ring-Opening Reaction of Cyclobutene Having a Stannyl Substituent at the 3-Position
-
Enantioface-Selective Palladium-Catalyzed Silaboration of Allenes via Double Asymmetric Induction
-
Palladium- and Nickel-Catalyzed Intramolecular Cyanoboration of Alkynes
-
Ruthenium-Mediated Regio- and Stereoselective Alkenylation of Pyridine
-
New Catalyzed Three-Component Cycloadditions for the Synthesis of Eight-Membered Carbocycles
-
A Study of the Stereochemical Course of β-Oxygen Elimination with a Rhodium(I) Complex
-
Catalyzed Intramolecular Olefin Insertion into a Carbon-Carbon Single Bond
-
Ruthenium-Mediated Domino Sequence Forming Six-Membered Ring Diene From Ene-Yne and Alkene
-
Rhodium-Catalyzed Addition of Arylboronic Acids to Oxabenzonorbornadienes
-
Stereoselective Synthesis of Isomeric Functionalized 1,3-Dienes from Cyclobutenones
-
A Silyl Substituent Can Dictate a Concerted Electrocyclic Pathway: Inward Torquoselectivity in the Ring Opening of 3-Silyl-1-cyclobutene
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Palladium-Catalyzed Asymmetric [4+2] Cycloaddition of Vinylallenes with 1,3-Dienes
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Lactone Formation by Rhodium-Catalyzed C-C Bond Cleavage of Cyclobutanone
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Fluoride-Catalyzed Aldol-type Reactions of α-Isocyano Esters Producing 2-Oxazoline Derivatives
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Construction of Eight-Membered Carbocycles by Palladium-Catalyzed [4+4] Cycloaddition of Vinylallenes
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Catalytic Asymmetric [4+1] Cycloaddition of Vinylallenes with Carbon Monoxide: Reversal of the Induced Chirality by the Choice of Metal
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Coordination Modes and Catalytic Carbonylative [4+1] Cycloaddition of Vinylallenes
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Cleavage of Carbon-Carbon Single Bonds by Transition Metals
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Single-Step Construction of a Nine-Membered Carbocycle by a New [4+4+1] Cycloaddition
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Ruthenium-Catalyzed Coupling of Unactivated Olefins with Unactivated Alkynes
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Rhodium-Catalyzed Intermolecular [4+2] Cycloaddition of Unactivated Substrates
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New Domino Sequences Involving Successive Cleavage of Carbon-Carbon and Carbon-Oxygen Bonds: Discrete Product Selection Dictated by Catalyst Ligands
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Synthesis of Pyrroline via Cyclization of 4-Isocyano-1-siloxy-1-alkene Induced by an Iminium Salt
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Palladium-Catalyzed Coupling Reactions of N-Methoxy-N-methylcarbamoyl Chloride for the Synthesis of N-Methoxy-N-methylamides
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Iridium-Catalyzed [5+1] Cycloaddition: Allenylcyclopropane as a Five-Carbon Assembling Unit
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Racemization and Deracemization of Poly(quinoxaline-2,3-diyl)s
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Rhodium(I)-Catalyzed Successive Double Cleavage of Carbon-Carbon Bonds of Strained Spiro Cyclobutanones
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Directed Intermolecular [4+2] Cycloaddition of Unactivated 1,3-Diene Substrates with High Regio- and Stereoselectivities
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Rhodium-Catalyzed Asymmetric [4+1] Cycloaddition
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New Synthetic Access to 1,3-Diaza-5-sila-2-boracyclohexane Frameworks by the Reaction of Borane with Bis[(N-arylimino)organosilylmethyl]silanes
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Synthesis of (Vinylallene)rhodium(III) Complex of Planar Structure: Perfect π–σ Conversion of 1,3-Diene System
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A New Water-Compatible Dehydrating Agent DPTF
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Breaking of the C–C Bond of Cyclobutanones by Rhodium(I) and Its Extension to Catalytic Synthetic Reactions
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Regio- and Stereoselective Incorporation of a 13C Nuclide into D-ribo-Phytosphingosine via SmI2-Mediated C-C Formation with 13C-Labeled Isocyanide
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New Synthesis of Quinoxaline Derivatives Based on Palladium Catalyzed Oligomerization of 1,2-Diisocyanoarenes
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Preparation of (Alkaneimidoyl)lanthanides and Their Reactions with Carbonyl Compounds
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Synthesis of a Bis(silyl)iridium(II) Complex via Oxidative Addition of an Si–Si Linkage to Ir(I) and Its Crystal Structure
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Alkyllithium-Mediated Anomalous Trimerization of 2,6-Xylyl Isocyanide
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A Study on Rhodium-Vinylallene Complexes Leading to a New Reaction, Rhodium-Catalyzed Carbonylative [4+1] Cycloaddition
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Generation of (α-Aminoalkyl)samarium(III) by a New Method of Metalation and Its Carbon-Carbon Bond-Forming Reactions
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A Remarkable Effect of Silyl Substitution on Electrocyclization of Vinylallenes
