メンバー

廣瀬　崇至　(Dr. Takashi HIROSE)

京都大学大学院工学研究科
合成・生物化学専攻　助教
（物理有機化学分野 松田研究室)

〒615-8510
京都市西京区京都大学桂
e-mail: thirose_[at]_sbchem.kyoto-u.ac.jp
Tel: 075-383-2746
Fax: 075-383-2741

居室: A4棟3階　325号室

学歴

2005.3 九州大学工学部 物質科学工学科 卒業
2007.3 九州大学大学院工学府 物質創造工学専攻 修士課程 修了
2010.3 九州大学大学院工学府 物質創造工学専攻 博士後期課程 修了
2010.3 博士（工学）取得

職歴

2007.4-2010.3 日本学術振興会特別研究員（DC1）(九州大学大学院工学府)
2010.4-2011.10 日本学術振興会特別研究員（PD）(東京大学大学院工学系研究科)
2010.5-2011.10 アイントホーフェン工科大学 (TU/e) 訪問研究員 (Bert Meijer教授, オランダ )
2011.11-現在 京都大学大学院工学研究科 合成・生物化学専攻 助教

受賞

2007.7 Best Poster Presentation Award at ISNA-12
2009.5 日本化学会第89春季年会 学生講演賞
2015.7 J. Mater. Chem. C Poster Prize at ISNA-16
2017.2 第26回日本MRS年次大会 奨励賞
2017.2

Outstanding Reviewer for Chemical Communications in 2016

(recognized as a Top 10 outstanding reviewers by the editors)
2017.3 日本化学会第97春季年会 第31回若い世代の特別講演証
2018.9

Publons Peer Review Awards 2018

(for placing in the top 1% of reviewers in Chemistry)

原著論文

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  • 34. Y. Nakakuki, T. Hirose, K. Matsuda
    "Synthesis of Helical Analogue of Kekulene: a Flexible π-Expanded Helicene with Large Helical Diameter Acting as a Soft Molecular Spring"
    J. Am. Chem. Soc. 2018, on the web. (2018.10) [DOI: 10.1021/jacs.8b09825]
     
  • 33. A. Carné-Sánchez, G. A. Craig, P. Larpent, T. Hirose, M. Higuchi, S. Kitagawa, K. Matsuda, K. Urayama, S. Furukawa
    "Self-assembly of Metal–Organic Polyhedra into Supramolecular Polymers with Intrinsic Microporosity"
    Nat. Commun. 2018, 9, 2506. (2018.6) [DOI: 10.1038/s41467-018-04834-0]
    Published a Press Release on 24 July, 2018.
    (English version has released at EurekAlert! on 12 July, 2018.)
    Highlighted in Mainichi Shimbun August 4, 2018
    Highlighted in Kyoto Shimbun July 25, 2018
    Highlighted in Sankei Shimbun July 13, 2018
    Highlighted in Nikkan Kogyo Shimbun July 13, 2018
    Highlighted in ScienceDaily July 12, 2018
     
  • 32. Y. Nakakuki, T. Hirose, H. Sotome, H. Miyasaka, K. Matsuda
    "Hexa-peri-hexabenzo[7]helicene: Homogeneously π-Extended Helicene as a Primary Substructure of Helically Twisted Chiral Graphenes"
    J. Am. Chem. Soc. 2018, 140, 4317−4326. (2018.3) [DOI: 10.1021/jacs.7b13412]
    Published a Press Release on 19 March, 2018.
    (English version has released at EurekAlert! on 29 March, 2018.)
    Highlighted in Nikkan Kogyo Shimbun March 20, 2018
    Highlighted in ScienceDaily March 29, 2018
     
  • 31. N. Nishitani, T. Hirose, K. Matsuda
    "Influence of Multidirectional Interactions on Domain Size and Shape of 2-D Molecular Assemblies"
    Langmuir 2017, 33, 9151−9159. (2017.8) [DOI: 10.1021/acs.langmuir.7b02094]
     
  • 30. H. Kubo, T. Hirose, K. Matsuda
    "Control over the Emission Properties of [5]Helicenes Based on the Symmetry and Energy Levels of their Molecular Orbitals"
    Org. Lett. 2017, 19, 1776−1779. (2017.3) [DOI: 10.1021/acs.orglett.7b00548]
     