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Synthesis, Structure, and Reaction of the First Thermally Stable cis-(Silyl)(stannyl)palladium(II) Complex
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Preparation of 2,2-Dichloro-3(2H)-furanone and Its Reactions with Heteronucleophiles
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Selective Activation of Carbon–Carbon Bonds Next to a Carbonyl Group
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Theoretical Study on the Reaction Mechanism and Regioselectivity of Silastannation of Acetylenes with a Palladium Catalyst
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Syntheses and Interconversion of [Bis(silyl)alkene]palladium(0) and Bis(silyl)palladium(II) Complexes: A Mechanistic Model for Palladium-Catalyzed Bis-Silylation
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Synthesis of Alkynylsilanes by Samarium-Mediated Alkylation of Ethynylsilanes
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Carbon-Carbon Bond Forming Reactions via New Organosamarium(III) Intermediates
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Screw-Sense Selective Self-Propelling Polymerizations Producing Chiral Poly(quinoxaline-2,3-diyl)
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Stereoselective Synthesis of 1,2,4-Triols via Intramolecular Bis-Silylation of Carbon–Carbon Triple Bonds Followed by Hydrogenation
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Stereoselective Synthesis of 2-Amino Alcohols by Use of an Isocyanide as an Aminomethylene Equivalent
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Synthesis of Unsymmetrical α-Diketones via Autoxidation of α-Hydroxy Imines
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Non-Twisted Tetrakis(organosilyl)ethene
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Synthesis of Acylsilanes via Silastannation of Alkynes by a Palladium-Isocyanide Catalyst
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Stereoselective Intramolecular Bis-Silylation of Alkenes Promoted by a Palladium-Isocyanide Catalyst Leading to Polyol Synthesis
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Synthesis of α-Hydroxy Ketones by Samarium(II) Iodide-Mediated Coupling of Organic Halides, an Isocyanide, and Carbonyl Compounds
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Enantioselective Polymerization of 1,2-Diisocyanoarenes—Synthesis of Optically Active, Helical Poly(quinoxaline-2,3-diyl)s
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Studies on the Conformation of Helical Poly(2,3-quinoxalines). Empirical Energy Calculation and Theoretical Circular Dichroism
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Synthesis of Novel Thermotropic Liquid Crystalline Poly(2,3-quinoxalines)
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Living Polymerization of 1,2-Diisocyanoarenes Promoted by (Quinoxalinyl)nickel Complexes
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Generation and Alkylation of Carbanions α to the Nitrogen of Amines by a New Metallation Procedure
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Synthesis of (±)-Allokainic Acid via the Zinc Acetate Catalyzed Cyclization of γ-Isocyano Silyl Enolates
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Palladium-Catalyzed Insertion of Isocyanides into the Silicon-Silicon Linkages of Oligosilanes
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The First Total Synthesis of OPC-15161
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Intramolecular Bis-Silylation of Carbon-Carbon Double Bonds Leading to Stereoselective Synthesis of 1,2,4-Triols
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Palladium(II) Acetate-tert-Alkyl Isocyanide as a Highly Efficient Catalyst for the Inter- and Intramolecular Bis-Silylation of Carbon-Carbon Triple Bonds
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Facile Synthesis of Vicinal Di- and Tricarbonyl Compounds by Samarium Diiodide-Mmediated Double Insertion of Isocyanides into Organic Halides
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Aromatizing Oligomerization of 1,2-Diisocyanoarene to Quinoxaline Oligomers
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The Palladium-Catalyzed Reaction of Disilanylstannanes with Alkynes
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New Synthesis of Macrocyclic Dialkynyl Imines
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New Living Polymerization of 1,2-Diisocyanoarenes via (Quinoxalinyl)palladium Complexes. Synthesis of Poly(2,3-quinoxaline)
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The Synthesis and Reaction of N-Phenyl Alkynyl Imine-Hexacarbonyldicobalt Complexes
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Synthesis and Aldol-Type Reaction of 5-Methoxy-2-(Trialkylsilyl)oxazoles
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[2-Benzyloxy)-1-(N-2,6-xylylimino)ethyl]samarium as a Synthetic Equivalent to α-Hydroxyacetyl Anion
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Metalation of Isocyanides
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Fluoride Catalyzed Michael Reaction of α-Isocyano Esters with α,β-Unsaturated Carbonyl Compounds
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Transition Metal-Catalyzed Coupling of [1-(Arylimino)alkyl]zinc with Aromatic Iodide
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Synthesis of Unsymmetrical Dialkynyl Imines. Stepwise Coupling of N-Phenyl(phenylthio)imidoyl Chloride with Alkynyltin Compounds