  • 29. M. Hasegawa, K. Kobayakawa, H. Matsuzawa, T. Nishinaga, T. Hirose, K. Sako, Y. Mazaki
    "Macrocyclic Oligothiophene with Stereogenic [2.2]Paracyclophane Scaffolds: Chiroptical Properties from π-Transannular Interactions"
    Chem. Eur. J. 2017, 23, 3267−3271. (2017.1) [DOI: 10.1002/chem.201605842]
     
  • 28. N. Maeda, T. Hirose, K. Matsuda
    "Discrimination between Conglomerates and Pseudoracemates Using Surface Coverage Plots in 2-D Self-Assemblies at the Liquid/Graphite Interface"
    Angew. Chem. Int. Ed. 2017, 56, 2371−2375. (2017.1) [DOI: 10.1002/anie.201611427]
     
  • 27. H. Noguchi, T. Hirose, S. Yokoyama, K. Matsuda
    "Fluorescence behavior of 2,6,10‐trisubstituted 4,8,12‐triazatriangulene cations in solution and in the solid state"
    CrystEngComm 2016, 18, 7377−7383. (2016.7) [DOI: 10.1039/C6CE00703A]
     
  • 26. T. Hirose, K. Sasatsuki, H. Noguchi, S. Yokoyama, K. Matsuda
    "Aggregation of 4,8,12-Triazatriangulene Cation with Amphiphilic Side Chains: Emission Properties in Solution, in Aggregates, and in the Solid State"
    Chem. Lett. 2016, 45, 1090−1092. (2016.6) [DOI: 10.1246/cl.160453]
     
  • 25. Y. Uchida, T. Hirose, T. Nakashima, T. Kawai, K. Matsuda
    "Synthesis and Photophysical Properties of a 13,13′-Bibenzo[b]perylenyl Derivative as a π-Extended 1,1′-Binaphthyl Analog"
    Org. Lett. 2016, 18, 2118−2121. (2016.4) [DOI: 10.1021/acs.orglett.6b00747]
     
  • 24. N. Maeda, T. Hirose, S. Yokoyama, K. Matsuda
    "Rational Design of Highly Photoresponsive Surface-Confined Self-Assembly of Diarylethenes: Reversible Three-State Photoswitching at the Liquid/Solid Interface"
    J. Phys. Chem. C 2016, 120, 9317−9325. (2016.4) [DOI: 10.1021/acs.jpcc.6b02115]
     
  • 23. T. Hirose, N. Ito, H. Kubo, T. Sato, K. Matsuda
    "Fluorescence Behavior of 5,10-Disubstituted [5]Helicene Derivatives in Solution and the Effect of Self-Assembly on Their Radiative and Non-Radiative Rate Constants"
    J. Mater. Chem. C 2016, 4, 2811−2819. (2016.1) [DOI: 10.1039/C5TC03675E]
    Selected as a Hot Paper
     
  • 22. S. Yokoyama, T. Hirose, K. Matsuda
    "Photochemical Cleavage of Axial Group Attached to the Central Carbon Atom of Triangulene Leuco Derivatives at the Ethanol/Au(111) Substrate"
    Chem. Lett. 2015, 44, 1616−1618. (2015.9) [DOI: 10.1246/cl.150738]
     
  • 21. S. Yokoyama, T. Hirose, K. Matsuda
    "Effects of Alkyl Chain Length and Hydrogen Bonds on the Cooperative Self-Assembly of 2-Thienyl-Type Diarylethenes at a Liquid/HOPG Interface"
    Chem. Eur. J. 2015, 21, 13569−13576. (2015.7) [DOI: 10.1002/chem.201500707]
    Selected as a Hot Paper
    Selected as a Cover Picture
    Highlighted in ATLAS of Science November 27, 2015
     
  • 20. N. Nishitani, T. Hirose, K. Matsuda
    "Investigation into Surface-Confined Self-Assembly Stabilized via Hydrogen Bond of Urea and Amide Groups: Quantitative Analysis of Concentration Dependence of Surface Coverage"
    Chem. Asian. J. 2015, 10, 1926−1931. (2015.7) [DOI: 10.1002/asia.201500453]
    Selected as a Very Important Paper (VIP)
    Selected as a Cover Picture
    Highlighted in ChemistryViews July 11, 2015
    Highlighted in ATLAS of Science January 7, 2016
     