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The Reaction of N-Phenyldialkynylimines with η5-Cyclopentadienyldicarbonylcobalt
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Novel Skeletal Rearrangement Reaction of Tetrasilanes with Aryl Isocyanides
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Palladium-Catalyzed Coupling of N-Substituted Isocyanide Dichlorides with Alkynyltin Compounds: New Synthesis of Dialkynylketones
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A Preparative Method for o-Diisocyanoarenes
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Claisen Rearrangement of Allylic α-Isocyano Esters—Regioselective Allylation of α-Isocyano Esters at the α-Carbon
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Conjugate Addition of N-Substituted Organo(silyliminomethyl)copper(I) to α,β-Unsaturated Carbonyl Compounds
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Reactions of (Triphenylphosphine)gold(I) Enolates and Homoenolates
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Convenient Preparative Method and Crystal Structures of (Triphenylphosphine)gold(I) Enolate and Homoenolate Complexes
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Preparation of [1-(Arylimino)alkyl]zinc by the α-Addition of Organozinc to Isocyanide
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Palladium-Catalyzed Regular Insertion of Isonitriles into Silicon–Silicon Linkage of Polysilane
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N-Substituted Organo(silyliminomethyl)stannanes: Synthetic Equivalent to Organosilylcarbonyl Anion and Carbonyl Dianion
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A Facile Synthesis of 1,5-dienes and β,γ-unsaturated nitriles via Trityl Perchlorate-Catalyzed Allylation
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Trityl Salt-Catalyzed Aldol-Type Reaction of Alkyl Enol Ethers with Acetals
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Cross-Coupling Reactions Based on Acetals
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A Novel Method for the Stereoselective Synthesis of β-Amino Acid Derivatives via Tin(II) Carboxylic Thio Ester Enolates
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A Convenient Method for the Hydrolysis of Diethyl Thioacetals Catalyzed by Trityl Perchlorate
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An Effective Activation of Allyl Methyl Ethers by a Catalytic Amount of Trityl Perchlorate in the Allylation of Silyl Enol Ethers
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A Convenient Method for Generation of Tin(II) thio Ester Enolate and Its Reaction with Aldehyde
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The Diphenylboryl Hexachloroantimonate Promoted Friedel-Crafts Acylation Reaction
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Recent Advances in Crossed Aldol Reactions
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Trityl Salts as Efficient Catalysts in the Aldol Reaction
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A Convenient Method for the Preparation of γ-Keto Sulfides from Thioacetals
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The Trityl Perchlorate Catalyzed Michael Reaction
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A Facile Synthesis of Homoallyl Ethers. The Reaction of Acetals with Allyltrimethylsilanes Promoted by Trityl Perchlorate or Diphenylboryl Triflate
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An Efficient Method for the preparation of threo Cross-Aldols from Silyl Enol Ethers and Aldehydes Using Trityl Perchlorate as a Catalyst
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Trityl Perchlorate as an Efficient Catalyst in the Aldol-Type Reaction
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A Facile Synthesis of γ,δ-Unsaturated Esters by the Palladium(II) Catalyzed Claisen Rearrangement
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A Novel Acid-Resistant Acetal-Type Protective Group for Alcohols
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2-(Benzyloxy)-1-propene: A Novel Protective Reagent of Hydroxyl Groups
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A New Method for the Stereoselective Synthesis of β-Xylofuranoside
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A Convenient Method for the Preparation of Enol Acetates of α-Keto Esters by the Alkylation of Cyanohydrin Silyl Ethers Derived from Glyoxylic Esters with Benzyl and Allyl Halides
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A Stereoselective Synthesis of 2-Amino-2-deoxy-D-ribose
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A New Method for the Generation of a Boron Enolate of an Ester. A New Synthesis of 2-Deoxy-D-ribose
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A Novel Method for the Generation of an Ester Enolate Anion from Ethoxyacetylene
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A New Aldol Reaction: a Method for the Generation of Vinyloxyboranes by the Acylation of Boron-Stabilized Carbanions
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Cesium Fluoride-Promoted Reaction of Aldehydes with S-(2-Benzimidazolyl)alkanethioates. A New Method for the Preparation of Enol Esters
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A New Allylation Reaction of the Copper(I) Salt of Enamines with 2-Allyloxybenzimidazoles