  • 19. D. Frath, T. Sakano, Y. Imaizumi, S. Yokoyama, T. Hirose, K. Matsuda
    "Diarylethene Self-Assembled Monolayers: Cocrystallization and Mixing-Induced Cooperativity Highlighted by Scanning Tunneling Microscopy at the Liquid/Solid Interface"
    Chem. Eur. J. 2015, 21, 11350−11358. (2015.6) [DOI: 10.1002/chem.201500804]
    Selected as a Frontispiece
    Highlighted in ATLAS of Science January 4, 2016
     
  • 18. S. Yokoyama, T. Hirose, K. Matsuda
    "Photoinduced Four-State Three-Step Ordering Transformation of Photochromic Terthiophene at a Liquid/Solid Interface Based on Two Principles: Photochromism and Polymorphism"
    Langmuir 2015, 31, 6404−6414. (2015.5) [DOI: 10.1021/acs.langmuir.5b01404]
     
  • 17. K. Higashiguchi, G. Taira, J.-i. Kitai, T. Hirose, K. Matsuda
    "Photoinduced Macroscopic Morphological Transformation of an Amphiphilic Diarylethene Assembly: Reversible Dynamic Motion"
    J. Am. Chem. Soc. 2015, 137, 2722−2729. (2015.2) [DOI: 10.1021/ja512924q]
     
  • 16. T. Hirose, Y. Tsunoi, Y. Fujimori, K. Matsuda
    "Fluorescence Enhancement of Covalently Linked 1-Cyano-1,2-Diphenylethene Chromophores with Naphthalene-1,8-diyl Linker Units: Analysis Based on Kinetic Constants"
    Chem. Eur. J. 2015, 21, 1637−1644. (2014.11) [DOI: 10.1002/chem.201404745]
    Highlighted by ACS Noteworthy Chemistry, March 16, 2015
     
  • 15. S. Yokoyama, T. Hirose, K. Matsuda
    "Photochemical Cleavage of Axial Group Attached to the Central Carbon Atom of Triazatriangulene"
    Chem. Lett. 2015, 44, 76−78. (2014.10) [DOI: 10.1246/cl.140897]
     
  • 14. T. Fukaminato, T. Hirose, T. Doi, M. Hazama, K. Matsuda, M. Irie
    "Molecular Design Strategy toward Diarylethenes that Photoswitch with Visible Light"
    J. Am. Chem. Soc. 2014, 136, 17145−17154. (2014.11) [DOI: 10.1021/ja5090749]
     
  • 13. N. Ito, T. Hirose, K. Matsuda
    "Facile Photochemical Synthesis of 5,10-Disubstituted [5]Helicenes by Removing Molecular Orbital Degeneracy"
    Org. Lett. 2014, 16, 2502−2505. (2014.4) [DOI: 10.1021/ol5008718]
    Highlighted in ChemInform 2014, 45
     
  • 12. T. Hirose, Y. Inoue, J.-y. Hasegawa, K. Higashiguchi, K. Matsuda
    "Investigation on CD Inversion at Visible Region Caused by a Tilt of π-Conjugated Substituent: Theoretical and Experimental Approaches by Using Asymmetric Framework of Diarylethene Annulated Isomer"
    J. Phys. Chem. A 2014, 118, 1084−1093. (2014.1) [DOI: 10.1021/jp4122694]
     
  • 11. S. Yokoyama, T. Hirose, K. Matsuda
    "Phototriggered Formation and Disappearance of Surface-Confined Self-Assembly Composed of Photochromic 2-Thienyl-Type Diarylethene: A Cooperative Model at the Liquid/Solid Interface"
    Chem. Commun. 2014, 50, 5964−5966. (2014.1) [DOI: 10.1039/c3cc48895k]
    Selected as a back cover
     
  • 10. T. Sakano, Y. Imaizumi, T. Hirose, K. Matsuda
    "Formation of Two-Dimensionally Ordered Diarylethene Annulated Isomer at the Liquid/HOPG Interface upon In Situ UV Irradiation"
    Chem. Lett. 2013, 42, 1537−1539. (2013.8) [DOI: 10.1246/cl.130705]
     
  • 9. T. Hirose, F. Helmich, E. W. Meijer
    "Photo-Control over Cooperative Porphyrin Self-Assembly with Phenylazopyridine Ligands"
    Angew. Chem. Int. Ed. 2013, 52, 304−309. (2012. 9) [DOI: 10.1002/anie.201205085]
    Selected as a frontispiece article on the 125th anniversary issue
     
  • 8. Y. Nakano, T. Hirose, P. J. M. Stals, E. W. Meijer, A. R. A. Palmans
    "Conformational Analysis of Supramolecular Polymerization Process of Disc-Like Molecules"
    Chem. Sci. 2012, 3, 148−155. (2011. 9) [DOI: 10.1039/c1sc00547b]
     
  • 7. T. Hirose, K. Higashiguchi, K. Matsuda
    "Self-Assembly and Aggregate-Induced Enhanced Emission of Amphiphilic Fluorescence Dyes in Water and in the Solid State"
    Chem. Asian J. 2011, 6, 1057−1063. (2011. 2) [DOI: 10.1002/asia.201000824]
     
  • 6. T. Hirose, J.-y. Hasegawa, K. Matsuda
    "Theoretical Investigation on the Origin of the CD Signal Reversal for the Closed-ring Isomer of Diarylethene with Peripherical pi-Conjugated Substituents"
    Chem. Lett. 2010, 39, 516−517. (2010. 4) [DOI: 10.1246/cl.2010.516]
     
  • 5. T. Hirose, K. Matsuda
    "Self-Assembly of Amphiphilic Fluorescent Dyes Showing Aggregate-Induced Enhanced Emission: Temperature Dependence of Molecular Alignment and Intermolecular Interaction in Aqueous Environment"
    Chem. Commun. 2009, 5832−5834. (2009. 9) [DOI: 10.1039/b910531j]
    Highlighted by ACS Noteworthy Chemistry, November 2, 2009
     
  • 4. T. Hirose, M. Irie, K. Matsuda
    "The Photochromic and Self-Assembling Properties of Diarylethenes Having Chiral Amphiphilic Chains at The Reactive Carbon Atoms"
    New J. Chem. 2009, 33, 1332−1334. (2009. 2) [DOI: 10.1039/b822880a]
     
  • 3. T. Hirose, M. Irie, K. Matsuda
    "Self-Assembly of Photochromic Diarylethenes with Amphiphilic Side Chains: Core-Chain Ratio Dependence of Supramolecular Structures"
    Chem. Asian J. 2009, 4, 58−66. (2008. 12) [DOI: 10.1002/asia.200800340]
     
  • 2. T. Hirose, M. Irie, K. Matsuda
    "Temperature-Light Dual Control of Clouding Behavior of an Oligo(ethylene glycol)-Diarylethene Hybrid System"
    Adv. Mater. 2008, 20, 2137−2141. (2008. 4) [DOI: 10.1002/adma.200702314]
    Highlighted in NPG Asia Materials
     
  • 1. T. Hirose, K. Matsuda, M. Irie
    "Self-Assembly of Photochromic Diarylethenes with Amphiphilic Side Chains: Reversible Thermal and Photochemical Control"
    J. Org. Chem. 2006, 71, 7499−7508. (2006. 5) [DOI: 10.1021/jo060505t]
    Selected as a cover picture
     

総説記事

  • 10. 廣瀬崇至
    "分子間相互作用および分子軌道の制御に基づく高発光性分子の設計"
    色材協会誌 2018, 91, 24−29. (2018. 1) [DOI: 10.4011/shikizai.91.24]

  • 9. D. Frath, S. Yokoyama, T. Hirose, K. Matsuda
    "Photoresponsive Supramolecular Self-Assemblies at the Liquid/Solid Interface"
    J. Photochem. Photobiol. C 2017, 34, 29−40. (2017. 12) [DOI: 10.1016/j.jphotochemrev.2017.12.005]
     
  • 8. 廣瀬崇至、松田建児
    "超分子形成メカニズムと外部刺激応答性"
    高分子 2017, 66, (12), 675−679. (2017. 12)

  • 7. 廣瀬崇至
    "二次元界面での超分子化学—協同的組織化を用いた高感度光応答性分子配列の設計"
    化学と工業 2017, 70-11, 1029−1030. (2017. 11)

  • 6. T. Hirose, K. Matsuda
    "Photochemical Manipulation of Two-Dimensional Self-Assembly"
    in Encyclopedia of Interfacial Chemistry: Surface Science and Electrochemistry; K. Wandelt Ed.; Elsevier: Cambridge, MA, 2018; Vol. 4, pp 354−360. (2018. 4)
    in Reference Module in Chemistry, Molecular Sciences and Chemical Engineering; J. Reedijk Ed.; Elsevier: Waltham, MA, 2017. (2017. 7)
    [DOI: 10.1016/B978-0-12-409547-2.13701-1]

  • 5. 廣瀬崇至
    "協同的組織化を用いた光応答性二次元分子配列の設計"
    日本化学会研究会「低次元系光機能材料研究会」ニュースレター 2017, 15, 9−12. (2017. 7)

  • 4. K. Matsuda, T. Hirose, S. Yokoyama, D. Frath
    "Cooperative Self-Assembly of Photochromic Diarylethenes at Liquid/Solid Interface and Highly Sensitive Photoinduced Transformation of the Ordering"
    in Photon-Working Switches; Y. Yokoyama, K. Nakatani Eds.; Springer: Tokyo, 2017; pp 409−419. [DOI: 10.1007/978-4-431-56544-4_20]

  • 3. 横山創一、廣瀬崇至、松田建児
    "固液界面での協同的組織化を用いた高感度光配列制御"
    化学工業 2015, 66, (7), 17−20. (2015. 7)

  • 2. T. Hirose, K. Matsuda
    "Photoswitching of Chiral Supramolecular Environments and Photoinduced Lower Critical Solution Temperature Transitions in Aqueous Media Following a Supramolecular Approach"
    Org. Biomol. Chem. 2013, 11, 873−880. (2012. 11) [DOI: 10.1039/C2OB27049H]
    Highlighted in ChemInform 2013, 44
     
  • 1. 廣瀬崇至、松田建児
    "水中で組織化する両親媒性ジアリールエテンによる光誘起超分子環境変化とLCST転移挙動"
    光化学, 2008, 39, (2), 113−117. (2008. 8)

依頼・招待講演

  • 7. 廣瀬 崇至
    "キラリティーを持つ大きなπ共役系分子の合成と分光特性評価"
    第5回π造形科学若手研究会 (愛知県蒲郡市) [特別講演]
    Aichi, Japan, 5th October, 2018.
  • 6. 廣瀬 崇至
    "π拡張型キラル化合物の合成と分光特性"
    第7回化学フロンティア研究会 (北海道大学 理学部)
    Sapporo, Japan, 2nd September, 2018.
  • 5. T. Hirose
    "Design of Highly Photoresponsive 2-D Molecular Orderings Based on Cooperative Assembly at the Liquid/Graphite Interface"
    Workshop on Control and Functions of Two-Dimensional Materials (Osaka University)
    Osaka, Japan, 6th June, 2016.
  • 4. 廣瀬 崇至
    "走査型トンネル顕微鏡 (STM) を用いた光応答性分子配列の観測：協同的組織化モデルを用いた配列形成プロセスの解析"
    第61回超分子創製化学セミナー (立命館大学 薬学部)
    Shiga, Japan, 19th January, 2016.
  • 3. T. Hirose
    "STM Observation of Phototriggered Formation and Disappearance of Molecular Orderings: A Cooperative Model on 2-D Surface"
    The 4th International Kyoto Symposium on Organic Nanostructures (Kyoto University)
    Kyoto, Japan, 6th November, 2014.
  • 2. T. Hirose
    "Photo-Control of Binding Affinity at Pyridyl Group Based on Steric and Electronic Effect"
    第７回 スマート分子材料研究分野セミナー (北海道大学 電子科学研究所)
    Sapporo, Japan, 16th April, 2013.
  • 1. T. Hirose
    "Photo-Control of Cooperative Porphyrin Fibrous Aggregates with Photoresponsive Phenylazopyridine Ligand"
    The 16th International Workshop at Kyushu University (G-COE program)
    Fukuoka, Japan, 12th January, 2012.

特許

  • 1. フォトクロミック材料
    松田建児、廣瀬崇至、入江正浩
    特開2006-249205, 特許4558542号（成立特許）